Highly active decomposition catalyst for low carbon hydrocarbon production from sulfur containing fuel

Patent metadata

Field	Value
Publication number	US-10245580-B2
Application number	US-201213584180-A
Country	US
Kind code	B2
Filing date	Aug 13, 2012
Priority date	Aug 11, 2011
Publication date	Apr 2, 2019
Grant date	Apr 2, 2019

Abstract

Methods for deriving a low-C hydrocarbon fuel from a high-C hydrocarbon fuel are generally provided. A catalytic material (e.g., an aluminosilicate and/or a zeolite) can be introduced to the high-C hydrocarbon fuel to produce a product stream comprising a low-C hydrocarbon fuel, and the low-C hydrocarbon fuel can be separated in the product stream from any remaining high-C hydrocarbon fuel.

First claim

What is claimed:

1. A method for deriving a low-C hydrocarbon fuel from a sulfur containing, high-C hydrocarbon fuel, the method comprising:
introducing a catalytic material to the sulfur containing, high-C hydrocarbon fuel, upon which a reaction occurs, to produce a product stream comprising a low-C hydrocarbon fuel, wherein the catalytic material comprises a zeolite comprising ion exchanged Pt, wherein the ion exchanged Pt is included in the catalytic material in a weight percent of about 0.1% to about 10% of the total weight of the catalytic material, and wherein the sulfur containing, high-C hydrocarbon fuel comprises about 200 ppm to about 3000 ppm sulfur; and
separating the low-C hydrocarbon fuel in the product stream from any remaining sulfur containing, high-C hydrocarbon fuel, and wherein the low-C hydrocarbon fuel has a sulfur content that is less than 100 ppm, wherein the low-C hydrocarbon fuel is separated from any remaining sulfur containing, high-C hydrocarbon fuel in the product stream through a condensation process.

2. The method as in claim 1 , further comprising:
heating the catalytic material and the sulfur containing, high-C hydrocarbon fuel to a reaction temperature of between about 300° C. and about 700° C. to produce the product stream.

3. The method as in claim 1 , wherein the low-C hydrocarbon fuel is produced from the sulfur containing, high-C hydrocarbon fuel in a reactor that includes the catalytic material.

4. The method as in claim 3 , wherein the sulfur containing, high-C hydrocarbon fuel is introduced into the reactor as a continuous inflow stream.

5. The method as in claim 3 , wherein a continuous outflow of the product stream exits the reactor.

6. The method as in claim 1 , wherein the condensation process comprises:
cooling the product stream to a condensation temperature where any remaining sulfur containing, high-C hydrocarbon fuel liquefies while the low-C hydrocarbon fuel remains gaseous; and
collecting the low-C hydrocarbon fuel.

7. The method as in claim 6 , wherein the condensation temperature is about 0° C. to about 10° C.

8. The method as in claim 1 , wherein the catalytic material comprises an aluminosilicate material with mordenite framework inverted structure.

9. The method as in claim 1 , wherein the catalytic material comprises an aluminosilicate material having silica to alumina molar ratio of from 20 to 200.

10. The method as in claim 1 , wherein the catalytic material further comprises a metal selected from the group consisting of Al, Ce, Cu, Eu, Fe, Gd, In, Ir, La, Na, Nd, Ni, Pd, Pr, Rh, Ru, Sm, Zn, Zr, and mixtures thereof.

11. The method as in claim 10 , wherein the metal is included in the catalytic material in a weight percent of about 0.1% to about 10% of the total weight of the catalytic material.

12. The method as in claim 10 , wherein the metal is included in the catalytic material in a weight percent of about 0.5% to about 5% of the total weight of the catalytic material.

13. The method as in claim 1 , wherein the reaction occurs at a reaction pressure of from about 100 mmHg to 760 mmHg.

14. The method as in claim 1 , wherein the reaction occurs at atmospheric pressure.

15. The method as in claim 1 , wherein any sulfur-containing molecules are separated from the low-C hydrocarbon fuel in the product stream.

16. The method as in claim 1 , wherein the low-C hydrocarbon fuel has a sulfur content that is less than 50 ppm.

17. The method as in claim 1 , wherein the zeolite further comprises Gd.

18. The method as in claim 1 , wherein the ion exchanged Pt is included in the catalytic material in weight percent of about 0.5% to about 5% of the total weight of the catalytic material.

Assignees

• Lauterbach Jochen
• Glascock Mary
• Bedenbaugh John
• Chien Chang Yin
• Jangam Ashok
• Salim Shahriar
• Kim Sungtak
• Tilburg Robin
• Univ South Carolina

Inventors

• Lauterbach Jochen
• Glascock Mary
• Bedenbaugh John
• Chien Chang-Yin
• Jangam Ashok
• Salim Shahriar
• Kim Sungtak
• Tilburg Robin

Classifications

• C07C4/02

  by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction · CPC title

• C07C4/06

  Catalytic processes {(C07C4/025 takes precedence)} · CPC title

• B01J29/18

  of the mordenite type · CPC title

• B01J29/405

  containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead · CPC title

• B01J29/06 Primary

  Crystalline aluminosilicate zeolites; Isomorphous compounds thereof · CPC title