Breaker and displacement fluid

Patent metadata

Field	Value
Publication number	US-10253242-B2
Application number	US-201615352163-A
Country	US
Kind code	B2
Filing date	Nov 15, 2016
Priority date	Jun 30, 2010
Publication date	Apr 9, 2019
Grant date	Apr 9, 2019

Abstract

A breaker fluid for breaking a filtercake in a wellbore. The fluid including a hydrolysable ester of carboxylic acid, and a chelant, an alkyl glycoside, or a combination thereof. The breaker fluid may be pre-mixed and include an amount of water less than required to completely hydrolyze the ester.

First claim

What is claimed:

1. A breaker fluid comprising:
a hydrolysable ester of carboxylic acid;
a chelant; and
an amount of water wherein the weight ratio of water to hydrolysable ester of carboxylic acid is less than 1.3 to 1, wherein the hydrolysable ester of carboxylic acid, the chelant, and the water are pre-mixed prior to circulating in a wellbore.

2. The breaker fluid of claim 1 wherein the hydrolysable ester of carboxylic acid is a formic acid ester of a C2 to C30 alcohol.

3. The breaker fluid of claim 1 wherein the hydrolysable ester of carboxylic acid comprises ethanediol monoformate.

4. The breaker fluid of claim 1 wherein the chelant comprises one or more chelants selected from a group consisting of: ethylenediaminetetraacetic acid; glutamic acid, N, N-diacetic acid; and salts thereof.

5. The breaker fluid of claim 1 wherein the chelant comprises at least one iminodiacetic acid or a salt thereof, represented by the formula

wherein the M groups each independently represents a hydrogen atom, an alkali metal atom, an ammonium group or a substituted ammonium group; Y represents a divalent alkyl group having from 1 to 7 carbon atoms and the divalent alkyl group may be substituted by a hydroxyl group or a COOM group wherein M represents a hydrogen atom, an alkali metal atom, an ammonium group or a substituted ammonium group; and W represents a hydrogen atom, a hydroxyl group or a COOM group wherein M represents a hydrogen atom, an alkali metal atom, an ammonium group or a substituted ammonium group.

6. The breaker fluid of claim 1 wherein the breaker fluid comprises 0 wt %-10 wt % water.

7. The breaker fluid of claim 1 further comprising an alkyl glycoside.

8. A breaker base fluid comprising:
a formic acid ester of a C2 to C30 alcohol;
one or more chelants selected from a group consisting of: ethylenediaminetetraacetic acid; glutamic acid; N, N-diacetic acid; and salts thereof; and
an amount of water where the weight ratio of water to hydrolysable ester of carboxylic acid is less than 1.3 to 1.

9. The breaker fluid of claim 8 comprising 5-35 wt % chelants.

10. The breaker fluid of claim 8 comprising 0 wt %-10 wt % water.

Assignees

• Mi Llc

Inventors

• Luyster Mark R
• Moore Latosha
• Jones Andrew G K

Classifications

• C09K8/52 Primary

  Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning · CPC title

• E21B37/00

  Methods or apparatus for cleaning boreholes or wells (E21B21/00 takes precedence) · CPC title

• C09K8/86

  containing organic compounds · CPC title

• C09K2208/32

  Anticorrosion additives · CPC title

• E21B37/06

  using chemical means for preventing or limiting {, e.g. eliminating,} the deposition of paraffins or like substances · CPC title