Reservoir wellbore fluid

Patent metadata

Field	Value
Publication number	US-10280355-B2
Application number	US-201314414079-A
Country	US
Kind code	B2
Filing date	Jul 9, 2013
Priority date	Jul 9, 2012
Publication date	May 7, 2019
Grant date	May 7, 2019

Abstract

In one aspect, embodiments disclosed herein relate to an oil-based wellbore fluid. The oil-based wellbore fluid may include an oleaginous liquid and a surface-modified precipitated silica, wherein the surface-modified precipitated silica comprises a lipophilic coating. In another aspect, embodiments disclosed herein relate to a method of drilling or servicing a well. The method may include circulating a wellbore fluid, such as that described in the paragraph above, into a wellbore, and recovering at least a portion of the wellbore fluid from the wellbore.

First claim

What is claimed:

1. An oil-based wellbore fluid, comprising:
an oleaginous liquid;
a surface-modified precipitated silica, wherein the surface-modified precipitated silica comprises a lipophilic coating; and
an organoclay.

2. The fluid of claim 1 , wherein the lipophilic coating comprises at least one of a polysiloxane, an aminoalkylsilane, and an alkoxyorganomercaptosilane.

3. The fluid of claim 1 , wherein the surface modified precipitated silica has an average particle size (D 50 ) of less than 100 microns.

4. The fluid of claim 1 , wherein the oleaginous liquid comprises at least one of a diesel oil, a mineral oil, and a synthetic oil.

5. The fluid of claim 1 , wherein the fluid has a density of less than about 9.0 lb/gal.

6. The fluid of claim 1 , wherein the precipitated silica is present in an amount ranging from about 10 ppb to about 25 ppb, based on a total volume of the fluid.

7. The fluid of claim 1 , wherein the organoclay is present in an amount ranging from about 4 ppb to about 8 ppb, based on a total volume of the fluid.

8. The fluid of claim 1 , further comprising at least one of drilled solids, a gravel packing material, a fluid loss control agent, and a micronized weighting agent.

9. The fluid of claim 1 , wherein the fluid does not include an emulsifier.

10. The fluid of claim 1 , wherein the fluid further comprises a wetting agent or a water-absorbing polymer.

11. The fluid of claim 1 , wherein the organoclay is a polygorskite.

12. The fluid of claim 1 , wherein the organoclay is attapulgite or sepiolite.

13. The fluid of claim 1 , wherein the fluid is substantially free of hydrating clays.

14. The fluid of claim 1 , wherein the organoclay is present in an amount ranging from about 2 ppb to about 15 ppb, based on a total volume of the fluid.

15. The fluid of claim 1 , wherein the precipitated silica as a BET-5 nitrogen surface area of less than about 200 m 2 /g.

16. The fluid of claim 8 , wherein the micronized weighting agent is selected from the group consisting of barite, calcite, dolomite, ilmenite, hematite, olivine, siderite, manganese oxide, and strontium sulphate.

17. An oil-based wellbore fluid, comprising:
an oleaginous liquid;
a surface-modified precipitated silica, wherein the surface-modified precipitated silica comprises a polysiloxane coating; and
an organoclay.

18. The fluid of claim 17 , wherein the polysiloxane is selected from the group consisting of diethyl dichlorosilane, phenyl ethyl diethoxy silane, methyl phenyl dichlorosilane, 3,3,3-trifluoropropylmethyl dichlorosilane, trimethylbutoxy silane, sym-diphenyltetramethyl disiloxane, octamethyl trisiloxane, octamethyl cyclotetrasiloxane, hexamethyl disiloxane, pentamethyl dichlorosilane, trimethyl chlorosilane, trimethyl methoxysilane, trimethyl ethoxysilane, methyl trichlorosilane, methyl triethoxysilane, methyl trimethoxysilane, hexamethyl cyclotrisiloxane, hexamethyldisiloxane, hexaethyldisiloxane, dimethyl dichlorosilane, dimethyl dimethoxy silane, dimethyl diethoxysilane, polydimethylsiloxanes comprising 3 to 200 dimethylsiloxy units, trimethyl siloxy or hydroxydimethylsiloxy end blocked poly(dimethylsiloxane) polymers having an apparent viscosity range of from 1 to 1000 mPascals at 25° C., vinyl silane, gamm-methacryloxypropyl trimethoxy silane, polysiloxanes, polysiloxane spheres, and mixtures thereof.

19. An oil-based wellbore fluid, comprising:
an oleaginous liquid;
a surface-modified precipitated silica, wherein the surface-modified precipitated silica comprises an alkoxyorganomercaptosilane coating; and
an organoclay.

20. The fluid of claim 19 , wherein the alkoxyorganomercaptosilane coating is selected from the group consisting of bis(3-(triethoxysilylpropyl) tetrasulfide, bis(3-(triethoxysilylpropyl) disulfide, vinyltrimethoxy silane, vinyltriethoxy silane, 3-mercaptopropyltrimethoxy silane; 3-mercaptopropyltriethoxy silane; 3-aminopropyltriethoxysilane and 3-aminopropyltrimethoxysilane.

Assignees

• Mi Llc

Inventors

• Luyster Mark
• Gray Leigh
• Mettath Sashikumar
• Young Steven
• Stamatakis Emanuel

Classifications

• C09K8/82

  Oil-based compositions (C09K8/64 takes precedence) · CPC title

• C09K8/34 Primary

  Organic liquids · CPC title

• C09K8/502

  Oil-based compositions · CPC title

• E21B2021/006

  Fixed Constructions · mapped topic

• C09K8/32 Primary

  Non-aqueous well-drilling compositions, e.g. oil-based · CPC title