Preparing method of polyolefin resin mono chip and polyolefin resin mono chip

Patent metadata

Field	Value
Publication number	US-10253167-B2
Application number	US-201615140627-A
Country	US
Kind code	B2
Filing date	Apr 28, 2016
Priority date	May 7, 2015
Publication date	Apr 9, 2019
Grant date	Apr 9, 2019

Abstract

The present invention relates to a preparing method of a polyolefin resin mono chip including: forming a thermoplastic resin composite by impregnating a fiber reinforcing agent having a length of 5 mm to 20 mm into a molten mixture including a propylene homopolymer of which a molecular weight distribution Is 3 to 6, and a colorant, wherein a cooling speed at room temperature of the thermoplastic resin composite is 19° C./min or more. In addition, the present invention relates to a polyolefin resin mono chip including: a thermoplastic resin composite including a polymer substrate including a propylene homopolymer of which a molecular weight distribution is 3 to 6, and a colorant; and a fiber reinforcing agent having a length of 5 mm to 20 mm and impregnated into the polymer substrate, wherein an impact strength measured according to ASTM D256 is 200 J/m or more.

First claim

What is claimed is:

1. A polyolefin resin mono chip comprising:
a thermoplastic resin composite including a polymer substrate including a propylene homopolymer of which a molecular weight distribution is 3 to 6, an olefin block copolymer including ethylene-based repeating units and C4-C30 α-olefin-based repeating units and a colorant; and a fiber reinforcing agent having a length of 5 mm to 20 mm and impregnated into the polymer substrate,
wherein an impact strength measured according to ASTM D256 is 200 J/m or more,
wherein a content of the propylene homopolymer is 40 wt % to 70 wt %, and a content of the olefin block copolymer is 0.1 wt % to 40 wt % based on a weight of the polyolefin resin mono chip, and a content of the fiber reinforcing agent relative to the polyolefin resin mono chip is 16 wt % to 30 wt %, and
wherein a melt index of the olefin block copolymer (measured according to ASTM D1238 at 230° C. and a load of 2.16 kg) is 2 g/10 min to 20 g/10 min.

2. The polyolefin resin mono chip of claim 1 , wherein:
a melt index of the propylene homopolymer (measured according to ASTM D1238 at 230° C. and a load of 2.16 kg) is 28 g/10 min to 50 g/10 min.

3. The polyolefin resin mono chip of claim 1 , wherein:
a weight ratio of the fiber reinforcing agent and the propylene homopolymer is 1:1.5 to 1:10.

4. The polyolefin resin mono chip of claim 1 , wherein:
a weight ratio of the colorant and the fiber reinforcing agent is 1:1 to 1:50.

5. The polyolefin resin mono chip of claim 1 , wherein:
the polymer substrate further includes at least one additive selected from the group consisting of impact modifiers, inorganic fillers, UV filters, antioxidants, lubricants, antistatic agents, compatibilizers, and fine particles.

6. The polyolefin resin mono chip of claim 1 , wherein:
a weight average molecular weight of the olefin block copolymer is 50,000 g/mol to 180,000 g/mol.

7. The polyolefin resin mono chip of claim 1 , wherein:
a length of the polyolefin resin mono chip is 1 mm to 500 mm, and a cross-sectional diameter of the polyolefin resin mono chip is 0.1 mm to 50 mm.

8. The polyolefin resin mono chip of claim 1 , wherein:
a specific gravity measured according to ASTM D792 is 0.8 to 1.2.

9. The polyolefin resin mono chip of claim 1 , wherein:
a tensile strength measured according to ASTM D638 is 50 MPa or more.

10. The polyolefin resin mono chip of claim 1 , wherein:
a cooling speed at room temperature of the thermoplastic resin composite obtained by Equation (1) below is 19° C./min or more:
Cooling speed(° C./min)=( T c1 −T c2 )/( t c2 −t c1 )  [Equation 1]

in Equation 1 above,
T c1 is a temperature at which crystallization starts, measured by DSC,
T c2 is a temperature at a time point at which the crystallization has been completed, measured by DSC,
t c1 is a time at which the crystallization starts, measured by DSC, and
t c2 is a time at which the crystallization has been completed, measured by DSC.

11. The polyolefin resin mono chip of claim 1 , wherein:
the polyolefin resin mono chip is used for interior and exterior components for automobiles.

12. A preparing method of a polyolefin resin mono chip comprising:
forming a thermoplastic resin composite by impregnating a fiber reinforcing agent having a length of 5 mm to 20 mm into a molten mixture including a propylene homopolymer of which a molecular weight distribution is 3 to 6, and a colorant,
wherein a cooling speed at room temperature of the thermoplastic resin composite obtained by Equation (1) below is 19° C./min or more,
Cooling speed(° C./min)=( T c1 −T c2 )/( t c2 −t c1 )  [Equation 1]

in Equation 1 above,
T c1 is a temperature at which crystallization starts, measured by DSC,
T c2 is a temperature at a time point at which the crystallization has been completed, measured by DSC,
t c1 is a time at which the crystallization starts, measured by DSC, and
t c2 is a time at which the crystallization has been completed, measured by DSC.

13. The preparing method of claim 12 , further comprising: pelletizing the thermoplastic resin composite.

Assignees

• Lotte Chemical Corp

Inventors

• Jang Eun Hwa
• Cho Seong-Min
• Kim Young-Bum
• Moon Byeong Kyu

Classifications

• B29B9/06

  in the form of filamentary material, e.g. combined with extrusion · CPC title

• B29B9/14

  fibre-reinforced · CPC title

• C08K3/04

  Carbon · CPC title

• C08J3/201

  Pre-melted polymers · CPC title

• C08J3/12

  Powdering or granulating · CPC title