High-temperature high-entropy alloy with light weight and high strength in as-cast state and preparation method thereof
US-2024410035-A1 · Dec 12, 2024 · US
US10240608B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10240608-B2 |
| Application number | US-201515115948-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 3, 2015 |
| Priority date | Feb 5, 2014 |
| Publication date | Mar 26, 2019 |
| Grant date | Mar 26, 2019 |
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A TiAl alloy comprising the elements C, Si, B, Al and Ti, wherein a C fraction is ≤0.5 wt %, an Si fraction is 0.05-2.5 wt %, a B fraction is ≤0.4 wt % and an Al fraction is 25-43 wt %, in each case in relation to the total weight of the alloy.
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The invention claimed is: 1. A TiAl alloy comprising the elements C, Si, B, Al and Ti, wherein a C fraction is ≤0.5 wt %, an Si fraction is 0.05-2.5 wt %, a B fraction is ≤0.4 wt % and an Al fraction is 25-43 wt %, in each case in relation to the total weight of the alloy, and wherein the TiAl alloy has an average grain size of 1 to 3 μm. 2. The TiAl alloy as claimed in claim 1 , wherein the C fraction is ≤0.4 wt %, the Si fraction is 0.08-2.2 wt %, the B fraction is ≤0.3 wt % and the Al fraction is 28-39 wt %, in each case in relation to the total weight of the alloy. 3. The TiAl alloy as claimed in claim 1 furthermore comprising Nb, wherein an Nb fraction is 0.1-8.0 wt % in relation to the total weight of the alloy. 4. The TiAl alloy as claimed in claim 1 , furthermore comprising at least one of Cr and V and Mo, wherein in the case of presence of Cr a Cr fraction is 0.1-4.0 wt %, in the case of presence of V a V fraction is ≤2.0 wt %, and in the case of presence of Mo an Mo fraction is ≤1.4 wt %, in each case in relation to the total weight of the alloy. 5. The TiAl alloy as claimed in claim 1 , wherein the alloy is composed of Ti, Al, C, Si, B, Al, Mo, Cr, V and Nb, wherein a C fraction is ≤0.5 wt %, an Si fraction is 0.05-2.5 wt %, a B fraction is ≤0.4 wt %, an Al fraction is 25-43 wt %, an Nb fraction is 0.1-8.0 wt %, a Cr fraction is 0.1-4.0 wt %, a V fraction is ≤2.0 wt %, and a Mo fraction is ≤1.4 wt %, in each case in relation to the total weight of the alloy, with a remainder=Ti. 6. The TiAl alloy as claimed in claim 1 , wherein the alloy is subjected to a heat treatment and hot isostatic pressing. 7. The TiAl alloy as claimed in claim 1 , wherein the alloy has a lamellar structure and a spacing between the lamellae is ≤1.5 μm. 8. A turbocharger component, composed of a TiAl alloy as claimed in claim 1 . 9. A turbocharger comprising at least one component, which is composed of a TiAl alloy comprising the elements C, Si, B, Al and Ti, wherein a C fraction is ≤0.5 wt %, an Si fraction is 0.05-2.5 wt %, a B fraction is ≤0.4 wt % and an Al fraction is 25-43 wt %, in each case in relation to the total weight of the alloy, and wherein the TiAl alloy has an average grain size of greater than 2 μm and/or a lamellar structure, wherein a spacing between the lamellae is ≤1.5 μm. 10. The turbocharger as claimed in claim 9 , wherein in the TiAl alloy, the C fraction is ≤0.4 wt %, the Si fraction is 0.08-2.2 wt %, the B fraction is ≤0.3 wt % and the Al fraction is 28-39 wt %, in each case in relation to the total weight of the alloy. 11. The turbocharger as claimed in claim 9 , wherein the TiAl alloy furthermore comprises Nb, wherein an Nb fraction is 0.1-8.0 wt %, in relation to the total weight of the alloy. 12. The turbocharger as claimed in claim 9 , wherein the TiAl alloy furthermore comprises Cr and/or V and/or Mo, wherein a Cr fraction is 0.1-4.0 wt %, and/or a V fraction is ≤2.0 wt %, and/or an Mo fraction is ≤1.4 wt %, in each case in relation to the total weight of the alloy. 13. The turbocharger as claimed in claim 9 , wherein the TiAl alloy is composed of Ti, Al, C, Si, B, Al, Mo, Cr, V and Nb, wherein a C fraction is ≤0.5 wt %, an Si fraction is 0.05-2.5 wt %, a B fraction is ≤0.4 wt %, an Al fraction is 25-43 wt %, an Nb fraction is 0.1-8.0 wt %, a Cr fraction is 0.1-4.0 wt %, a V fraction is ≤2.0 wt %, and a Mo fraction is ≤1.4 wt %, in each case in relation to the total weight of the alloy, with a remainder=Ti. 14. The turbocharger as claimed in claim 9 , wherein the TiAl alloy is subjected to a heat treatment and hot isostatic pressing. 15. A method for producing a TiAl alloy as claimed in claim 1 , comprising the steps: melting the alloy elements to form an alloy material, subjecting the alloy material to heat treatment, and subjecting the alloy material to hot isostatic pressing. 16. The method as claimed in claim 15 , wherein the heat treatment comprises the following steps: heating the alloy material to approximately 1260° C. within two hours, holding the alloy material at a temperature of approximately 1260° C. for three hours, and cooling the alloy material in a nitrogen inert gas atmosphere to a temperature of 650° C. with a cooling rate of 7 K/sec. 17. The TiAl alloy as claimed in claim 1 , furthermore comprising Nb, wherein an Nb fraction is 0.15-6.5 wt % in relation to the total weight of the alloy. 18. The TiAl alloy as claimed in claim 1 , furthermore comprising at least one of Cr and V and Mo, wherein in the case of presence of Cr a Cr fraction is 0.15-3.5 wt %, in the case of presence of V a V fraction is ≤1.7 wt %, and in the case of presence of Mo an Mo fraction is ≤1.2 wt %, in each case in relation to the total weight of the alloy.
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