N-Doped Semiconducting Material Comprising Phosphine Oxide Matrix and Metal Dopant
US-2016322568-A1 · Nov 3, 2016 · US
US10243158B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10243158-B2 |
| Application number | US-201715717406-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 27, 2017 |
| Priority date | Sep 9, 2015 |
| Publication date | Mar 26, 2019 |
| Grant date | Mar 26, 2019 |
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An organic light emitting display device and a light apparatus for vehicles using the same are provided. The organic light emitting display device includes a first layer on a first electrode, a second layer on the first layer, a second electrode on the second layer, and an N-type charge generation layer between the first layer and the second layer. The first layer includes a first emission layer and a first electron transport layer, and the second layer includes a second emission layer and a second electron transport layer. A low unoccupied molecular orbitals (LUMO) level of the first electron transport layer is higher than a LUMO level of a host included in the N-type charge generation layer.
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What is claimed is: 1. An organic light emitting display device, comprising: a first electrode and a second electrode; a first emission layer and a second emission layer between the first electrode and the second electrode; a charge generation layer on the first emission layer; and an electron transport layer between the first emission layer and the charge generation layer, wherein a low unoccupied molecular orbitals (LUMO) level of the electron transport layer is higher than a LUMO level of a host in the charge generation layer. 2. The organic light emitting display device of claim 1 , wherein a difference between the LUMO level of the electron transport layer and the LUMO level of the host in the charge generation layer is greater than 0.2 eV. 3. The organic light emitting display device of claim 1 , wherein a difference between the LUMO level of the electron transport layer and the LUMO level of the host in the charge generation layer is 0.4 eV or more. 4. The organic light emitting display device of claim 1 , wherein a thickness of the electron transport layer is 5 nm to 30 nm, and the electron transport layer comprises one material or the electron transport layer is formed by co-depositing at least two materials. 5. The organic light emitting display device of claim 1 , wherein the host of the charge generation layer is doped with at least one material among lithium (Li), sodium (Na), potassium (K), cesium (Cs), magnesium (Mg), strontium (Sr), barium (Ba), radium (Ra), Liq, and an N-type dopant. 6. The organic light emitting display device of claim 1 , wherein one among the first electrode and the second electrode comprises one among a transmissive electrode and a reflective electrode. 7. The organic light emitting display device of claim 1 , wherein the first emission layer and the second emission layer emit lights having a same color. 8. The organic light emitting display device of claim 1 , further comprising at least one of a hole injection layer and a hole transport layer on the first electrode. 9. The organic light emitting display device of claim 1 , further comprising a p-type hole injection layer on the charge generation layer. 10. An organic light emitting display device, comprising: a first layer on a first electrode, the first layer including a first emission layer and a first electron transport layer; a second layer on the first layer; a second electrode on the second layer; and an N-type charge generation layer between the first layer and the second layer, wherein a low unoccupied molecular orbitals (LUMO) level of the first electron transport layer is higher than a LUMO level of a host in the N-type charge generation layer. 11. The organic light emitting display device of claim 10 , wherein a difference between the LUMO level of the first electron transport layer and the LUMO level of the host in the N-type charge generation layer is greater than 0.2 eV. 12. The organic light emitting display device of claim 10 , wherein a difference between the LUMO level of the first electron transport layer and the LUMO level of the host in the N-type charge generation layer is 0.4 eV or more. 13. The organic light emitting display device of claim 10 , wherein the host of the charge generation layer is doped with at least one material among lithium (Li), sodium (Na), potassium (K), cesium (Cs), magnesium (Mg), strontium (Sr), barium (Ba), radium (Ra), Liq, and an N-type dopant. 14. A lighting apparatus for vehicles, comprising: an organic light emitting device including an emission layer, an electron transport layer, and a charge generation layer between an anode and a cathode, wherein a low unoccupied molecular orbitals (LUMO) level of the electron transport layer is higher than a LUMO level of a host in the charge generation layer. 15. The lighting apparatus of claim 14 , wherein the charge generation layer comprises an N-type charge generation layer. 16. The lighting apparatus of claim 14 , wherein a difference between the LUMO level of the electron transport layer and the LUMO level of the host in the charge generation layer is greater than 0.2 eV. 17. The lighting apparatus of claim 14 , wherein a difference between the LUMO level of the electron transport layer and the LUMO level of the host in the charge generation layer is 0.4 eV or more. 18. The lighting apparatus of claim 14 , wherein the host of the charge generation layer is doped with at least one material among lithium (Li), sodium (Na), potassium (K), cesium (Cs), magnesium (Mg), strontium (Sr), barium (Ba), radium (Ra), Liq, and an N-type dopant. 19. The lighting apparatus of claim 14 , wherein one among the anode and the cathode comprises one among a transmissive electrode and a reflective electrode. 20. The lighting apparatus of claim 14 , wherein a temperature range of the organic light emitting device is 25° C. to 105° C. 21. The lighting apparatus of claim 14 , wherein the emission layer includes at least one emission layer, and the at least one emission layer emits lights having a same color. 22. The lighting apparatus of claim 14 , wherein the charge generation layer is disposed on the electron transport layer.
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