Lithium metal composite oxide having layered structure

Patent metadata

Field	Value
Publication number	US-10263244-B2
Application number	US-201214359346-A
Country	US
Kind code	B2
Filing date	Nov 26, 2012
Priority date	Nov 25, 2011
Publication date	Apr 16, 2019
Grant date	Apr 16, 2019

Abstract

Provided is a lithium metal composite oxide having a layered structure, which is particularly excellent as a positive electrode active material for batteries that are mounted on electric vehicles or hybrid vehicles. Proposed is a lithium metal composite oxide having a layered structure, which is represented by general formula Li 1+x (Mn α Co β Ni γ ) 1−x O 2 (0.00≤X≤0.07, 0.10≤α≤0.40, 0.10≤β≤0.40, and 0.30≤γ≤0.75) and has a specific surface area of more than 2.0 m 2 /g but 5.0 m 2 /g or less and has an average particle size of the primary particles/crystallite size ratio of 5.7 to 18.5.

First claim

The invention claimed is:

1. A positive electrode active material comprising a lithium metal composite oxide having a layered structure, which is expressed by General Formula of Li 1+x (Mn α Co β Ni γ ) 1−x O 2 (0.00<X≤0.07, 0.10≤α≤0.40, 0.10≤β≤0.40, and 0.30≤γ≤0.75),
wherein a specific surface area is more than 2.0 m 2 /g and equal to or less than 4.0 m 2 /g,
wherein a ratio of an average particle size of primary particles of a powder of the lithium metal composite oxide to a crystallite size of a powder of the lithium metal composite oxide is 5.7 to 13.0,
wherein a ratio of a pressed D50 of secondary agglomerated particles of a powder of the lithium metal composite oxide to a crystallite size of a powder of the lithium metal composite oxide is 25 to 500,
wherein the pressed D50 of the secondary agglomerated particles is measured by adding N-methyl pyrrolidone to the lithium metal composite oxide to obtain a paste, drying the paste, compressing the dried paste at a pressure of 32 MPa by using a pressing machine, and measuring the D50 after pressing using a laser diffraction and scattering type particle size distribution measuring device,
wherein the crystallite size is determined by measuring the crystallite size of a measurement sample (powder) by using an X-ray diffraction device using Cu-kα rays, at this time, analysis is performed by employing a fundamental parameter, and the crystallite size is calculated by using analysis software on the basis of an X-ray diffraction pattern obtained from a diffraction angle (2θ) range of 15° to 120°, and
wherein the average particle size of the primary particles is determined by observing the average particle size of the primary particles by using a scanning electron microscope at an acceleration voltage of 20 kV and a magnification of 5000 times, and an image of the primary particles in an electron microscope photograph is analyzed using image analysis software to calculate the average particle size of the primary particles.

2. A lithium battery, comprising:
the positive electrode active material according to claim 1 as the positive electrode active material.

3. A lithium battery for a hybrid electric vehicle, comprising:
the positive electrode active material according to claim 1 as the positive electrode active material.

Assignees

• Mitsui Mining & Smelting Co

Inventors

• Mitsumoto Tetsuya
• Ochi Yasuhiro
• Sakata Tomohiro
• Ide Hitohiko
• Hata Yoshimi
• Kagei Shinya

Classifications

• C01P2006/80

  Compositional purity · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title