All-solid-state battery

Patent metadata

Field	Value
Publication number	US-10270135-B2
Application number	US-201415022716-A
Country	US
Kind code	B2
Filing date	Sep 12, 2014
Priority date	Sep 25, 2013
Publication date	Apr 23, 2019
Grant date	Apr 23, 2019

Abstract

An all-solid-state battery that makes it possible to improve the cycling properties is provided. The all-solid-state battery includes an anode; a cathode; a solid electrolyte layer that is arranged between the anode and the cathode; an anode collector that is connected to the anode; and a cathode collector that is connected to the cathode. In the all-solid-state battery, a metal layer is arranged between the anode and the anode collector and/or between the cathode and the cathode collector, and metal that does not undergo an electrochemical reaction with metal ions under a potential environment where an active material stores and releases the metal ions, and whose percent elongation is no less than 22% is used for the metal layer.

First claim

The invention claimed is:

1. An all-solid-state battery comprising:
an anode that includes an anode active material;
a cathode that includes a cathode active material;
a solid electrolyte layer that is arranged between the anode and the cathode;
an anode collector that is connected to the anode; and
a cathode collector that is connected to the cathode,
wherein a metal layer is arranged between the anode and the anode collector and/or between the cathode and the cathode collector,
in a case where the metal layer is a metal layer in an anode side which is arranged between the anode and the anode collector, the metal layer in the anode side contains metal whose percent elongation is no less than 22%, and an inert metal layer in the anode side is arranged between the metal layer in the anode side and the anode,
metal that does not undergo an electrochemical reaction with metal ions under a potential environment where the anode active material stores and releases the metal ions is used for the inert metal layer in the anode side,
the anode collector contains a metal, which metal is different from a metal of the metal layer whose percent elongation is no less than 22%, and is different from a metal of the inert metal layer, and which metals in the metal layer whose percent elongation is no less than 22% and in the inert metal layer are different from each other, and
the metal whose percent elongation is no less than 22% is selected from the group consisting of In and metals softer than In,
in a case where the metal layer is a metal layer in a cathode side which is arranged between the cathode and the cathode collector, the metal layer in the cathode side contains metal whose percent elongation is no less than 22%, and an inert metal layer in the cathode side is arranged between the metal layer in the cathode side and the cathode,
metal that does not undergo an electrochemical reaction with metal ions under a potential environment where the cathode active material stores and releases the metal ions is used for the inert metal layer in the cathode side,
the cathode collector contains a metal, which metal is different from a metal of the metal layer whose percent elongation is no less than 22%, and is different from a metal of the inert metal layer, and which metals in the metal layer whose percent elongation is no less than 22% and in the inert metal layer are different from each other, and
the metal whose percent elongation is no less than 22% is selected from the group consisting of In and metals softer than In.

2. The all-solid-state battery according to claim 1 , wherein
the anode active material is graphite, and the inert metal layer in an anode side includes metal selected from Li, Cu, Au, Ti, Fe, Nb and Ni.

3. The all-solid-state battery according to claim 1 , wherein
the cathode active material is LiCoO 2 or LiNi 1/3 Co 1/3 Mn 1/3 O 2 , and the inert metal layer in a cathode side includes metal selected from Li, In, Zn, Al, Ca, Zr, Sn, W, Ti, Fe, Nb, Ni, V, Pd, Mn and Mo.

4. The all-solid-state battery according to claim 2 , wherein
the cathode active material is LiCoO 2 or LiNi 1/3 Co 1/3 Mn 1/3 O 2 , and the inert metal layer in a cathode side includes metal selected from Li, In, Zn, Al, Ca, Zr, Sn, W, Ti, Fe, Nb, Ni, V, Pd, Mn and Mo.

5. The all-solid-state battery according to claim 1 , wherein
the metal whose percent elongation is no less than 22% is In, and the metal of the inert metal layer is Cu, for the cathode side only, for the anode side only, or for both the cathode side and the anode side.

Assignees

• Toyota Motor Co Ltd

Inventors

• Yamasaki Hisatsugu
• Kato Yuki
• Ohtomo Takamasa
• Kawakami Masatsugu

Classifications

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/366

  as layered products · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/667

  in the form of layers, e.g. coatings · CPC title