Composition including silane-grafted polyolefin

Patent metadata

Field	Value
Publication number	US-10253127-B2
Application number	US-201815978919-A
Country	US
Kind code	B2
Filing date	May 14, 2018
Priority date	Jun 14, 2013
Publication date	Apr 9, 2019
Grant date	Apr 9, 2019

Abstract

A silane-grafted polyolefin composition is disclosed, and includes a desired reduced specific weight material. The composition finds application in a wide array of uses, and in particular automotive and uses such as weatherstrips, where this composition is used in place of conventional materials such as TPV and EPDM rubber formulations.

First claim

The invention claimed is:

1. A weatherstrip consisting essentially of a weatherstrip composition, the weatherstrip composition consisting of:
a silane-grafted polyolefin having a density of from about 0.84 g/cm 3 to about 0.96 g/cm 3 ; and
one or more additives selected from the group consisting of polypropylenes, thermoplastic vulcanates (TPV), olefinic block copolymers, ethylene propylene diene terpolymers (EPDM), ethylene vinyl acetate (EVA) copolymers, ethylene n-butyl acrylate copolymers, and ethylene methacrylate copolymers;
wherein the polyolefin is selected from the group consisting of a blend of propylene/α-olefin copolymer with an ethylene/α-olefin copolymer, and a propylene/α-olefin copolymer.

2. A method for manufacturing a weatherstrip, comprising:
grafting silanes to a polyolefin to form a silane-grafted polyolefin;
extruding a composition comprising the silane-grafted polyolefin having a density of from about 0.84 g/cm 3 to about 0.96 g/cm 3 , a condensation catalyst, and optionally one or more fillers selected from the group consisting of polypropylenes, thermoplastic vulcanates (TPV), ethylene propylene diene terpolymers (EPDM), ethylene vinyl acetate (EVA) copolymers, ethylene n-butyl acrylate copolymers, and ethylene methacrylate copolymers; and
molding the extruded composition into the weatherstrip;
wherein the polyolefin is selected from the group consisting of a blend of propylene/α-olefin copolymer with an ethylene/α-olefin copolymer, and a propylene/α-olefin copolymer.

3. The method of claim 2 , wherein the grafting is performed in a melt.

4. The method of claim 2 , wherein the grafting is performed in solution.

5. The method of claim 2 , wherein the grafting is performed in a solid-state.

6. The method of claim 2 , wherein the grafting is performed in a swollen-state.

7. The method of claim 2 , wherein the composition further comprises:
one or more fillers selected from the group consisting of antistatic agents, dyes, pigments, UV light absorbers, nucleating agents, fillers, slip agents, plasticizers, fire retardants, lubricants, processing aides, smoke inhibitors, anti-blocking agents, and viscosity control agents.

8. The method of claim 2 , wherein the weatherstrip is selected from the group consisting of a static seal, a dynamic seal, a sunroof seal, a mirror seal, body-panel interface seal, a stationary window molding, a cut-line seal, a rocker seal, a margin seal, an edge protector seal, and combinations thereof.

9. The method of claim 2 , wherein the weatherstrip is a static seal.

10. The method of claim 2 , wherein the weatherstrip is a dynamic seal.

11. The method of claim 2 , wherein the weatherstrip is a sunroof seal.

12. A weatherstrip comprising:
a weatherstrip composition that comprises:
a silane-grafted polyolefin having a density of from about 0.84 g/cm 3 to about 0.96 g/cm 3 ,
wherein the polyolefin is a blend of propylene/α-olefin copolymer and an ethylene/α-olefin copolymer.

13. The weatherstrip of claim 12 , wherein the weatherstrip further comprises:
one or more additives selected from the group consisting of polypropylenes, thermoplastic vulcanates (TPV), ethylene propylene diene terpolymers (EPDM), ethylene vinyl acetate (EVA) copolymers, ethylene n-butyl acrylate copolymers, and ethylene methacrylate copolymers.

14. The weatherstrip of claim 12 , wherein the weatherstrip further comprises:
one or more additives selected from the group consisting of antistatic agents, dyes, pigments, UV light absorbers, nucleating agents, fillers, slip agents, plasticizers, fire retardants, lubricants, processing aides, smoke inhibitors, anti-blocking agents, and viscosity control agents.

15. The weatherstrip of claim 12 , wherein the weatherstrip further comprises:
one or more fillers selected from the group consisting of metal oxides, metal hydroxides, metal carbonates, metal sulfates, metal silicates, clays, talcs, carbon black, and silicas.

16. The weatherstrip of claim 15 wherein the one or more fillers are present in an amount from about 1 wt % to about 20 wt %.

17. The weatherstrip of claim 12 , wherein the weatherstrip further comprises:
one or more tackifying resins selected from the group consisting of aliphatic hydrocarbons, aromatic hydrocarbons, modified hydrocarbons, terpenes, modified terpenes, hydrogenated terpenes, rosins, hydrogenated rosins, and combinations thereof.

18. The weatherstrip of claim 12 , wherein the weatherstrip is selected from the group consisting of a static seal, a dynamic seal, a sunroof seal, a mirror seal, body-panel interface seal, a stationary window molding, a cut-line seal, a rocker seal, a margin seal, an edge protector seal, and combinations thereof.

19. The weatherstrip of claim 12 , wherein the weatherstrip is a static seal.

20. The weatherstrip of claim 12 , wherein the weatherstrip is a dynamic seal.

Assignees

• Cooper Standard Automotive Inc

Inventors

• Gopalan Krishnamachari
• Lenhart Robert J
• Ji Gending

Classifications

• C08F255/00 Primary

  Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 · CPC title

• C08F255/04 Primary

  on to ethylene-propylene copolymers {(C08F255/023 takes precedence)} · CPC title

• C08F230/085

  the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes · CPC title

• B60J10/17

  provided with a low-friction material on the surface · CPC title

• B60J10/16

  consisting of two or more plastic materials having different physical or chemical properties (B60J10/17 takes precedence) · CPC title