Reforming device and method for manufacturing chemical products

Patent metadata

Field	Value
Publication number	US-10258960-B2
Application number	US-201615377596-A
Country	US
Kind code	B2
Filing date	Dec 13, 2016
Priority date	Sep 12, 2012
Publication date	Apr 16, 2019
Grant date	Apr 16, 2019

Abstract

A reforming device (10) according to the present invention has a compressor (11), a first heat exchanger (12), a desulfurization device (13), a reformer (14), a raw material gas branching line (L11) that extracts a compressed natural gas (21) from a downstream side of the desulfurization device (13) with respect to the flow direction of the natural gas (21) and supplies the natural gas (21) to the reformer (14), and a flue gas discharging line (L12) that discharges a flue gas (22) generated in the reformer (14), wherein the first heat exchanger (12) is provided in the flue gas discharging line (L12), and the flue gas (22) is used as a heating medium of the compressed natural gas (21).

First claim

The invention claimed is:

1. A reforming method comprising:
supplying a raw material gas containing hydrocarbon and sulfur to a first compression unit through a raw material gas supply line;
compressing the raw material gas in the first compression unit to produce a compressed raw material gas;
desulfurizing sulfur content contained in the compressed raw material gas in a desulfurization unit to produce a compressed natural gas;
extracting a part of the compressed natural gas through a raw material gas branching line;
reforming the hydrocarbon in the unextracted compressed natural gas to generate a reformed gas containing either one or both of H2 and CO or H2 and CO2 in a reforming unit including a burner;
discharging a flue gas which is generated by combustion in the burner through a flue gas discharging line;
heat-exchanging, in a fourth heat exchanger, the compressed raw material gas with the extracted part of the compressed natural gas to produce a heated compressed raw material gas;
heat-exchanging, in a first heat exchanger, the heated compressed raw material gas with the flue gas supplied through the flue gas discharging line as a heating medium;
heat-exchanging, in a third heat exchanger, feed water to be supplied to a steam generation unit with the flue gas after the heat exchange in the first heat exchanger;
heat-exchanging, in a second heat exchanger, combustion air used for the combustion with the flue gas after the heat exchange in the third heat exchanger; and
supplying the extracted part of the compressed natural gas after the heat exchange in the fourth heat exchanger to the burner as a combustion fuel for heating in the reforming unit.

2. The reforming method according to claim 1 ,
wherein ammonia is synthesized using the reformed gas in an ammonia synthesis unit.

3. The device for manufacturing chemical products according to claim 1 ,
wherein urea is synthesized using the reformed gas in a urea synthesis unit.

4. The device for manufacturing chemical products according to claim 1 ,
wherein methanol is synthesized using the reformed gas in a methanol synthesis unit.

Assignees

• Mitsubishi Heavy Ind Ltd
• Mitsubishi Heavy Ind Eng Ltd

Inventors

• Sakurai Mikiya
• Okuzumi Naoya
• Shimura Ryota
• Miyamoto Shuichi
• Seiki Yoshio
• Osora Hiroyuki

Classifications

• Y02P20/129

  Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines · CPC title

• C01B2203/0475

  the impurity being carbon dioxide · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• C01B2203/0816

  Heating by flames · CPC title

• C01B2203/1258

  Pre-treatment of the feed · CPC title