Transition metal compound, catalyst composition comprising same, and method for producing olefin polymer using same

Patent metadata

Field	Value
Publication number	US-10280238-B2
Application number	US-201615557328-A
Country	US
Kind code	B2
Filing date	Jun 28, 2016
Priority date	Aug 24, 2015
Publication date	May 7, 2019
Grant date	May 7, 2019

Abstract

The present invention provides a transition metal compound, a catalyst composition comprising the same, and a method for producing an olefin polymer using the catalyst composition, the transition metal compound being capable of exhibiting high activity in olefin polymerization reaction, and also being capable of easily controlling the physical properties of an olefin polymer. When the transition metal compound is used, it is possible to provide an olefin polymer having an excellent energy-saving effect at the time of processing or molding.

First claim

The invention claimed is:

1. A transition metal compound represented by the following Chemical Formula 1:

in the Chemical Formula 1,
M 1 is Group 3 transition metal, Group 4 transition metal, Group 5 transition metal, lanthanides transition metal or actinides transition metal,
X 1 and X 2 are identical to or different from each other, and each independently, halogen or C1-20 alkyl,
A is a Group 14 atom, n is an integer of 1 to 20,
R 1 is C1-20 alkyl, C2-20 alkenyl, C7-30 alkylaryl, C7-30 arylalkyl, or C6-30 aryl,
R 2 is hydrogen, C1-20 alkyl, C2-20 alkenyl, C7-30 alkylaryl, C7-30 arylalkyl, or C6-30 aryl,
R 3 and R 4 are each independently hydrogen, or C1-20 alkyl.

2. The transition metal compound according to claim 1 , wherein R 3 and R 4 are each independently hydrogen, or C1-5 linear alkyl.

3. The transition metal compound according to claim 1 , wherein R 1 is C3-6 branched alkyl, and n is 4 to 8.

4. The transition metal compound according to claim 1 , wherein R 2 is C1-6 linear alkyl.

5. The transition metal compound according to claim 1 , wherein M 1 is Group 4 transition metal.

6. A catalyst composition comprising the transition metal compound represented by the Chemical Formula 1 of claim 1 .

7. The catalyst composition according to claim 6 , wherein the catalyst composition comprises one or more cocatalysts selected from the group consisting of the compounds represented by the following Chemical Formulas 2, 3, and 4:
R 6 —[Al(R 5 )—O] m —R 7   [Chemical Formula 2]

in the Chemical Formula 2,
R 5 , R 6 and R 7 are each independently[M] hydrogen, halogen, a C1-20 hydrocarbyl group, or a C1-20 hydrocarbyl group substituted with halogen,
m is an integer of 2 or more,
D(R 8 ) 3   [Chemical Formula 3]

in the Chemical Formula 3
D is aluminum or boron,
R 8 's are each independently halogen, a C1-20 hydrocarbyl group, a C1-20 hydrocarbyloxy group, or a C1-20 hydrocarbyl group substituted with halogen,
[L-H] + [W(J) 4 ] − or [L] + [W(J) 4 ] −   [Chemical Formula 4]

in the Chemical Formula 4,
L is neutral or cationic Lewis base,
W is a Group 13 atom, and J's are each independently a C1-20 hydrocarbyl group; a C1-20 hydrocarbyloxy group; or a C1-20 hydrocarbyl group or a C1-20 hydrocarbyloxy group of which one or more hydrogen atoms are substituted with one or more substituents selected from halogen, a C1-20 hydrocarbyloxy group and a C1-20 hydrocarbyl(oxy)silyl group.

8. The catalyst composition according to claim 6 , further comprising s carrier supporting the transition metal compound.

9. The catalyst composition according to claim 8 , wherein the carrier is silica, alumina, magnesia or a mixture thereof.

10. The catalyst composition according to claim 7 , wherein the catalyst composition further comprises a carrier supporting the transition metal compound, and the mole ratio of the transition metal compound and the cocatalyst is 10:1 to 1:1.

11. A method for preparing olefin polymer comprising the step of polymerizing olefin monomers in the presence of the catalyst composition of claim 6 .

12. The method according to claim 11 , wherein the olefin monomer is propylene.

13. The method according to claim 12 , wherein polypropylene having a melting temperature of 130° C. to 146° C. is provided.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Byung Seok
• Park Hee Kwang
• Noh Kyung Seop
• An Sang Eun
• Lee In Sun
• Lee Hye Kyung
• Jeon Sang Jin
• Choi Ra Yun

Classifications

• C07F7/0803 Primary

  Compounds with Si-C or Si-Si linkages · CPC title

• C07F5/02

  Boron compounds · CPC title

• C08F10/06 Primary

  Propene · CPC title

• C08F4/65927

  two cyclopentadienyl rings being mutually bridged · CPC title

• C07F5/06

  Aluminium compounds · CPC title