Method of drying electrode assemblies

Patent metadata

Field	Value
Publication number	US-10254043-B2
Application number	US-201615272504-A
Country	US
Kind code	B2
Filing date	Sep 22, 2016
Priority date	Sep 22, 2016
Publication date	Apr 9, 2019
Grant date	Apr 9, 2019

Abstract

Provided herein is a method of drying an electrode assembly of lithium-ion battery, comprising drying the electrode assembly in two successive stages under vacuum at elevated temperature; filling the oven with hot, dry air or inert gas; repeating the steps of vacuum drying and gas filling several times. The method disclosed herein is particularly suitable for drying electrode assemblies using aqueous binders.

First claim

What is claimed is:

1. A method of drying an electrode assembly, comprising the steps of:
1) stacking at least one anode, at least one cathode, and at least one separator interposed between the at least one anode and at least one cathode to prepare an electrode assembly;
2) placing the electrode assembly in a drying chamber;
3) drying the electrode assembly under vacuum at a temperature from about 50° C. to about 90° C. for a period of time from 5 minutes to 4 hours;
4) further drying the electrode assembly under vacuum at a temperature from about 80° C. to about 155° C.;
5) filling the drying chamber with a dry air or inert gas; and
6) repeating steps 4) and 5) to obtain a dried electrode assembly.

2. The method of claim 1 , wherein the pressure in the drying chamber in step 3) is reduced to less than 25 kPa, less than 15 kPa, less than 10 kPa, or less than 5 kPa.

3. The method of claim 1 , wherein the electrode assembly in step 4) is further dried for a time period from about 15 minute to about 4 hours.

4. The method of claim 1 , wherein the electrode assembly in step 4) is further dried for a time period from about 30 minutes to about 2 hours.

5. The method of claim 1 , wherein the pressure in the drying chamber in step 4) is less than 25 kPa, less than 15 kPa, less than 10 kPa, or less than 5 kPa.

6. The method of claim 1 , wherein the temperature of the dry air or inert gas is from about 70° C. to about 155° C., or from about 80° C. to about 120° C.

7. The method of claim 1 , wherein the dry air or inert gas stays in the drying chamber for a time period from about 5 minute to about 2 hours.

8. The method of claim 1 , wherein the dry air or inert gas stays in the drying chamber for a time period from about 15 minutes to about 30 minutes.

9. The method of claim 1 , wherein the dry air or inert gas restores the drying chamber to atmospheric pressure.

10. The method of claim 1 , wherein steps 4) and 5) are repeated between 2 and 50 times, between 2 and 30 times, or between 2 and 20 times.

11. The method of claim 1 , wherein the at least one cathode comprises a cathode current collector and a cathode electrode layer, wherein the peeling strength between the cathode current collector and the cathode electrode layer is 0.25 N/cm or more.

12. The method of claim 1 , wherein the at least one anode comprises an anode current collector and an anode electrode layer, wherein the peeling strength between the anode current collector and the anode electrode layer is 0.15 N/cm or more.

13. The method of claim 1 , wherein the water content of the dried electrode assembly is less than 20 ppm by weight, based on the total weight of the dried electrode assembly.

14. The method of claim 1 , wherein the at least one anode and at least one cathode in the dried electrode assembly have a water content of less than 20 ppm by weight, based on the total weight of the at least one dried anode and at least one dried cathode.

15. The method of claim 1 , wherein the at least one anode and at least one cathode in the dried electrode assembly have a water content of less than 10 ppm by weight, based on the total weight of the at least one dried anode and at least one dried cathode.

16. The method of claim 1 , wherein the at least one separator in the dried electrode assembly has a water content of less than 20 ppm by weight, based on the total weight of the at least one dried separator.

17. The method of claim 1 , wherein the at least one separator in the dried electrode assembly has a water content of less than 10 ppm by weight, based on the total weight of the at least one dried separator.

18. The method of claim 1 , wherein the at least one separator is made of polymeric fibers selected from the group consisting of polyolefin, polyethylene, high-density polyethylene, linear low-density polyethylene, low-density polyethylene, ultrahigh-molecular-weight polyethylene, polypropylene, polypropylene/polyethylene co-polymer, polybutylene, polypentene, polyacetal, polyamide, polycarbonate, polyimide, polyetherether ketone, polysulfones, polyphenylene oxide, polyphenylene sulfide, polyacrylonitrile, polyvinylidene fluoride, polyoxymethylene, polyvinyl pyrrolidone, polyester, polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalene, polybutylene naphthalate, and combinations thereof.

19. The method of claim 1 , wherein each of the at least one anode and at least one cathode independently comprises a binder material selected from the group consisting of styrene-butadiene rubber, acrylated styrene-butadiene rubber, acrylonitrile copolymer, acrylonitrile-butadiene rubber, nitrile butadiene rubber, acrylonitrile-styrene-butadiene copolymer, acryl rubber, butyl rubber, fluorine rubber, polytetrafluoroethylene, polyethylene, polypropylene, ethylene/propylene copolymers, polybutadiene, polyethylene oxide, chlorosulfonated polyethylene, polyvinylpyrrolidone, polyvinylpyridine, polyvinyl alcohol, polyvinyl acetate, polyepichlorohydrin, polyphosphazene, polyacrylonitrile, polystyrene, latex, acrylic resins, phenolic resins, epoxy resins, carboxymethyl cellulose, hydroxypropyl cellulose, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cyanoethylcellulose, cyanoethylsucrose, polyester, polyamide, polyether, polyimide, polycarboxylate, polycarboxylic acid, polyacrylic acid, polyacrylate, polymethacrylic acid, polymethacrylate, polyacrylamide, polyurethane, fluorinated polymer, chlorinated polymer, a salt of alginic acid, polyvinylidene fluoride, poly(vinylidene fluoride)-hexafluoropropene, and combinations thereof.

Assignees

• Grst Int Ltd

Inventors

• Ho Kam Piu
• Wang Ranshi
• Shen Peihua

Classifications

• F26B5/042 Primary

  for drying articles or discrete batches of material in a continuous or semi-continuous operation, e.g. with locks or other air tight arrangements for charging/discharging · CPC title

• H01M4/623

  fluorinated polymers · CPC title

• F26B25/00

  Details of general application not covered by group F26B21/00 or F26B23/00 (loading, conveying, and unloading in general B65G) · CPC title

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M4/622

  being polymers · CPC title