Solar thermochemical reactor, methods of manufacture and use thereof and thermogravimeter

Patent metadata

Field	Value
Publication number	US-10239036-B2
Application number	US-201715645223-A
Country	US
Kind code	B2
Filing date	Jul 10, 2017
Priority date	Dec 22, 2011
Publication date	Mar 26, 2019
Grant date	Mar 26, 2019

Abstract

A solar thermochemical reactor includes an outer member, an inner member disposed within an outer member, wherein the outer member surrounds the inner member and wherein the outer member has an aperture for receiving solar radiation and wherein an inner cavity and an outer cavity are formed by the inner member and outer member and a reactive material capable of being magnetically stabilized wherein the reactive material is disposed in the outer cavity between the inner member and the outer member.

First claim

What is claimed is:

1. A solar reactor comprising:
an outer member;
an inner member disposed within an outer member, wherein the outer member surrounds the inner member, wherein the outer member has an aperture for receiving solar radiation and wherein an inner cavity and an outer cavity are formed by the inner member and the outer member; and
a reactive material disposed in the outer cavity between the inner member and the outer member; wherein the reactive material is one of:
a) a composite particle comprising:
a first non-metallic particle in which is dispersed a second non-metallic particle; where the first non-metallic particle and the second non-metallic particle comprise inorganic materials; or

b) a monolithic solid comprising:
a plurality of particles fused together in the form of aligned chains; the monolithic solid being porous; where the fused particles are oriented in a magnetic or electrical field while being fused together.

2. The solar reactor of claim 1 , where the composite particle further comprises a third non-metallic derivative that stabilizes the first non-metallic particle and the second non-metallic particle against further sintering.

3. The solar reactor of claim 2 , where the composite particle has an average particle size of about 200 to about 2000 micrometers.

4. The solar reactor of claim 1 , where the first non-metallic particle has an average particle size of about 20 to about 80 micrometers, and where the second non-metallic particle has an average particle size of about 0.5 to about 10 micrometers prior to a sintering.

5. The solar reactor of claim 1 , where a weight ratio of the first non-metallic particle to the second non-metallic particle is about 1:4 to about 1:6.

6. The solar reactor of claim 1 , where the first non-metallic particle comprises magnetite.

7. The solar reactor of claim 1 , where the second non-metallic particle comprises zirconia.

8. The solar reactor of claim 1 , where the composite particle has a surface area of greater than or equal to about 100 square meter per gram.

9. The solar reactor of claim 1 , where the monolithic solid comprises particles that comprise iron, nickel, cobalt, ferrites, rare earth metals or alloys thereof.

10. The solar reactor of claim 1 , where the monolithic solid comprises first particles that are magnetic particles or that are susceptible to a magnetic field and second particles that are not magnetic particles or that are not susceptible to a magnetic field.

11. The solar reactor of claim 10 , where the monolithic solid comprises ferroelectric particles.

12. The solar reactor of claim 1 , where the monolithic solid comprises magnetic particles that comprise NdFeB, FeOFe2O3, NiOFe2O3, CuOFe2O3, MgOFe2O3, MnBi, MnSb, MnOFe2O, or a combination comprising at least one of the foregoing magnetic particles.

13. The solar reactor of claim 1 , where the chains of aligned particles comprise a particle whose magnetic north poles contact a magnetic south pole on a neighboring particle.

Assignees

• Univ Florida
• Univ Florida

Inventors

• Klausner James F
• Petrasch Joerg
• Mei Renwei
• Momen Ayyoub Mehdizadeh
• Allen Kyle
• Al-Raqom Fotouh A

Classifications

• C01B3/10

  by reaction of water vapour with metals · CPC title

• F24S20/20

  Solar heat collectors for receiving concentrated solar energy, e.g. receivers for solar power plants · CPC title

• B01J2219/085

  creating magnetic fields · CPC title

• Y02E10/41

  Cross-Sectional Technologies · mapped topic

• Y02E60/364

  Cross-Sectional Technologies · mapped topic