Block copolymer hydride and stretched film formed from same

Patent metadata

Field	Value
Publication number	US-10239966-B2
Application number	US-201515517964-A
Country	US
Kind code	B2
Filing date	Oct 8, 2015
Priority date	Oct 15, 2014
Publication date	Mar 26, 2019
Grant date	Mar 26, 2019

Abstract

The present invention is a hydrogenated block copolymer obtained by hydrogenating a block copolymer [C] that comprises polymer blocks [A] and polymer block [B],
a ratio (wA:wB) of a weight fraction wA of the polymer blocks [A] and a weight fraction wB of the polymer block [B] in the block copolymer [C] being 45:55 to 65:35, a ratio (w[I B ]:w[II B ]) of a weight fraction w[I B ] of the repeating unit [I] derived from an aromatic vinyl compound and a weight fraction w[II B ] of the repeating unit [II] derived from a linear conjugated diene compound in the polymer block [B] being 40:60 to 55:45, 90% of more of unsaturated bonds included in the block copolymer [C] having been hydrogenated, a weight average molecular weight of 60,000 to 150,000, a low-temperature-side glass transition temperature [Tg 1 ] of 0° C. or more and a high-temperature-side glass transition temperature [Tg 2 ] of 135° C. or more, and a stretched film.

First claim

The invention claimed is:

1. A hydrogenated block copolymer obtained by hydrogenating a block copolymer [C] that comprises two polymer blocks [A] and one polymer block [B], the polymer blocks [A] comprising a repeating unit [I] derived from an aromatic vinyl compound as a main component, and the polymer block [B] comprising a repeating unit [I] derived from an aromatic vinyl compound and a repeating unit [II] derived from a linear conjugated diene compound as main components,
(i) a ratio (wA:wB) of a total weight fraction wA of the polymer blocks [A] in the block copolymer [C] to a weight fraction wB of the polymer block [B] in the block copolymer [C] being 45:55 to 65:35,
(ii) a ratio (w[I B ]:w[II B ]) of a weight fraction w[I B ] of the repeating unit [I] derived from an aromatic vinyl compound in the polymer block [B] to a weight fraction w[II B ] of the repeating unit [II] derived from a linear conjugated diene compound in the polymer block [B] being 40:60 to 55:45,
(iii) 90% of more of unsaturated bonds included in the block copolymer [C] having been hydrogenated,
(iv) the hydrogenated block copolymer having a weight average molecular weight of 60,000 to 150,000, and
(v) the hydrogenated block copolymer having a low-temperature-side glass transition temperature [Tg 1 ] determined by dynamic viscoelastic measurement of 0° C. or more, and having a high-temperature-side glass transition temperature [Tg 2 ] determined by dynamic viscoelastic measurement of 135° C. or more.

2. A stretched film comprising the hydrogenated block copolymer according to claim 1 .

3. A method for producing the hydrogenated block copolymer according to claim 1 , comprising a step of continuously adding a monomer mixture including an aromatic vinyl compound and a linear conjugated diene compound as the main components to the polymerization reaction system to form the polymer block [B] having a homogeneous monomer composition.

Assignees

• Zeon Corp

Inventors

• Saito Daisuke
• Harauchi Yosuke
• Ishiguro Atsushi
• Kohara Teiji

Classifications

• G02B5/3033

  in the form of a thin sheet or foil, e.g. Polaroid · CPC title

• C08F8/04 Primary

  Reduction, e.g. hydrogenation · CPC title

• C08F2500/26

  Use as polymer for film forming · CPC title

• C08J2353/02

  of vinyl aromatic monomers and conjugated dienes · CPC title

• C08F297/046

  polymerising vinyl aromatic monomers and isoprene, optionally with other conjugated dienes · CPC title