Colored translucent zirconia sintered body and powder, and application thereof
US-2017143458-A1 · May 25, 2017 · US
US10273189B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10273189-B2 |
| Application number | US-201515522965-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 30, 2015 |
| Priority date | Oct 31, 2014 |
| Publication date | Apr 30, 2019 |
| Grant date | Apr 30, 2019 |
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A zirconia sintered body that suppresses discoloration due to porcelain. The zirconia sintered body contains at least one of a coloring agent A, which is erbium oxide and a coloring agent B, which is nickel oxide, and contains a composite oxide of zirconium and vanadium. A composition, containing zirconium oxide, yttrium oxide, and a coloring agent, where the coloring agent contains at least one of a coloring agent A, which is erbium oxide and a coloring agent B, which is nickel oxide, and contains a coloring agent C, which is a composite oxide of zirconium and vanadium.
Opening claim text (preview).
The invention claimed is: 1. A zirconia sintered body, comprising: a coloring agent B: nickel oxide; and a coloring agent C: a composite oxide of zirconium and vanadium. 2. The zirconia sintered body according to claim 1 , further comprising: a coloring agent A: erbium oxide, wherein the coloring agent A is contained in an amount of 0.002 to 0.4 mass %; the coloring agent B is contained in an amount of 0.0002 to 0.03 mass %; and the coloring agent C is contained in an amount of 0.005 to 0.1 mass %. 3. The zirconia sintered body according to claim 1 , wherein the coloring agent B is contained in an amount of 0.01 to 0.02 mass %; and the coloring agent C is contained in an amount of 0.06 to 0.08 mass %. 4. A composition, comprising: zirconium oxide; yttrium oxide; and a coloring agent, wherein the coloring agent comprises a coloring agent B: nickel oxide, and a coloring agent C: a composite oxide of zirconium and vanadium. 5. The composition according to claim 4 , further comprising: a coloring agent A: erbium oxide, wherein the coloring agent A is contained in an amount of 0.002 to 0.5 mass %; the coloring agent B is contained in an amount of 0.0002 to 0.03 mass %; and the coloring agent C is contained in an amount of 0.005 to 0.1 mass %. 6. The composition according to claim 4 , wherein the coloring agent B is contained in an amount of 0.01 to 0.02 mass %; and the coloring agent C is contained in an amount of 0.06 to 0.08 mass %. 7. A pre-sintered body, produced by firing a composition according to claim 4 at 800° C. to 1200° C. 8. A zirconia sintered body, produced by firing a composition according to claim 4 at 1300° C. to 1600° C. 9. A pre-sintered body, comprising: zirconium oxide; yttrium oxide; and a coloring agent, wherein the coloring agent comprises a coloring agent B: nickel oxide, and a coloring agent C: a composite oxide of zirconium and vanadium. 10. The pre-sintered body according to claim 9 , further comprising: a coloring agent A: erbium oxide, wherein the coloring agent A is contained in an amount of 0.002 to 0.4 mass %; the coloring agent B is contained in an amount of 0.0002 to 0.03 mass %; and the coloring agent C is contained in an amount of 0.005 to 0.1 mass %. 11. The pre-sintered body according to claim 9 , wherein the coloring agent B is contained in an amount of 0.01 to 0.02 mass %; and the coloring agent C is contained in an amount of 0.06 to 0.08 mass %. 12. A zirconia sintered body, produced by firing a pre-sintered body according to claim 9 at 1300° C. to 1600° C. 13. A dental product, comprising a zirconia sintered body according to claim 1 . 14. The dental product according to claim 13 , further comprising: a porcelain layer laminated on the zirconia sintered body, wherein the porcelain layer comprises an anti-yellowing material. 15. The dental product according to claim 14 , wherein the anti-yellowing material comprises at least one selected from the group consisting of an antimony compound and a cerium compound.
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