Composite material having reduced degradation of pasty property

Patent metadata

Field	Value
Publication number	US-10265248-B2
Application number	US-201514797538-A
Country	US
Kind code	B2
Filing date	Jul 13, 2015
Priority date	Jul 29, 2014
Publication date	Apr 23, 2019
Grant date	Apr 23, 2019

Abstract

A composite material including silanated filler and mixed polymerizable monomer, having a stable pasty property which keeps well and has a consistent usability. A composite material containing a silanated filler, a polymerizable monomer, and a polymerization initiator, and may be produced by a process which includes in order of a mixed polymerizable monomer preparing step, a mixed polymerizable monomer preserving step, a composite material preparing step, a composite material preserving step, a composite material filling step, and a small quantity preserving container preserving step.

First claim

The invention claimed is:

1. A method for manufacturing a composite material comprising a silanated filler, a polymerizable monomer, and a polymerization initiator, the method comprising, in order, a mixed polymerizable monomer preparing step, a mixed polymerizable monomer preserving step, a composite material preparing step, a composite material preserving step, a composite material filling step, and a small quantity preserving container preserving step, wherein:
the mixed polymerizable monomer preparing step comprises charging the polymerization initiator into the polymerizable monomer in a mixing container, and mixing the polymerizable monomer and the polymerization initiator at a mixing temperature of 1-60° C. for a mixing period of 1 minute-24 hours to prepare a mixed polymerizable monomer,
the mixed polymerizable monomer preserving step comprises preserving 1-50 liters of the mixed polymerizable monomer prepared in the mixed polymerizable monomer preparing step at a preserving temperature of 1-23° C. for a preserving period of 10 days-1.5 years,
the composite material preparing step comprises performing a kneading step and a defoaming step, wherein
the kneading step comprises kneading the mixed polymerizable monomer and the silanated filler at a kneading temperature of 5-60° C. for a kneading period of 5-40 minutes after charging the silanated filler into the mixed polymerizable monomer, wherein a ratio of the silanated filler to the mixed polymerizable monomer is 0.1-9 parts by weight of the silanated filler to 1 part by weight of the mixed polymerizable monomer, and
the defoaming step comprises defoaming the mixed polymerizable monomer and the silanated filler at 5-200 Torr for a defoaming period of 5-30 minutes to prepare a composite material,

the composite material preserving step comprises preserving 1-8 liters of the composite material prepared in the composite material preparing step at a preserving temperature of 1-25° C. for a preserving period of 10 days-1.5 years,
the composite material filling step comprises filling the composite material preserved in the composite material preserving step by extrusion from a nozzle of a filling machine into a small quantity preserving container having 1-50 cc of volume, and
the small quantity preserving container preserving step comprises preserving the composite material filled in the composite material filling step in the small quantity preserving container at a preserving temperature of 1-40° C. for a preserving period of 50 days-5 years.

2. The method for manufacturing a composite material according to claim 1 , wherein the method further comprises, between the mixed polymerizable monomer preserving step and the kneading step of the composite material preparing step,
a particulate filler kneading step that comprises kneading the mixed polymerizable monomer and a particulate filler at a kneading temperature of 5-60° C. for a kneading period of 5-30 minutes after charging the particulate filler into the mixed polymerizable monomer, wherein a ratio of the particulate filler to the mixed polymerizable monomer is 0.01-0.2 parts by weight of the particulate filler to 1 part by weight of the mixed polymerizable monomer, and
a particulate filler defoaming step after the particulate filler kneading step that comprises defoaming the mixed polymerizable monomer and the particulate filler at 5-200 Torr for a defoaming period of 5-30 minutes,
wherein the mixture obtained from the particulate filler kneading step and the particulate filler defoaming step is utilized in the subsequent composite material preparing step,
wherein the particulate filler is kneaded with the mixed polymerizable monomer and the silanated filler in the kneading step of the composite material preparing step,
wherein the particulate filler is defoamed with the mixed polymerizable monomer and the silanated filler in the defoaming step of the composite material preparing step, and
wherein the composite material prepared in the defoaming step of the composite material preparing step comprises the particulate filler, the silanated filler, the polymerizable monomer, and the polymerization initiator.

3. The method for manufacturing a composite material according to claim 1 , wherein the mixed polymerizable monomer preserving step comprises a mixed polymerizable monomer evaluation step of evaluating a portion of the mixed polymerizable monomer.

4. The method for manufacturing a composite material according to claim 1 , wherein the composite material preserving step comprises a composite material evaluation step of evaluating a portion of the composite material.

Assignees

• Shofu Inc

Inventors

• Kadobayashi Yusei
• Shigezawa Masako

Classifications

• A61K6/887 Primary

  Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• A61K6/60 Primary

  comprising organic or organo-metallic additives · CPC title

• A61K6/77

  Glass · CPC title

• A61K6/0091

  Human Necessities · mapped topic

• A61K6/083 Primary

  Human Necessities · mapped topic