Method for manufacturing positive electrode active material for power storage device

Patent metadata

Field	Value
Publication number	US-10272594-B2
Application number	US-201514642079-A
Country	US
Kind code	B2
Filing date	Mar 9, 2015
Priority date	Oct 15, 2010
Publication date	Apr 30, 2019
Grant date	Apr 30, 2019

Abstract

In a manufacturing process of a positive electrode active material for a power storage device, which includes a lithium silicate compound represented by a general formula Li 2 MSiO 4 , heat treatment is performed at a high temperature on a mixture material, grinding treatment is performed, a carbon-based material is added, and then heat treatment is performed again. Therefore, the reactivity between the substances contained in the mixture material is enhanced, favorable crystallinity can be obtained, and further microparticulation of the grain size of crystal which is grown larger by the high temperature treatment and crystallinity recovery are achieved; and at the same time, carbon can be supported on the surfaces of particles of the crystallized mixture material. Accordingly, a positive electrode active material for a power storage device, in which electron conductivity is improved, can be manufactured.

First claim

What is claimed is:

1. A method for manufacturing an active material, comprising the steps of:
forming a mixture by a mixing treatment of a compound containing lithium, a compound containing a transition metal, and a compound containing silicon;
performing first heat treatment on the mixture to form first particles after the mixing treatment;
performing grinding treatment on the first particles to obtain second particles after the first heat treatment; and
performing second heat treatment on the second particles at a temperature lower than a temperature of the first heat treatment to form third particles after the grinding treatment,
wherein the grinding treatment is performed by a planetary ball mill after adding a solvent to the first particles,
wherein the grinding treatment is performed for longer time than the mixing treatment, and
wherein the active material comprises lithium metal silicate.

2. The method for manufacturing an active material according to claim 1 , wherein the transition metal is selected from the group consisting of manganese, iron, cobalt and nickel.

3. The method for manufacturing an active material according to claim 1 , wherein the first heat treatment is performed at a temperature of higher than or equal to 800° C. and lower than or equal to 1500° C., and the second heat treatment is performed at a temperature of higher than or equal to 400° C. and lower than or equal to 900° C.

4. The method for manufacturing an active material according to claim 1 , wherein the first heat treatment is performed plural times at different temperatures which are sequentially set higher every time heat treatment is performed.

5. The method for manufacturing an active material according to claim 1 , wherein a thickness of a carbon layer supported on a surface of the active material is less than or equal to 100 nm.

6. The method for manufacturing an active material according to claim 1 , wherein an average primary particle size of the third particles measured with a SEM is smaller than that of the first particles measured with a SEM.

7. The method for manufacturing an active material according to claim 1 ,
wherein the first particles have a first crystallinity,
wherein the second particles have a second crystallinity,
wherein the third particles have a third crystallinity,
wherein the second crystallinity is lower than the first crystallinity, and
wherein the second crystallinity is lower than the third crystallinity.

8. The method for manufacturing an active material according to claim 1 , wherein the mixing treatment is performed by a planetary ball mill.

9. The method for manufacturing an active material according to claim 1 ,
wherein the mixing treatment is performed for longer than or equal to 30 minutes and shorter than or equal to 5 hours, and
wherein the grinding treatment is performed for longer than or equal to 10 hours and shorter than or equal to 60 hours.

10. The method for manufacturing an active material according to claim 1 ,
wherein the third particles comprise lithium metal silicate represented by Formula Li 2 MSiO 4 , and
wherein M is selected from the group consisting of manganese, iron, cobalt and nickel.

11. A method for manufacturing an active material, comprising the steps of:
performing a first mixing treatment of a mixture material comprising a compound containing lithium, a compound containing a transition metal, and a compound containing silicon to obtain a first mixture;
performing first heat treatment on the first mixture to form first particles after the first mixing treatment;
performing grinding treatment on the first particles to obtain second particles after the first heat treatment;
adding a carbon-based material to the second particles and performing a second mixing treatment to obtain a second mixture; and
performing second heat treatment on the second mixture at a temperature lower than a temperature of the first heat treatment to form third particles after the second mixing treatment,
wherein the grinding treatment is performed by a planetary ball mill after adding a solvent to the first particles,
wherein the grinding treatment is performed for longer time than the first mixing treatment, and
wherein the active material comprises a lithium metal silicate.

12. The method for manufacturing an active material according to claim 11 , wherein the transition metal is selected from the group consisting of manganese, iron, cobalt and nickel.

13. The method for manufacturing an active material according to claim 11 , wherein the first heat treatment is performed at a temperature of higher than or equal to 800° C. and lower than or equal to 1500° C., and the second heat treatment is performed at a temperature of higher than or equal to 400° C. and lower than or equal to 900° C.

14. The method for manufacturing an active material according to claim 11 , wherein the first heat treatment is performed plural times at different temperatures which are sequentially set higher every time heat treatment is performed.

15. The method for manufacturing an active material according to claim 11 , wherein the carbon-based material is any of glucose, cyclic monosaccharide, straight-chain monosaccharide and polysaccharide.

16. The method for manufacturing an active material according to claim 11 , wherein a thickness of a carbon layer supported on a surface of one of the third particles is less than or equal to 100 nm.

17. The method for manufacturing an active material according to claim 11 , wherein an average primary particle size of the third particles measured with a SEM is smaller than that of the first particles measured with a SEM.

18. The method for manufacturing an active material according to claim 11 ,
wherein the first particles have a first crystallinity,
wherein the second particles have a second crystallinity,
wherein the third particles have a third crystallinity,
wherein the second crystallinity is lower than the first crystallinity, and
wherein the second crystallinity is lower than the third crystallinity.

19. The method for manufacturing an active material according to claim 11 , wherein the first mixing treatment is performed by a planetary ball mill.

20. The method for manufacturing an active material according to claim 11 ,
wherein the first mixing treatment is performed for longer than or equal to 30 minutes and shorter than or equal to 5 hours, and
wherein the grinding treatment is performed for longer than or equal to 10 hours and shorter than or equal to 60 hours.

21. The method for manufacturing an active material according to claim 11 ,
wherein the third particles comprise lithium metal silicate represented by Formula Li 2 MSiO 4 , and
wherein M is selected from the group consisting of manganese, iron, cobalt and nickel.

Assignees

• Semiconductor Energy Lab

Inventors

• Yamakaji Masaki
• Nara Koji
• Motoyoshi Mako

Classifications

• C01B33/32

  Alkali metal silicates ({C01B33/24} , C01B33/26 take precedence) · CPC title

• B29B9/16

  Auxiliary treatment of granules · CPC title

• Y02P70/54

  Cross-Sectional Technologies · mapped topic

• H01M10/052

  Li-accumulators · CPC title

• B29B9/12 Primary

  characterised by structure or composition · CPC title