Electrochemical cell
US-2024332559-A1 · Oct 3, 2024 · US
US10270119B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10270119-B2 |
| Application number | US-201515125150-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 12, 2015 |
| Priority date | Mar 12, 2014 |
| Publication date | Apr 23, 2019 |
| Grant date | Apr 23, 2019 |
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The present invention is concerned with improved fuel cell stack assembly arrangements.
Opening claim text (preview).
The invention claimed is: 1. An intermediate-temperature solid oxide fuel cell stack assembly comprising: (i) a base plate; (ii) at least one intermediate-temperature solid oxide fuel cell stack mounted upon said base plate; (iii) an end plate; and (iv) clamping means adapted to exert compressive force upon said at least one fuel cell stack between said base plate and said end plate, each fuel cell stack having first and second ends, each fuel cell stack arranged mounted between said base plate and said end plate, and comprising at least one electrochemically active fuel cell stack repeat layer and at least one of: (a) an at least one electrochemically inactive fuel cell stack repeat layer positioned between said base plate and said at least one electrochemically active fuel cell stack repeat layer; and (b) an at least one electrochemically inactive fuel cell stack repeat layer positioned between said end plate and said at least one electrochemically active fuel cell stack repeat layer; each electrochemically active fuel cell stack repeat layer comprising a metal substrate, anode, electrolyte and cathode layers mounted upon said metal substrate, and a metal interconnect plate, a metal spacer located between said metal substrate and said metal interconnect plate, and defining an oxidant flow path from an oxidant inlet to an exhaust oxidant outlet, and a fuel flow path from a fuel inlet to an exhaust fuel outlet, and each electrochemically inactive fuel cell stack repeat layer adapted such that it is incapable of performing an electrochemical function and comprising a metal substrate, anode, electrolyte and cathode layers mounted upon said metal substrate, and a metal interconnect plate, a metal spacer located between said metal substrate and said metal interconnect plate, and defining an oxidant flow path from an oxidant inlet to an exhaust oxidant outlet. 2. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 1 , wherein said at least one electrochemically inactive fuel cell stack repeat layer comprises a plurality of electrochemically inactive fuel cell stack repeat layers, and both: (a) at least one of said electrochemically inactive fuel cell stack repeat layers is positioned between said base plate and said at least one electrochemically active fuel cell stack repeat layer; and (b) at least one of said electrochemically inactive fuel cell stack repeat layers is positioned between said end plate and said at least one electrochemically active fuel cell stack repeat layer. 3. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 2 , wherein each fuel cell stack, arranged in a direction from said base plate to said end plate, comprises: (A) a first of said electrochemically inactive fuel cell stack repeat layers; (B) said at least one electrochemically active fuel cell stack repeat layer; and (C) a second of said electrochemically inactive fuel cell stack repeat layers. 4. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 1 , wherein said metal substrate is formed from a sheet or foil. 5. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 4 , wherein said metal spacer of at least one of said electrochemically inactive fuel cell stack repeat layers is configured to block fuel flow from said fuel inlet to said exhaust fuel outlet. 6. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 1 , additionally comprising at least one electrically insulating gasket being located between an adjacent pair of said fuel cell stack repeat layers. 7. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 1 , wherein each of said fuel cell stack repeat layers is adjacent to at least one other of said fuel cell stack repeat layers, and additionally comprising at least one electrically insulating gasket being located between each of said adjacent fuel cell stack repeat layers. 8. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 1 , additionally comprising at least one of: (a) an endpole located between a first of said at least one electrochemically inactive fuel cell stack repeat layer and said at least one electrochemically active fuel cell stack repeat layer; and (b) an endpole located between a second of said at least one electrochemically inactive fuel cell stack repeat layer and said at least one electrochemically active fuel cell stack repeat layer. 9. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 1 , wherein said at least one intermediate-temperature solid oxide fuel cell stack is a planar fuel cell stack. 10. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 1 , additionally comprising a hood defining a hood volume containing said at least one intermediate-temperature solid oxide fuel cell stack. 11. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 10 , further comprising said hood being sealingly attached to said base plate and defining at least a portion of said hood volume between said base plate and said hood. 12. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 11 , further comprising said hood additionally being sealingly attached to said end plate and defining said hood volume between said base plate, said end plate and said hood. 13. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 1 , additionally comprising a thermally and electrically insulating gasket mounted between at least one of: (a) said base plate and said at least one fuel cell stack; and (b) said end plate and said at least one fuel cell stack. 14. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 1 , wherein said base plate and said end plate are electrically isolated from said at least one electrochemically active fuel cell stack repeat layer. 15. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 1 , additionally comprising first and second endpoles in electrical contact with said at least one electrochemically active fuel cell stack repeat layer, and wherein said base plate and said end plate are electrically isolated from said at least one electrochemically active fuel cell stack repeat layer. 16. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 15 , wherein said first endpole is part of the electrochemically active fuel cell stack repeat layer closest to said baseplate. 17. The intermediate-temperature solid oxide fuel cell stack assembly according to claim 15 , wherein said second endpole is part of the electrochemically inactive fuel cell stack repeat layer adjacent to the electrochemically active fuel cell stack repeat layer closest to said end plate. 18. A method of operating the intermediate-temperature solid oxide fuel cell stack assembly of claim 1 , the method comprising the steps of: (a) feeding fuel and oxidant to respective fuel and oxidant inlets to said intermediate-temperature solid oxide fuel cell stack assembly; and (b) operating said intermediate-temperature solid oxide fuel cell stack assembly to oxidise said fuel with said oxidant and generate electricity.
Metals or alloys · CPC title
Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks · CPC title
operating at high temperature, e.g. with stabilised ZrO2 electrolyte · CPC title
High-temperature cells with solid electrolytes · CPC title
Fuel cells with solid oxide electrolytes · CPC title
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