Process for recovering methane from a gas stream comprising methane and ethylene

Patent metadata

Field	Value
Publication number	US-10239013-B2
Application number	US-201515305523-A
Country	US
Kind code	B2
Filing date	Apr 20, 2015
Priority date	Apr 22, 2014
Publication date	Mar 26, 2019
Grant date	Mar 26, 2019

Abstract

The invention relates to a process for recovering methane from a gas stream comprising methane and ethylene, comprising a sorption step which comprises contacting the gas stream comprising methane and ethylene with a sorption agent which has a lower affinity for methane than for ethylene, resulting in sorption of ethylene and 0 to 90% of the methane by the sorption agent and in a gas stream comprising methane in an amount of 10 to 100% based on the amount of methane in the gas stream that is subjected to the sorption step; and a desorption step which comprises desorbing sorbed ethylene and optionally sorbed methane resulting in a gas stream comprising ethylene and optionally methane.

First claim

That which is claimed is:

1. A process for recovering methane from a gas stream comprising methane and ethylene, comprising:
a sorption step which comprises contacting the gas stream comprising methane and ethylene with a sorption agent which has a lower affinity for methane than for ethylene, resulting in sorption of ethylene and 0 to 25% of the methane by the sorption agent and in a methane gas stream comprising methane in an amount of 75 to 100% based on the amount of methane in the gas stream that is subjected to the sorption step; and
a desorption step which comprises desorbing sorbed ethylene and sorbed methane resulting in a gas stream comprising ethylene and methane,
a distillation step which comprises distilling the gas stream comprising ethylene and methane resulting from the desorption step, said distillation step resulting in a top stream comprising methane and a bottom stream comprising ethylene,
wherein the gas stream that is subjected to the sorption step is derived from an oxidative coupling of methane process.

2. A process according to claim 1 , wherein the gas stream that is subjected to the sorption step comprises of 50 to 99 mol % of methane and 1 to 50 mol % of ethylene.

3. A process according to claim 1 , wherein desorption in the desorption step is effected by reducing the pressure.

4. A process according to claim 3 , wherein the pressure in the sorption step is in the range of from 5 to 15 bar, and the pressure in the desorption step is in the range of from 0.1 to 3 bar.

5. A process according to claim 1 , wherein the gas stream comprising methane and ethylene that is subjected to the sorption step additionally comprises hydrogen, optionally nitrogen, carbon monoxide, carbon dioxide, ethane and hydrocarbons having 3 or more carbon atoms, which process comprises:
a sorption step which comprises contacting the gas stream comprising methane, ethylene, hydrogen, optionally nitrogen, carbon monoxide, carbon dioxide, ethane and hydrocarbons having 3 or more carbon atoms with a sorption agent which has a lower affinity for methane, hydrogen, nitrogen and carbon monoxide than for carbon dioxide, ethane, ethylene and hydrocarbons having 3 or more carbon atoms, resulting in sorption of hydrocarbons having 3 or more carbon atoms, ethane, ethylene, carbon dioxide and 0 to 25% of the methane by the sorption agent and in a gas stream comprising hydrogen, optionally nitrogen, carbon monoxide and methane wherein the amount of methane in said gas stream is 75 to 100% based on the amount of methane in the gas stream that is subjected to the sorption step; and
a desorption step which comprises desorbing sorbed carbon dioxide, ethylene, ethane and hydrocarbons having 3 or more carbon atoms and sorbed methane resulting in a gas stream comprising carbon dioxide, ethylene, ethane, hydrocarbons having 3 or more carbon atoms and methane.

6. A process according to claim 5 , wherein the gas stream that is subjected to the sorption step comprises 40 to 90 mol % of methane, 0.5 to 45 mol % of ethylene, 0.01 to 3 mol % of hydrogen, 0 to 80 mol % of nitrogen, 0.1 to 5 mol % of carbon monoxide, 5 to 25 mol % of carbon dioxide, 0.1 to 25 mol % of ethane and 0.5 to 20 mol % of hydrocarbons having 3 or more carbon atoms.

7. A process according to claim 5 , additionally comprising a distillation step which comprises distilling the gas stream comprising hydrogen, nitrogen, carbon monoxide and methane resulting from the sorption step, said distillation step resulting in a top stream comprising hydrogen, nitrogen and carbon monoxide and a bottom stream comprising methane.

8. A process according to claim 5 , additionally comprising a carbon dioxide removal step which comprises removing carbon dioxide from the gas stream comprising carbon dioxide, ethylene, ethane, hydrocarbons having 3 or more carbon atoms and optionally methane resulting from the desorption step, resulting in a gas stream comprising ethylene, ethane, hydrocarbons having 3 or more carbon atoms and methane.

9. A process according to claim 8 , wherein the sorption step results in sorption of hydrocarbons having 3 or more carbon atoms, ethane, ethylene, carbon dioxide and part of the methane by the sorption agent, which process additionally comprises a distillation step which comprises distilling the gas stream comprising ethylene, ethane, hydrocarbons having 3 or more carbon atoms and methane resulting from the carbon dioxide removal step, said distillation step resulting in a top stream comprising methane and a bottom stream comprising ethylene, ethane and hydrocarbons having 3 or more carbon atoms.

10. A process according to claim 9 , additionally comprising a distillation step which comprises distilling a gas stream comprising ethylene, ethane and hydrocarbons having 3 or more carbon atoms resulting from the carbon dioxide removal step of the process of claim 8 or distilling the bottom stream comprising ethylene, ethane and hydrocarbons having 3 or more carbon atoms resulting from the distillation step of the process of claim 9 , said distillation step resulting in a top stream comprising ethylene and a bottom stream comprising ethane and hydrocarbons having 3 or more carbon atoms.

Assignees

• Shell Oil Co

Inventors

• Sadasivan Vijayakumari Sivakumar
• Sanders Charles-Edouard
• Shah Vatsal Mukundlal

Classifications

• C07C7/04

  by distillation · CPC title

• B01D2253/108

  Zeolites · CPC title

• B01D53/047 Primary

  Pressure swing adsorption · CPC title

• Y02P20/152

  Cross-Sectional Technologies · mapped topic

• B01D2257/502

  Carbon monoxide · CPC title