Anode for lithium metal battery, and electrochemical device comprising same
US-12176528-B2 · Dec 24, 2024 · US
US10243216B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10243216-B2 |
| Application number | US-201615306230-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 7, 2016 |
| Priority date | Jul 24, 2015 |
| Publication date | Mar 26, 2019 |
| Grant date | Mar 26, 2019 |
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An electrolytic copper foil for a lithium secondary battery, wherein a curl indicator C of the electrolytic copper foil, which is defined as 1.21ΔR+1.12ΔCr+0.01ΔG, is 0 or above and 4.0 or below, where ΔR corresponds to an absolute value of a difference between roughness measured on a first surface of the electrolytic copper foil for a lithium secondary battery and roughness measured on a second surface thereof, ΔCr corresponds to an absolute value of a difference between a chrome-deposited amount of an anti-corrosion layer formed on the first surface of the electrolytic copper foil for a lithium secondary battery and a chrome-deposited amount of an anti-corrosion layer formed on the second surface, and ΔG corresponds to an absolute value of a difference between glossiness measured on the first surface of the electrolytic copper foil for a lithium secondary battery and glossiness measured on the second surface.
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What is claimed is: 1. An electrolytic copper foil for a lithium secondary battery, wherein a curl indicator C of the electrolytic copper foil, which is defined as 1.21ΔR+1.12ΔCr+0.01ΔG, is 0 or above and 4.0 or below, wherein the ΔR corresponds to an absolute value of a difference between roughness (Rz) (μm) of a first surface of the electrolytic copper foil for a lithium secondary battery and roughness (Rz) (μm) of a second surface thereof, wherein the ΔCr corresponds to an absolute value of a difference between a chrome-deposited amount (mg/m 2 ) of an anti-corrosion layer formed on the first surface of the electrolytic copper foil for a lithium secondary battery and a chrome-deposited amount (mg/m 2 ) of an anti-corrosion layer formed on the second surface, and wherein the ΔG corresponds to an absolute value of a difference between glossiness (GU) of the first surface of the electrolytic copper foil for a lithium secondary battery and glossiness (GU) of the second surface, the glossinesses of the first and second surfaces measured with an incident angle of 60 degrees. 2. The electrolytic copper foil for a lithium secondary battery according to claim 1 , wherein surface roughness measured at the first surface and the second surface of the electrolytic copper foil for a lithium secondary battery is respectively 0.2 μm to 2.5 μm. 3. The electrolytic copper foil for a lithium secondary battery according to claim 1 , wherein the chrome-deposited amount of the anti-corrosion layer formed on the first surface and the second surface of the electrolytic copper foil for a lithium secondary battery is respectively 1.0 mg/m 2 or above and 4.5 mg/m 2 or below. 4. The electrolytic copper foil for a lithium secondary battery according to claim 1 , wherein the glossiness measured at the first surface and the second surface of the electrolytic copper foil for a lithium secondary battery is respectively 10 GU to 450 GU. 5. The electrolytic copper foil for a lithium secondary battery according to claim 1 , wherein the ΔR is 0 μm or above and 2.0 μm or below. 6. The electrolytic copper foil for a lithium secondary battery according to claim 1 , wherein the ΔCr is 0 mg/m 2 or above and 3.5 mg/m 2 or below. 7. The electrolytic copper foil for a lithium secondary battery according to claim 1 , wherein the ΔG is 0 GU or above and 350 GU or below. 8. The electrolytic copper foil for a lithium secondary battery according to claim 5 , wherein the ΔG is 0 GU or above and 350 GU or below. 9. The electrolytic copper foil for a lithium secondary battery according to claim 8 , wherein the ΔCr is 0 mg/m 2 or above and 3.5 mg/m 2 or below. 10. The electrolytic copper foil for a lithium secondary battery according to claim 5 , wherein the ΔCr is 0 mg/m 2 or above and 3.5 mg/m 2 or below. 11. The electrolytic copper foil for a lithium secondary battery according to claim 7 , wherein the ΔCr is 0 mg/m 2 or above and 3.5 mg/m 2 or below. 12. The electrolytic copper foil for a lithium secondary battery according to claim 1 , wherein the electrolytic copper foil for a lithium secondary battery has a thickness of 4 μm to 35 μm. 13. A lithium secondary battery, to which the electrolytic copper foil for a lithium secondary battery according to claim 1 is applied as a negative electrode current collector.
Selection of materials · CPC title
Inhibitors, e.g. gassing inhibitors, corrosion inhibitors · CPC title
Li-accumulators · CPC title
Electrodes based on metals, Si or alloys · CPC title
in the form of layers, e.g. coatings · CPC title
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