Apparatus for pvc-containing mixed plastic waste pyrolysis
US-2024327719-A1 · Oct 3, 2024 · US
US10273411B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10273411-B2 |
| Application number | US-201515309707-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 7, 2015 |
| Priority date | May 9, 2014 |
| Publication date | Apr 30, 2019 |
| Grant date | Apr 30, 2019 |
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A compact, transportable batch-process supertorrefaction system includes at least one supertorrefying unit, a liquid tank containing molten salt, and a wash tank including a plurality of basins containing water having different temperatures and different salinity. The liquid tank and the wash tank sequentially supply the molten salt and the water to a receiving space of the at least one supertorrefying unit to supertorrefy the biomass into charcoal and to rinse and cool the charcoal, respectively. The plurality of basins of the wash tank sequentially supply water having different temperatures and salinity to the same receiving space to gradually rinse and cool the charcoal. The biomass is not moved in the at least one supertorrfeying unit during biomass supertorrefaction. The charcoal is not moved during charcoal cooling.
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What is claimed is: 1. A supertorrefaction system comprising: at least one supertorrefying unit defining a receiving space for receiving biomass; a liquid tank in fluid communication with the at least one supertorrefying unit and containing a first heat transfer liquid; a wash tank in fluid communication with the at least one supertorrefying unit and containing a second heat transfer liquid; a first filtration apparatus provided between the at least one supertorrefying unit and the liquid tank; a second filtration apparatus provided between the at least one supertorrefying unit and the wash tank; and an oxidizer comprising carbonate salt and nitrate salt as catalyst; wherein the at least one supertorrefying unit receives the first heat transfer liquid from the liquid tank to supertorrefy and convert the biomass into charcoal, and receives the second heat transfer liquid from the wash tank to rinse and cool the charcoal without moving the biomass and the charcoal during supertorrefaction and cooling processes; wherein the wash tank includes a plurality of basins containing the second heat transfer liquid having different temperatures and salinity, and wherein the first heat transfer liquid is molten salt. 2. The supertorrefaction system according to claim 1 , further comprising a holding member for carrying and moving the biomass to the receiving space and for carrying and moving the charcoal out of the receiving space. 3. The supertorrefaction system according to claim 1 , wherein the second heat transfer liquid is water. 4. The supertorrefaction system according to claim 2 , wherein the holding member includes a meshed basket. 5. The supertorrefaction system according to claim 2 , wherein the first heat transfer liquid is in direct contact with the biomass carried by the holding member and the second heat transfer liquid is in direct contact with the charcoal carried by the holding member, when the holding member is placed in the receiving space and when the first and second heat transfer liquids are supplied to the receiving space of the at least one supertorrefying unit at different time. 6. The supertorrefaction system according to claim 1 , further comprising a filtration apparatus disposed between the at least one supertorrefying unit and at least one of the liquid tank and the wash tank. 7. The supertorrefaction system according to claim 1 , further comprising a volatile organic compound (VOC) unit in fluid communication with the at least one supertorrefying unit for collecting VOCs. 8. The supertorrefaction system according to claim 7 , wherein the VOC unit includes a scrubber containing carbonate salt to remove acetic acid from the VOCs. 9. The supertorrefaction system according to claim 8 , wherein the VOC unit further includes a condenser for separating condensable VOCs as a bioliquor from incondensable gases. 10. The supertorrefaction system according to claim 1 , wherein the first heat transfer liquid includes LiOAc, NaOAc, KOAc in various singlet, binary, or ternary combinations. 11. A method of batch-processing biomass into charcoal, comprising: providing biomass in a receiving space of at least one supertorrefying unit; supplying a first heat transfer liquid to the supertorrefying unit to supertorrefy and converting the biomass into charcoal; sequentially supplying a second heat transfer liquid having different temperatures and different salinity to the at least one supertorrefying unit to cool the charcoal; removing charcoal fines particles from the first heat transfer liquid by a first filtration apparatus; removing charcoal fines particles from the second heat transfer liquid by a second filtration apparatus; and treating the first heat transfer liquid tainted by charcoal fines particles generated during a supertorrefaction process by an oxidizer in the at least one supertorrefying unit; wherein said oxidizer comprises carbonate salt and nitrate salt as catalyst; wherein the biomass is not moved in the at least one supertorrefying unit during supertorrefaction of the biomass and the charcoal is not moved in the at least one supertorrefying unit during cooling of the charcoal; wherein the first heat transfer liquid is molten salt. 12. The method according to claim 11 , further comprising preheating and supertorrefying the biomass in the receiving space of the supertorrefying unit and cooling the charcoal in the same receiving space of the supertorrefying unit. 13. The method according to claim 11 , wherein the second heat transfer liquid is water. 14. The method according to claim 11 , further comprising supplying the first heat transfer liquids to preheat and supertorrefy the biomass in the supertorrefying unit. 15. The method according to claim 11 , further comprising transporting the biomass into the supertorrefying unit before the first heat transfer liquid is supplied to the supertorrefying unit. 16. The method according to claim 15 , further comprising causing the first heat transfer liquid to be in direct contact with the biomass in the supertorrefying unit and causing the second heat transfer liquid to be in direct contact with the charcoal. 17. The method according to claim 16 , further comprising changing at least one of operating temperature, residence time, and pretreatment impregnation of the biomass to generate different types of charcoal.
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