Electrode material, and lithium-ion battery or lithium-ion capacitor using same

Patent metadata

Field	Value
Publication number	US-10270100-B2
Application number	US-201515325947-A
Country	US
Kind code	B2
Filing date	Jul 9, 2015
Priority date	Jul 15, 2014
Publication date	Apr 23, 2019
Grant date	Apr 23, 2019

Abstract

Provided is an electrode material which has a co-continuous porous structure configured from a carbon skeleton and voids and which, by providing a large surface area, has excellent electrical conductivity, thermal conductivity, etc. This electrode material includes a porous carbon material having a co-continuous structure portion in which a carbon skeleton and voids form a continuous structure, and in the porous carbon material, the specific surface area measured by the BET method is 1 to 4500 m 2 /g, and the pore volume measured by the BJH method is 0.01 to 2.0 cm 3 /g.

First claim

The invention claimed is:

1. An electrode material comprising a porous carbon material having a co-continuous structure portion in which a carbon skeleton and voids form a continuous structure, wherein in the porous carbon material, the specific surface area measured by the BET method is 1 to 4500 m 2 /g, and the pore volume measured by the BJH method is 0.01 to 2.0 cm 3 /g, wherein a structural period of the co-continuous structure portion of the porous carbon material is 0.002 to 3 μm.

2. The electrode material according to claim 1 , wherein a volume ratio (Vm/Vb) of a pore volume (Vm) measured by a MP method to a pore volume (Vb) measured by the BJH method of the porous carbon material is 1.0 or less.

3. The electrode material according to claim 1 , wherein a raw material of the porous carbon material is mainly polyacrylonitrile.

4. An electrode material formed by compositing the porous carbon material according to claim 1 with a metal capable of reversibly absorbing/releasing a lithium metal.

5. The electrode material according to claim 4 , wherein the metal capable of reversibly absorbing/releasing a lithium metal is at least one selected from the group consisting of Si, Sn, Ge, In, Sb, Zn, Mg, Al, Pb, and oxides thereof.

6. The electrode material according to claim 4 , wherein the metal capable of reversibly absorbing/releasing a lithium metal is supported or contained in the carbon skeleton in the co-continuous structure portion of the porous carbon material so as to be partially exposed to the surface of the carbon skeleton.

7. The electrode material according to claim 4 , wherein the metal capable of reversibly absorbing/releasing a lithium metal is supported in microscopic pores formed at the surface of the porous carbon material.

8. A lithium-ion battery using the electrode material according to claim 1 .

9. A lithium-ion capacitor using the electrode material according to claim 1 .

Assignees

• Toray Industries

Inventors

• Mihara Takaaki
• Tanaka Kentaro
• Takeuchi Kosaku
• Horiguchi Tomoyuki

Classifications

• C01P2006/40

  Electric properties · CPC title

• H01M4/38

  of elements or alloys · CPC title

• H01M4/386

  Silicon or alloys based on silicon · CPC title

• H01M4/364

  as mixtures · CPC title

• C01P2006/12

  Surface area · CPC title