Ultraviolet-light-emitting device with adhesive having low glass transition temperature

Patent metadata

Field	Value
Publication number	US-10246615-B2
Application number	US-201715401772-A
Country	US
Kind code	B2
Filing date	Jan 9, 2017
Priority date	Jul 15, 2014
Publication date	Apr 2, 2019
Grant date	Apr 2, 2019

Abstract

Provided is an adhesive for use in an ultraviolet-light-emitting device using ultraviolet light having a wavelength of from 200 to 400 nm as a light source, which can attach adherends made of a polymer having a fluorine-containing alicyclic structure with excellent adhesiveness which is unlikely to be impaired by exposure to such ultraviolet light or heat.
An adhesive for forming an adhesive joint in an ultraviolet-light-emitting device, which is either the following adhesive (A) or the following adhesive (B) comprising a fluoropolymer having a fluorine-containing alicyclic structure:
the adhesive (A): an adhesive in which the glass transition temperature of the fluoropolymer is from 30 to 100° C., and which does not contain an ultraviolet-shielding agent; and the adhesive (B): an adhesive comprising the fluoropolymer and an ultraviolet-shielding agent.

First claim

What is claimed is:

1. An adhesive for forming an adhesive joint in an ultraviolet-light-emitting device, which is either the following adhesive (A) or the following adhesive (B) comprising a fluoropolymer having a fluorine-containing alicyclic structure:
wherein:
the ultraviolet-light-emitting device comprises a light-emitting element generating ultraviolet light having a wavelength of from 200 to 400 nm, an optical member which transmits the ultraviolet light generated by the light-emitting element and the adhesive joint formed from the adhesive between the light-emitting element and the optical member, wherein the optical member is made of a fluoropolymer having a fluorine-containing alicyclic structure;
the adhesive (A) is an adhesive in which the glass transition temperature of the fluoropolymer is from 30 to 100° C., and which does not comprise an ultraviolet-shielding agent; and
the adhesive (B) is an adhesive comprising the fluoropolymer and an ultraviolet-shielding agent.

2. The adhesive according to claim 1 , which is the adhesive (B), wherein the glass transition temperature of the fluoropolymer in the adhesive (B) is from 30 to 100° C.

3. The adhesive according to claim 1 , which is the adhesive (B), wherein the adhesive (B) comprises the ultraviolet-shielding agent in an amount of from 0.1 to 20 mass % based on the fluoropolymer.

4. The adhesive according to claim 1 , wherein the ultraviolet-shielding agent comprises at least one kind selected from the group consisting of inorganic particles and organic particles.

5. The adhesive according to claim 1 , wherein the fluoropolymer has a reactive functional group in a side chain or at the end of the main chain and has no hydrogen atoms bonded to a carbon atom anywhere other than the reactive functional group.

6. The adhesive according to claim 1 , wherein the glass transition temperature of the fluoropolymer in the optical member is equal to or higher than the glass transition temperature of the fluoropolymer in the adhesive.

7. The adhesive according to claim 1 , wherein the glass transition temperature of the fluoropolymer in the optical member is 100 to 180° C.

8. The adhesive according to claim 1 , wherein the fluoropolymer having the fluorine-containing alicyclic structure has units (a) having the fluorine-containing alicyclic structure.

9. The adhesive according to claim 8 , wherein at least one of the ring-constituting carbon atoms in the fluorine-containing alicyclic ring is in the polymer main chain.

10. The adhesive according to claim 8 , wherein the units (a) have no hydrogen atoms bonded to a carbon atom.

11. The adhesive according to claim 8 , wherein the unit (a) is formed by cyclization polymerization of a fluorine-containing diene monomer.

12. The adhesive according to claim 8 , wherein the fluoropolymer having a glass transition temperature of from 30 to 100° C. comprises the units (a) and units (b) represented by the following formula (b), and the total content of the unit (a) and the units (b) is from 50 to 100 mol % based on the total of all units:

(wherein R f is a perfluoroalkylene group which may have an ethereal oxygen atom, X is COOH, COOR, SO 2 F, SO 3 R or SO 3 H, and R is a C 1-5 alkyl) group.

13. The ultraviolet-light-emitting device comprising the light-emitting element generating ultraviolet light having the wavelength of from 200 to 400 nm and the optical member which transmits ultraviolet light having the wavelength of from 200 to 400 nm, wherein the light-emitting element and the optical member are bonded together by the adhesive joint formed from the adhesive according to claim 1 .

Assignees

• Agc Inc

Inventors

• Nakayama Fumiko
• Sakane Yoshihiko
• Ito Masahiro
• Hatanaka Yuki
• Koyanagi Atsushi

Classifications

• C08F216/14

  Monomers containing only one unsaturated aliphatic radical · CPC title

• C09J127/12 Primary

  containing fluorine atoms · CPC title

• C09J11/04

  inorganic · CPC title

• C09J11/08

  Macromolecular additives · CPC title

• C09J11/06

  organic · CPC title