Preparation method of silica aerogel-containing blanket and silica aerogel-containing blanket prepared by using the same

Patent metadata

Field	Value
Publication number	US-10260670-B2
Application number	US-201615548621-A
Country	US
Kind code	B2
Filing date	Feb 4, 2016
Priority date	Feb 13, 2015
Publication date	Apr 16, 2019
Grant date	Apr 16, 2019

Abstract

Provided are a preparation method of a silica aerogel-containing blanket which includes mixing a water glass solution, a polar organic solvent, and a silazane-based surface modifier to prepare a sol, preparing a silica gel-base material composite by immersion and gelation of a base material for a blanket in the sol, and drying the silica gel-base material composite, and a silica aerogel-containing blanket prepared by using the preparation method.
A silica aerogel-containing blanket having a high degree of hydrophobicity as well as excellent physical properties, particularly, low tap density, high porosity, and excellent mechanical flexibility may be prepared by the minimal use of a surface modifier without a surface modification step by the above method.

First claim

The invention claimed is:

1. A preparation method of a silica aerogel-containing blanket, the preparation method comprising:
mixing a water glass solution, an alcohol-based solvent, and a silazane-based surface modifier to prepare a sol including silica and an alkoxysilane-based compound which is formed by decomposition of the silazane-based surface modifier and the alcohol-based solvent;
preparing a silica gel-base material composite by immersion and gelation of a base material for a blanket in the sol; and
drying the silica gel-base material composite.

2. The preparation method of claim 1 , wherein the water glass solution comprises silica in an amount of 0.1 wt % to 30 wt % based on a total weight of the water glass solution.

3. The preparation method of claim 1 , wherein the water glass solution further comprises an acid catalyst.

4. The preparation method of claim 1 , wherein the alcohol-based solvent is a linear alcohol having 1 to 4 carbon atoms.

5. The preparation method of claim 1 , wherein the silazane-based surface modifier comprises a silazane-based compound including two or more alkyl groups in a molecule.

6. The preparation method of claim 1 , wherein the silazane-based surface modifier is a compound of Formula 1:

in Formula 1, R 11 each independently represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and R 12 each independently represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms,
wherein at least two functional groups among entire functional groups corresponding to R 11 and R 12 are alkyl groups.

7. The preparation method of claim 1 , wherein the silazane-based surface modifier comprises any one selected from the group consisting of tetraalkyldisilazane and hexaalkyldisilazane or a mixture of two or more thereof, and
the alkyl is an alkyl group having 1 to 4 carbon atoms.

8. The preparation method of claim 1 , wherein the silazane-based surface modifier is used in an amount of 0.6 part by weight to 2 parts by weight based on 1 part by weight of silica included in the sol.

9. The preparation method of claim 1 , wherein the base material for a blanket is any one selected from the group consisting of fibers, a film, a sheet, a net, a textile, a porous body, a foam body, and a non-woven fabric body, or a laminate of two or more thereof.

10. The preparation method of claim 1 , wherein the base material for a blanket comprises at least one selected from the group consisting of glass fibers, polyethylene, and polyester.

11. The preparation method of claim 1 , further comprising at least one process selected from the group consisting of a stabilization process, a pre-aging process, and an aging process of the silica gel-base material composite, after preparing the silica gel-base material composite.

12. The preparation method of claim 11 , wherein the pre-aging process is performed by maintaining the silica gel-base material composite in a temperature of 50° C. to 70° C. for 1 hour to 6 hours.

13. The preparation method of claim 11 , wherein the aging process is performed by maintaining the silica gel-base material composite in a hydrophilic polar organic solvent in a temperature of 50° C. to 80° C.

14. The preparation method of claim 1 , further comprising a step of sequentially performing a pre-aging process in which the silica gel-base material composite is maintained in a temperature of 50° C. to 70° C. for 1 hour to 6 hours, and an aging process in which the pre-aged silica gel-base material composite is maintained in an alcohol-based solvent in a temperature of 50° C. to 80° C.

15. The preparation method of claim 1 , wherein the drying is performed by supercritical drying process or an ambient pressure drying process.

16. The preparation method of claim 15 , wherein the supercritical drying process is performed by using supercritical carbon dioxide.

17. A preparation method of a silica aerogel-containing blanket, the preparation method comprising:
mixing a water glass solution, a linear alcohol having 1 to 4 carbon atoms as a hydrophilic polar organic solvent, and a silazane-based surface modifier including two or more alkyl groups in a molecule to prepare a sol including silica and an alkoxysilane-based compound which is formed by the decomposition reaction of the silazane-based surface modifier and a hydrophilic polar organic solvent;
preparing a silica gel-base material composite by immersion and gelation of a base material for a blanket in the sol;
sequentially performing a pre-aging process in which the silica gel-base material composite is maintained in a temperature of 50° C. to 70° C. for 1 hour to 6 hours, and an aging process in which the pre-aged silica gel-base material composite is maintained in the hydrophilic polar organic solvent in a temperature of 50° C. to 80° C.; and
supercritical drying of the aged silica gel-base material composite.

18. The preparation method of claim 17 , wherein the silazane-based surface modifier is hexamethylyldisilazane, and the alkoxysilane-based compound is trimethylmethoxysilane.

19. The preparation method of claim 1 , wherein the sol is a single-phase sol.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Mi Ri
• Oh Jin Hee
• Oh Kyoung Shil
• Lee Je Kyun

Classifications

• F16L59/02

  Shape or form of insulating materials, with or without coverings integral with the insulating materials · CPC title

• B05D1/18

  performed by dipping · CPC title

• C01P2006/12

  Surface area · CPC title

• C01B33/158

  Purification; Drying; Dehydrating · CPC title

• C01P2006/32

  Thermal properties · CPC title