Fuel cell manifold including a coating to reduce the possibility of an electrical short

Patent metadata

Field	Value
Publication number	US-10263274-B2
Application number	US-201415126953-A
Country	US
Kind code	B2
Filing date	Mar 20, 2014
Priority date	Mar 20, 2014
Publication date	Apr 16, 2019
Grant date	Apr 16, 2019

Abstract

An illustrative example fuel cell manifold includes a manifold structure having at least one surface situated where the surface may be exposed to phosphoric acid. The surface has a coating that reduces a possibility of an electrical short between the manifold and the fuel cell stack adjacent the manifold if that surface is exposed to phosphoric acid during fuel cell operation.

First claim

I claim:

1. A fuel cell stack, comprising:
a cell stack assembly including a plurality of fuel cells arranged in series;
a liquid phosphoric acid electrolyte in the cell stack;
a first manifold structure coupled to the cell stack assembly and having at least one surface situated adjacent the cell stack assembly where the at least one surface is exposed to the phosphoric acid electrolyte; and
a first coating on the at least one surface of the first manifold that reduces a possibility of an electrical short between the manifold and the cell stack assembly adjacent the first manifold, the first coating being a self-healing phosphate coating and the first coating in contact with the at least one surface and at least one fuel cell of the plurality of fuel cells of the cell stack assembly.

2. The fuel cell stack of claim 1 further comprising:
a second manifold structure coupled to the cell stack assembly and having at least one surface situated adjacent the cell stack assembly where the at least one surface is exposed to the phosphoric acid electrolyte, the at least one surface of the second manifold structure having a second coating that reduces a possibility of an electrical short between the second manifold structure and the cell stack assembly adjacent the second manifold structure, the second coating being a self-healing phosphate coating.

3. The fuel cell stack of claim 1 , wherein one of the first and second coatings further comprises a dielectric insulator.

4. A fuel cell assembly, comprising:
a cell stack including a plurality of phosphoric acid fuel cells arranged in series, the cell stack having a first end and a second end;
a liquid phosphoric acid electrolyte in the cell stack;
a first manifold coupled to the cell stack and having a surface adjacent the first end of the cell stack;
a second manifold coupled to the cell stack assembly and having a surface adjacent the second end of the cell stack assembly;
a first coating layer on the surface of the first manifold, the first coating layer being a self-healing phosphate coating, the first coating layer being in contact with the surface of the first manifold and a surface of at least one phosphoric acid fuel cell of the plurality of phosphoric acid fuel cells of the cell stack; and
a second coating layer on the surface of the second manifold, the second coating layer including iron oxide.

5. The fuel cell assembly of claim 4 wherein the cell stack is configured to generate electricity based on an electrochemical reaction and the first and second coating layers reduce a possibility of an electrical short between the first manifold and the second manifold and the cell stack when the first coating layer and the second coating layer are exposed to phosphoric acid during fuel cell operation.

6. The fuel cell assembly of claim 4 , wherein the first coating layer and the second coating layer cover the entire surface of the first manifold adjacent the first end of the cell stack and the surface of the second manifold adjacent the second end of the cell stack.

7. The fuel cell assembly of claim 4 , wherein the second coating layer further comprises a dielectric insulator.

8. A method of forming a fuel cell assembly, the method comprising:
forming a cell stack assembly by arranging a plurality of fuel cells in series, the plurality of fuel cells including a liquid phosphoric acid electrolyte in the cell stack assembly;
coupling a first manifold to the cell stack assembly, the first manifold having a first surface in contact with the cell stack assembly;
coupling a second manifold to the cell stack assembly, the second manifold having a first surface in contact with the cell stack assembly, the first surface of the second manifold opposite the first surface of the first manifold;
forming a first coating on the first surface of the first manifold by forming a precursor layer of iron oxide and contacting the precursor layer with phosphoric acid; and
forming a second coating on the first surface of the second manifold, the second coating in contact with the first surface of the second manifold and an end surface of at least one of the plurality of fuel cells of the cell stack assembly, the forming of the second coating including forming a self-healing phosphate layer and contacting the self-healing phosphate layer with phosphoric acid.

9. The method of claim 8 wherein the first surface of the first manifold and the first surface of the second manifold are situated where the first surface of the first manifold and the first surface of the second manifold may be exposed to phosphoric acid, and wherein the first coating and the second coating reduce a possibility of an electrical short between the first manifold and the second manifold and the cell stack if the first surface of the first manifold and the first surface of the second manifold are exposed to phosphoric acid during fuel cell operation.

10. The method of claim 8 wherein the first coating and the second coating cover the entire first surfaces of the first manifold and the second manifold.

11. The method of claim 8 , wherein one of the first coating and the second coating further include a dielectric insulator.

12. A fuel cell stacking, comprising:
a cell stack assembly including a plurality of phosphoric acid fuel cells arranged in series;
a first manifold adjacent the cell stack assembly and having a first surface in contact with the cell stack assembly; and
a first coating layer formed on the first surface of the first manifold, the first coating layer positioned between the first manifold and the cell stack assembly and contacting the first surface and a first end of each of the plurality of phosphoric acid fuel cells, the first coating laying being a self-healing phosphate layer formed from a precursor of iron oxide interacting with phosphoric acid.

13. The fuel cell stack of claim 12 further comprising:
a second manifold adjacent the cell stack assembly and having a first surface in contact with the cell stack assembly; and
a second coating layer on the first surface of the second manifold, the second coating layer positioned between the second manifold and the cell stack assembly and contacting the first surface and a second end of each of the plurality of phosphoric acid fuel cells, the second coating layer including one of phosphate and iron oxide.

14. The fuel cell stack of claim 13 wherein one of the first coating and the second coating layer include a dielectric insulator.

15. A method for forming a fuel cell stack, comprising:
forming a cell stack assembly by arranging a plurality of phosphoric acid fuel cells in an interconnected series;
coupling a first manifold to the cell stack assembly, the first manifold having a first surface; and
forming a first coating on the first surface of the first manifold, the first coating contacting the first surface of the first manifold and each of the plurality of phosphoric acid fuel cells, forming the first coating including forming a self-healing phosphate layer by contacting an iron oxide precursor layer with phosphoric acid.

16. The method of claim 15 further comprising:
coupling a second manifold to the cell stack assembly opposite the first manifold, the second manifold having a first surface; and
forming a second coating on the first surface of the second manifold, the second coating contacting the first surface of the second manifold and each of the plurality of phosphoric acid fuel cells, the second coating including one of phosphate and an iron oxide precursor.

17. A fuel cell stack, com

Assignees

• Audi Ag

Inventors

• Ramaswamy Sitaram

Classifications

• H01M8/04201 Primary

  Reactant storage and supply, e.g. means for feeding, pipes · CPC title

• H01M8/086

  Phosphoric acid fuel cells [PAFC] · CPC title

• H01M8/2484 Primary

  characterised by external manifolds · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M8/2485

  Arrangements for sealing external manifolds; Arrangements for mounting external manifolds around a stack · CPC title