Polyamide resin composition

Patent metadata

Field	Value
Publication number	US-10273359-B2
Application number	US-201013395535-A
Country	US
Kind code	B2
Filing date	Sep 14, 2010
Priority date	Sep 14, 2009
Publication date	Apr 30, 2019
Grant date	Apr 30, 2019

Abstract

Disclosed is a polyamide resin composition, including: a polyamide (A) containing a diamine unit including 70 mol % or more of a p-xylylenediamine unit and a dicarboxylic acid unit including 70 mol % or more of a linear aliphatic dicarboxylic acid unit having 6 to 18 carbon atoms; and a filler (B), in which the polyamide (A) includes a polyamide having a phosphorus atom concentration of 50 to 1,000 ppm and a YI value of 10 or less in a color difference test in accordance with JIS-K-7105, and a content of the filler (B) is 1 to 200 parts by mass with respect to 100 parts by mass of the polyamide (A).

First claim

The invention claimed is:

1. A molded article, comprising:
a polyamide (A) comprising a diamine unit including 90 mol % or more of a p-xylylenediamine unit and a dicarboxylic acid unit including 90 mol % or more of a sebacic acid unit and/or an azelaic acid unit;
a fibrous filler (B1) comprising at least one selected from the group consisting of a glass fiber and a carbon fiber and included in an amount of from 5 to 200 parts by mass with respect to 100 parts by mass of the polyamide (A); and
a solid lubricant (C) comprising at least one of a fluorine-based resin and graphite and included in an amount of 5 to 50 parts by mass with respect to 100 parts by mass of the polyamide (A),
wherein the polyamide (A) has a phosphorus atom concentration of 50 to 1,000 ppm and a YI value of 10 or less in a color difference test in accordance with JIS-K-7105,
the polyamide (A) has a number average molecular weight Mn within a range of from 14,000 to 30,000 in gel permeation chromatography, and a dispersivity Mw/Mn within a range of from 1.5 to 5.0,
the molded article has a tensile strength of from 135 MPa to 282 MPa, measured according to test method ISO527 with ISO3167 test piece dimensions, and
the molded article is an automotive part, an electrical part, an electronic part, or a sliding part.

2. The molded article according to claim 1 , wherein the dicarboxylic acid unit is the sebacic acid unit.

3. The molded article according to claim 1 , wherein the dicarboxylic acid unit is the azelaic acid unit.

4. The molded article according to claim 1 , wherein the polyamide (A) has a relative viscosity in a range of from 1.8 to 4.2.

5. The molded article according to claim 1 , wherein the fibrous filler (B1) is the glass fiber.

6. The molded article according to claim 1 , wherein the fibrous filler (B1) is the glass fiber or the carbon fiber included in an amount of from 5 to 180 parts by mass with respect to 100 parts by mass of the polyamide (A).

7. The molded article according to claim 6 , wherein the solid lubricant (C) is polytetrafluoroethylene or graphite included in an amount of from 5 to 33 parts by mass with respect to 100 parts by mass of the polyamide (A).

8. The molded article according to claim 7 , wherein the solid lubricant (C) is graphite.

9. The molded article according to claim 7 , wherein the solid lubricant (C) is polytetrafluoroethylene.

10. The molded article according to claim 1 , wherein the polyamide (A) has the dispersivity Mw/Mn in a range of from 2.5 to 2.7.

11. The molded article according to claim 1 , wherein the polyamide (A) includes 10 mol % or less of an m-xylylenediamine unit.

12. The molded article according to claim 11 , wherein the m-xylylenediamine unit is present in the polyamide (A).

13. The molded article according to claim 11 , wherein the dicarboxylic acid unit is the sebacic acid unit or the azelaic acid unit.

14. The molded article according to claim 5 , wherein the fibrous filler (B1) is included in an amount of from 5 to 180 parts by mass with respect to 100 parts by mass of the polyamide (A).

15. The molded article according to claim 6 , wherein the fibrous filler (B1) is included in an amount of from 10 to 150 parts by mass with respect to 100 parts by mass of the polyamide (A).

16. The molded article according to claim 6 , wherein the fibrous filler (B1) is included in an amount of from 33 to 180 parts by mass with respect to 100 parts by mass of the polyamide (A).

17. The molded article according to claim 1 , wherein the solid lubricant (C) is included in an amount of 10 to 40 parts by mass with respect to 100 parts by mass of the polyamide (A).

18. The molded article according to claim 16 , wherein the solid lubricant (C) is included in an amount of 20 to 33 parts by mass with respect to 100 parts by mass of the polyamide (A).

19. The molded article according to claim 18 , wherein the polyamide (A) has the phosphorus atom concentration of 300 to 315 ppm.

20. The molded article according to claim 18 , wherein the polyamide (A) has the phosphorus atom concentration of 300 to 315 ppm, which is derived from at least one phosphorus-atom containing compound selected from the group consisting of calcium hypophosphite, calcium phosphite, and calcium dihydrogen phosphate.

21. The molded article according to claim 1 , wherein the molded article has a bending strength (MPa) of from 220 MPa to 430 MPa, measured according to test method ISO178 with test piece dimensions of 80×10×4 mm.

Assignees

• Ogawa Shun
• Kuwahara Hisayuki
• Ayuba Shinichi
• Sumino Takahiko
• Ishii Kentaro
• Mitsubishi Gas Chemical Co

Inventors

• Ogawa Shun
• Kuwahara Hisayuki
• Ayuba Shinichi
• Sumino Takahiko
• Ishii Kentaro

Classifications

• C08L77/06 Primary

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title

• C08G69/26

  derived from polyamines and polycarboxylic acids · CPC title

• C08G69/265

  from at least two different diamines or at least two different dicarboxylic acids · CPC title

• Y10T428/31681

  Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.] · CPC title