Microlayer component for films with improved gas/moisture carrier by controlling crystal lamellae orientation

Patent metadata

Field	Value
Publication number	US-10265933-B2
Application number	US-201314646425-A
Country	US
Kind code	B2
Filing date	Nov 18, 2013
Priority date	Nov 28, 2012
Publication date	Apr 23, 2019
Grant date	Apr 23, 2019

Abstract

A microlayer component having improved oxygen and water vapor barrier properties (i.e., decreased permeabilities) comprises a barrier microlayer of a semi-crystalline barrier polymer in direct contact with a confining microlayer to promote in-plane crystalline lamellae formation. A microlayer component having a significant amount of in-plane crystalline lamellae may be characterized by at least 1.5× oxygen permeability improvement and at least 1.5× water vapor permeability improvement. A microlayer component having at least 1.5× improvement in oxygen and water vapor permeability may be coextruded and subjected to post extrusion stretching or heat treating.

First claim

What is claimed is:

1. A microlayer component comprised of:
at least one barrier microlayer having a thickness from 80 nm to 120 nm, the barrier microlayer of a first polymer material (barrier polymer) consisting of poly(l-butene), poly(l-butene) copolymer and combinations thereof, each barrier microlayer having opposing facial surfaces, wherein at least one facial surface is in direct contact with at least one confining microlayer of a second polymer material (confining polymer),
the barrier polymer being semi-crystalline, and
the barrier microlayer consisting of crystalline lamellae parallel with the barrier and confining microlayers.

2. The microlayer component of claim 1 , wherein the barrier polymer consists of poly(1-butene).

3. The microlayer component of claim 1 , wherein the confining polymer is selected from the group consisting of cyclo-olefin polymer (COP), polypropylene (PP), PP copolymers, and polycarbonate (PC).

4. The microlayer component of claim 1 having between about 90 and 10 volume percent (vol %) confining layer polymer material based on the total volume of the confining and barrier polymer material.

5. The microlayer component of claim 1 having a total thickness between about 0.001 mm and about 15 mm.

6. The microlayer component of claim 1 having an effective oxygen permeability improvement of at least about 1.5× over a barrier monolayer film and an effective water vapor permeability improvement of at least about 1.5× over the barrier monolayer film.

7. The microlayer component of claim 1 having an effective oxygen permeability improvement of at least about 5× over a barrier monolayer film.

8. The microlayer component of claim 1 having an effective water vapor permeability improvement of at least about 5× over a barrier monolayer film.

9. The microlayer component of claim 1 including at least one other microlayer or layer selected from the group consisting of skin layers, tie layers, EVOH layers, sealant layers, adhesive layers, foil layers, print layers, lamination layers, PET layers, other polymer layers, additional barrier layers, additional confining layers and combinations thereof.

10. The microlayer component of claim 1 which is heated above the melting temperature of the barrier polymer material and cooled to an isothermal temperature between the melting temperature and the onset of crystallization temperature and held at the isothermal temperature until the barrier polymer reaches at least about 50% of its final crystallinity.

Assignees

• Dow Global Technologies Llc

Inventors

• Jenkins Steven R
• Lee Patrick
• Dooley Joseph
• Kirkpatrick Donald E
• Obi Bernard

Classifications

• B32B27/306

  comprising vinyl acetate or vinyl alcohol (co)polymers · CPC title

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• B29C47/78

  Operations & Transport · mapped topic

• B32B2307/7244

  Oxygen barrier · CPC title

• B32B2250/42

  Alternating layers, e.g. ABAB(C), AABBAABB(C) · CPC title