High strength glass fiber

Patent metadata

Field	Value
Publication number	US-10259741-B2
Application number	US-201615369900-A
Country	US
Kind code	B2
Filing date	Dec 6, 2016
Priority date	Jul 8, 2016
Publication date	Apr 16, 2019
Grant date	Apr 16, 2019

Abstract

A high strength glass fiber is prepared by following steps: weighing raw materials according to a mass percentage of 50-60% silica sol, 24-31% aluminum sol, 8-11% magnesia, 4-5% calcium oxide, 0.1-2% titanium dioxide, 0-0.5% ferric oxide, 0.5-2% niobium pentoxide, 0.5-1.5% antimony trioxide, 0.3-1.5% bismuth nitrate, and 0.1-0.5% boric acid. Deionized water is added. The raw material undergoes mixing by ball milling, spray-drying, calcining, isostatic pressing, melting, and wire-drawing. The invention adopts silicon sol, aluminum sol and bismuth nitrate. Through ball milling and spray-drying, silicon aluminum barium plasmas is evenly coated on surface of other oxide powders. Then nano particles, of silica, alumina and bismuth oxide are obtained by calcining. Under the effect of the high specific surface energy of nano particles, and the close contact of each component, high strength glass fiber is obtained in relatively low fiber drawing temperature while the glass melting temperature and time are significantly reduced.

First claim

What is claimed is:

1. A method for preparing a glass fiber, comprising steps of:
(1) weighing in a basis of a mass percentage of raw materials, respectively weighing zirconia grinding ball 4-5 times a weight of the raw materials and deionized water 1-2 times the weight of the raw materials, then ball milling the raw materials, the zirconia grinding ball and the deionized water for 12-24 hours and obtaining a mixture, wherein: the mass percentage of the raw materials is as follows:

silica sol
 50-60%;

aluminum sol
 24-31%;

magnesia
  8-11%;

calcium oxide
  4-5%;

titanium dioxide
0.1-2%;

ferric oxide
  0-0.5%;

niobium pentoxide
0.5-2%;

antimony trioxide
0.5-1.5%;

bismuth nitrate
0.3-1.5%; and

boric acid
0.1-0.5%,

wherein a sum of the mass percentage of the raw materials is 100%;
(2) spray-drying the mixture through an atomizer, and obtaining a powder material, wherein: an inlet air temperature of spray-drying is in a range of 180-280° C. and an outlet air temperature thereof is in a range of 30-100° C.;
(3) calcining the powder material at 700-900° C. for 1-3 hours, and then cooling the calcined powder material to a room temperature;
(4) putting the calcined and cooled powder material into a rubber mold, isostatic pressing at 100-300 MPa in a cold isostatic press, and obtaining a compact block;
(5) putting the compact block into a crucible, melting at 1400-1450° C. for 2-3 hours, and obtaining a molten glass fluid; and
(6) decreasing a temperature of the glass fluid to a range of 1250-1300° C., and then performing fiber-drawing through a fiber drawing machine, and finally obtaining a continuous fiber with a size of 5-12 μm, wherein a rotating speed of the fiber drawing machine is in a range of 1000-1400 r/min.

Assignees

• Univ Jiliang China

Inventors

• Xu Shiqing
• Wang Huanping
• Gao Ren
• Zhu Qingong
• Yang Qinghua
• Eckert Hellmut
• Zhang Xianghua

Classifications

• C03B19/09

  by fusing powdered glass in a shaping mould · CPC title

• C03C13/00 Primary

  Fibre or filament compositions (manufacture of fibres or filaments C03B37/00) · CPC title

• C03B1/00

  Preparing the batches (chemical compositions C03C) · CPC title

• C03B37/02

  by drawing or extruding, {e.g. direct drawing of molten glass from nozzles; Cooling fins therefor (C03B37/04 takes precedence; sizing of the fibres C03C25/00)} · CPC title

• C03C1/02

  Pretreated ingredients · CPC title