Process and apparatus for the preparation of alkylene glycol

Patent metadata

Field	Value
Publication number	US-10279280-B2
Application number	US-201515513572-A
Country	US
Kind code	B2
Filing date	Sep 21, 2015
Priority date	Sep 24, 2014
Publication date	May 7, 2019
Grant date	May 7, 2019

Abstract

A process for the preparation of an alkylene glycol from an alkene is provided, along with an absorber apparatus. The process comprises: supplying a gas composition to an absorber comprising a column of vertically stacked trays, wherein each of the vertically stacked trays comprises: a perforated gas-liquid contacting member or members, a liquid inlet area, an outlet weir extending vertically above a surface of the tray at an opposite end of the tray from the liquid inlet area and having a height of at least 200 mm and at most 1500 mm, and a downcomer element which, in cooperation with an inner surface of a wall of the column, forms a downcomer for the passage of liquid downwardly to the liquid inlet area of an adjacent vertically stacked tray below, and allowing the gas composition to pass upwards through the alkylene oxide absorber.

First claim

That which is claimed is:

1. A process for the preparation of an alkylene glycol from an alkene comprising:
(a) supplying a gas composition comprising alkylene oxide, alkene, oxygen, carbon dioxide and water vapour to the bottom of an alkylene oxide absorber that comprises a column of vertically stacked trays, wherein each of the vertically stacked trays comprises:
a perforated gas-liquid contacting member or members,
a liquid inlet area,
an outlet weir extending vertically above a surface of the tray at an opposite end of the tray from the liquid inlet area and having a height of at least 200 mm and at most 1500 mm, and
a downcomer element which, in cooperation with an inner surface of a wall of the column, forms a downcomer for the passage of liquid downwardly to the liquid inlet area of an adjacent vertically stacked tray below, and
allowing the gas composition to pass upwards through the alkylene oxide absorber;

(b) supplying lean absorbent to the top of the alkylene oxide absorber and allowing the lean absorbent to pass downwards through the alkylene oxide absorber;
(c) intimately contacting the gas composition with lean absorbent on the trays in the alkylene oxide absorber in the presence of one or more catalysts that promote carboxylation and hydrolysis; and
(d) withdrawing fat absorbent from the alkylene oxide absorber.

2. The process as claimed in claim 1 , wherein the outlet weir on each vertically stacked tray has a height of at least 250 mm and at most 1000 mm.

3. The process as claimed in claim 1 , wherein the outlet weir on each vertically stacked tray comprises one or more apertures positioned below an upper edge of the outlet weir.

4. The process according to claim 1 , wherein the one or more catalyst that promote carboxylation and hydrolysis are selected from the group consisting of alkali metal halides, basic alkali metal salts and combinations thereof.

5. The process as claimed in claim 1 , wherein the lean absorbent comprises at least 5 wt % and less than 80 wt % water.

Assignees

• Shell Oil Co

Inventors

• Wilkinson Peter Mervyn
• Black Jesse Raymond
• Bastings Roel Guillaume Hubertus Leonardus

Classifications

• B01D3/20 Primary

  Bubble caps; Risers for vapour; Discharge pipes for liquid · CPC title

• C07C29/10

  of ethers, including cyclic ethers, e.g. oxiranes · CPC title

• C07C31/20

  Dihydroxylic alcohols · CPC title

• B01D3/22

  with horizontal sieve plates or grids; Construction of sieve plates or grids · CPC title

• C07C29/106 Primary

  of oxiranes · CPC title