Molecules having pesticidal utility and intermediates, compositions and processes related thereto

Patent metadata

Field	Value
Publication number	US-10258045-B2
Application number	US-201715727878-A
Country	US
Kind code	B2
Filing date	Oct 9, 2017
Priority date	Oct 12, 2016
Publication date	Apr 16, 2019
Grant date	Apr 16, 2019

Abstract

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

First claim

The invention claimed is:

1. A molecule selected from the group consisting of

2. A composition comprising a molecule according to claim 1 and an active ingredient wherein said active ingredient is selected from the group consisting of acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(1R)-trans-isomers], deltamethrin, empenthrin [(EZ)-(1R)-isomers], esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate, halfenprox, imiprothrin, kadethrin, permethrin, phenothrin [(1R)-trans-isomer], prallethrin, pyrethrins (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(1R)-isomers], tralomethrin, and transfluthrin, and methoxychlor.

3. A composition according to claim 1 wherein said active ingredient is bifenthrin.

4. A composition according to claim 1 wherein said active ingredient is lambda-cyhalothrin.

5. A composition according to claim 1 wherein the weight ratio of said molecule to said active ingredient is 3:1 to 1:3.

6. A composition according to claim 3 wherein the weight ratio of said molecule to said active ingredient is 3:1 to 1:3.

7. A composition according to claim 4 , wherein the weight ratio of said molecule to said active ingredient is 3:1 to 1:3.

8. A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a molecule according to claim 1 .

9. A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 2 .

10. A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 3 .

11. A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4 .

12. A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 5 .

13. A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6 .

14. A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 7 .

15. A process according to 8 wherein said pest is selected from the group consisting of ants, aphids, bed bugs, beetles, bristletails, caterpillars, cockroaches, crickets, earwigs, fleas, flies, grasshoppers, grubs, leafhoppers, lice, locusts, maggots, mites, nematodes, planthoppers, psyllids, sawflies, scales, silverfish, slugs, snails, spiders, springtails, stink bugs, symphylans, termites, thrips , ticks, wasps, whiteflies, and wireworms.

16. A process according to 15 wherein said pest are stink bugs.

17. A process according to 9 wherein said pest is selected from the group consisting of Adelges spp., Aulacaspis spp., Aphrophora spp., Aphis spp., Bemisia spp., Ceroplastes spp., Chionaspis spp., Chrysomphalus spp., Coccus spp., Empoasca spp., Euschistus spp., Lepidosaphes spp., Lagynotomus spp., Lygus spp., Macrosiphum spp., Nephotettix spp., Nezara spp., Nilaparvata spp., Philaenus spp., Phytocoris spp., Piezodorus spp., Planococcus spp., Pseudococcus spp., Rhopalosiphum spp., Saissetia spp., Therioaphis spp., Toumeyella spp., Toxoptera spp., Trialeurodes spp., Triatoma spp., and Unaspis spp.

18. A process according to 17 wherein said pest is selected from the group consisting of Acrosternum hilare, Acyrthosiphon pisum, Aleyrodes proletella, Aleurodicus dispersus, Aleurothrixus floccosus, Amrasca biguttula biguttula, Aonidiella aurantii, Aphis fabae, Aphis gossypii, Aphis glycines, Aphis pomi, Aulacorthum solani, Bactericera cockerelli, Bagrada hilaris, Bemisia argentifolii, Bemisia tabaci, Blissus leucopterus, Boisea trivittata, Brachycorynella asparagi, Brevennia rehi, Brevicoryne brassicae, Cacopsylla pyri, Cacopsylla pyricola, Calocoris norvegicus, Ceroplastes rubens, Cimex hemipterus, Cimex lectularius, Coccus pseudomagnoliarum, Dagbertus fasciatus, Dichelops furcatus, Diuraphis noxia, Diaphorina citri, Dysaphis plantaginea, Dysdercus suturellus, Edessa meditabunda, Empoasca vitis, Eriosoma lanigerum, Erythroneura elegantula, Eurygaster maura, Euschistus conspersus, Euschistus heros, Euschistus servus, Halyomorpha halys, Helopeltis antonii, Hyalopterus pruni, Helopeltis antonii, Helopeltis theivora, Icerya purchasi, Idioscopus nitidulus, Jacobiasca formosana, Laodelphax striatellus, Lecanium corni, Leptocorisa oratorius, Leptocorisa varicornis, Lygus hesperus, Maconellicoccus hirsutus, Macrosiphum euphorbiae, Macrosiphum granarium, Macrosiphum rosae, Macrosteles quadrilineatus, Mahanarva frimbiolata, Megacopta cribraria, Metopolophium dirhodum, Mictis longicornis, Myzus persicae, Nasonovia ribisnigri, Nephotettix cincticeps, Neurocolpus longirostris, Nezara viridula, Nilaparvata lugens, Paracoccus marginatus, Paratrioza cockerelli, Parlatoria pergandii, Parlatoria ziziphi, Peregrinus maidis, Phylloxera vitifoliae, Physokermes piceae, Phytocoris californicus, Phytocoris relativus, Piezodorus guildinii, Planococcus citri, Planococcus ficus, Poecilocapsus lineatus, Psallus vaccinicola, Pseudacysta perseae, Pseudococcus brevipes, Quadraspidiotus perniciosus, Rhopalosiphum maidis, Rhopalosiphum padi, Saissetia oleae, Scaptocoris castanea, Schizaphis graminum, Sitobion a venae, Sogatella furcifera, Trialeurodes vaporariorum, Trialeurodes abutiloneus, Unaspis yanonensis , and Zulia entrerriana.

19. A process according to claim 9 wherein said locus soybeans are growing.

Assignees

• Dow Agrosciences Llc

Inventors

• Heemstra Ronald J
• Ross Jr Ronald
• Martin Timothy P
• Vermeulen Nicolaas
• Daeuble Sr John F
• Eckelbarger Joseph D
• Nolan Alex
• Gray Kaitlyn
• Demeter David A
• Hunter Ricky
• Trullinger Tony K

Classifications

• C07D333/38

  Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals · CPC title

• C07C381/00

  Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00 · CPC title

• A01N53/00 Primary

  Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof · CPC title

• C07C311/48

  having nitrogen atoms of sulfonamide groups further bound to another hetero atom · CPC title

• C07C255/46

  to carbon atoms of non-condensed rings · CPC title