Optical layered body, method for producing optical layered body, polarizer and image display device

Patent metadata

Field	Value
Publication number	US-10254446-B2
Application number	US-201614988909-A
Country	US
Kind code	B2
Filing date	Jan 6, 2016
Priority date	May 12, 2010
Publication date	Apr 9, 2019
Grant date	Apr 9, 2019

Abstract

The present invention provides an optical layered body which stably keeps light resistance such as ultraviolet resistance and oxidation resistance while keeping conventional physical properties and optical properties as the outermost surface material of an image display device, which is excellent in an antistatic property and which is capable of providing high image contrast when employed for an image display device. The optical layered body has a light transmitting substrate and a resin layer formed on one surface of the light transmitting substrate and is characterized in that the resin layer contains a binder resin, a polythiophene, an auxiliary conductive agent, and a leveling agent.

First claim

The invention claimed is:

1. An optical layered body having a light transmitting substrate and a resin layer formed on one surface of said light transmitting substrate,
wherein said resin layer comprises a binder resin, a polythiophene, an auxiliary conductive agent, a leveling agent, and an additive having a protonic functional group which carries out a cross-linking reaction,
a rough surface under coat layer is further formed between the light transmitting substrate and the resin layer,
the auxiliary conductive agent is carbon nanotubes,
the resin layer has an antiglare function,
the resin layer having an antiglare function has an uneven surface shape,
the uneven shape of the resin layer satisfies the following expression in which the average interval of the projections and recesses of the resin layer surface is expressed as Sm; the average slanting angle of the uneven part is expressed as θa; the arithmetic mean roughness of the unevenness is expressed as Ra; and the ten point average roughness of the unevenness is expressed as Rz:
50 μm<Sm<600 μm
0.1°<θa<1.50°
0.02 μm<Ra<0.25 μm
0.30 μm<Rz<2.00 μm;
the resin layer is composed of a single layer and has a first region containing no auxiliary conductive agent from the interface on the opposite side to the light transmitting substrate to 100 nm; and
the resin layer further comprises:
(i) a second region wherein the auxiliary conductive agent exists from the interface of the resin layer on the light transmitting substrate side and a third region wherein the polythiophene exists and being located between the first region and the second region, or
(ii) a second region wherein the auxiliary conductive agent exists from the interface of the resin layer on the light transmitting substrate side and a third region wherein the auxiliary conductive agent and polythiophene exist and being located between the first region and the second region.

2. The optical layered body according to claim 1 , wherein the content of the polythiophene is 0.1 to 1.0 part by weight relative to 100 parts by weight of the binder resin.

3. The optical layered body according to claim 1 , wherein the polythiophene is a complex with an anionic compound.

4. The optical layered body according to claim 1 , wherein the auxiliary conductive agent is carbon nanotubes and the content of said auxiliary conductive agent is 0.001 to 0.13 parts by weight relative to 100 parts by weight of the binder resin.

5. The optical layered body according to claim 1 , wherein the initial surface resistance value and the surface resistance value after a light resistance test of the resin layer are less than 1×10 12 Ω/□.

6. The optical layered body according to claim 1 , wherein the additive having a protonic functional group is epoxy acrylate.

7. A polarizer having a polarizing element, wherein said polarizer has the optical layered body according to claim 1 , on a surface of said polarizing element.

8. An image display device having the optical layered body according to claim 1 or the polarizer according to claim 7 on an outermost surface.

9. The optical layered body according to claim 2 , wherein the polythiophene is a complex with an anionic compound.

10. The optical layered body according to claim 2 , wherein the initial surface resistance value and the surface resistance value after a light resistance test of the resin layer are less than 1×10 12 Ω/□.

11. The optical layered body according to claim 3 , wherein the initial surface resistance value and the surface resistance value after a light resistance test of the resin layer are less than 1×10 12 Ω/□.

Assignees

• Dainippon Printing Co Ltd

Inventors

• Eguchi Junya
• Kitamura Tasuku
• Ichikawa Yuki
• Kodama Takashi

Classifications

• Y10T428/24364

  with transparent or protective coating · CPC title

• Y10T428/31533

  Of polythioether · CPC title

• G02B1/11

  Anti-reflection coatings · CPC title

• G02B1/04

  made of organic materials, e.g. plastics (G02B1/08 takes precedence) · CPC title

• G02B5/3025 Primary

  Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state (G02B5/3008, G02B5/3016 take precedence) · CPC title