Bonding adhesive and adhered roofing systems prepared using the same
US-2016340905-A1 · Nov 24, 2016 · US
US10260237B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10260237-B2 |
| Application number | US-201415103497-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 12, 2014 |
| Priority date | Dec 12, 2013 |
| Publication date | Apr 16, 2019 |
| Grant date | Apr 16, 2019 |
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An adhered roofing system comprising a roof substrate, a thermoplastic membrane including at least one layer that includes a functionalized thermoplastic polymer, and an adhesive securing the membrane to the substrate, where the adhesive includes a cured residue of a polymer having a silicon-containing hydrolyzable terminal group.
Opening claim text (preview).
What is claimed is: 1. An adhered roofing system comprising: i. a roof substrate; ii. a thermoplastic membrane including an upper thermoplastic polymer layer and a lower thermoplastic polymer layer, where the lower layer includes from about 3 to about 50 weight percent of a functionalized thermoplastic polyolefin polymer having a polar group, based upon the entire weight of the lower layer, and where the upper layer is devoid of a functionalized thermoplastic polyolefin polymer; and iii. an adhesive securing the membrane to the substrate, where the adhesive includes a cured residue of a polymer having a silicon-containing hydrolyzable terminal group, where the lower layer of the thermoplastic membrane is in direct contact with said adhesive. 2. The roofing system of claim 1 , where the adhered roofing system is a fully-adhered roofing system. 3. The roofing system of claim 1 , where the functionalized thermoplastic polymer is maleated polypropylene. 4. The roofing system of claim 1 , where the functionalized thermoplastic polymer is a maleated propylene-based polymer. 5. The roofing system of claim 1 , where the thermoplastic membrane is a two-layered, laminated membrane. 6. The roofing system of claim 1 , where the thermoplastic membrane is a multi-layered membrane including two or more coextruded layers. 7. The roofing system of claim 1 , where the roof substrate includes an insulation board or a cover board. 8. The roofing system of claim 1 , where the roof substrate includes an existing membrane. 9. The roofing system of claim 1 , where the lower layer that includes a functionalized polymer includes from about 5 to about 25 weight percent of the functionalized polymer, based upon the entire weight of the layer that includes the functionalized polymer. 10. The roofing system of claim 1 , where the lower layer that includes a functionalized polymer includes from about 7 to about 15 weight percent of the functionalized polymer, based upon the entire weight of the layer that includes the functionalized polymer. 11. The roofing system of claim 1 , where the functionalized thermoplastic polymer is a maleated polyolefin. 12. The roofing system of claim 1 , where the polar group is selected from the group consisting of hydroxyl, carbonyl, ether, ester, halide, amine, imine, nitrile, oxirane, and isocyanate groups. 13. The roofing system of claim 1 , where the polar group is selected from carboxylic acid, anhydride, ketone, acid halide, ester, amide, and imide groups, and derivatives thereof. 14. The roofing system of claim 1 , where the functionalized thermoplastic polyolefin polymer includes at least 0.2 weight percent of a pendent polar functional group, based upon the total weight of the functionalized thermoplastic polyolefin polymer. 15. The roofing system of claim 1 , where the membrane further includes a scrim layer disposed between the upper layer and the lower layer. 16. A method for forming an adhered membrane roof system, the method comprising: i. applying a bond adhesive to a substrate on a roof to form an adhesive layer, where the bond adhesive includes a polymer having a silicon-containing hydrolyzable terminal group; and ii. applying a thermoplastic membrane directly to the adhesive layer, where the thermoplastic membrane includes an upper thermoplastic polymer layer and a lower thermoplastic polymer layer, where the lower layer includes from about 3 to about 50 weight percent of a functionalized thermoplastic polyolefin polymer having a polar group, based upon the entire weight of the lower layer, where the upper layer is devoid of a functionalized thermoplastic polyolefin polymer, and where the lower layer is in contact with said adhesive layer. 17. The method of claim 16 , where the substrate is completely covered with the adhesive. 18. The method of claim 16 , where the substrate is partially covered with the adhesive. 19. The method of claim 16 , where the adhesive is applied to the roof substrate in the form of a bead that is from about ¼ in to about 1 in. in diameter or thickness. 20. The method of claim 16 , where the functionalized thermoplastic polymer is maleated polypropylene. 21. The method of claim 16 , where the functionalized thermoplastic polymer is a maleated propylene-based polymer. 22. The method of claim 16 , where the lower layer includes from about 5 to about 25 weight percent of the functionalized thermoplastic polyolefin polymer, based upon the entire weight of the lower layer.
Net structure, e.g. spaced apart filaments bonded at the crossing points · CPC title
characterised by the use of special additives · CPC title
comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title
4 layers · CPC title
3 layers · CPC title
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