Static disk electrode for electroplating bath analysis

Patent metadata

Field	Value
Publication number	US-10234419-B2
Application number	US-201615162609-A
Country	US
Kind code	B2
Filing date	May 23, 2016
Priority date	May 23, 2016
Publication date	Mar 19, 2019
Grant date	Mar 19, 2019

Abstract

The presently claimed invention provides an electrochemical analytical apparatus for electrochemical bath analysis. The apparatus comprise a static electrode and a rotatable unit. As steady liquid flow can be generated on the electrolytic surface of the static electrode by the rotatable unit through rotation, the static disk electrode does not involve any movement during the bath analysis such that the design of the electrical contact in the electrode can be substantially simplified.

First claim

What is claimed is:

1. An electrochemical analytical apparatus for electrochemical bath analysis, comprising:
a static working electrode having a body and at least one electrolytic surface for being inserted into a liquid electrolyte;
a rotatable unit comprising at least one blade and located concentrically with and near the static working electrode for creating a laminar flow of the liquid electrolyte towards the at least one electrolytic surface of the static working electrode; wherein the rotatable unit is freely mounted along a vertical axis of the body of the static working electrode and downstream from the at least one electrolytic surface of the static working electrode relative to the laminar flow; and
a control unit for controlling the rotation of the rotatable unit for arousing a relative motion between the electrolytic surface of the static working electrode and a bulk portion of the liquid electrolyte, wherein the laminar flow is symmetrical relative to the vertical axis of the body of the static working electrode.

2. The apparatus of claim 1 , wherein the static working electrode is connected with an electrical contact.

3. The apparatus of claim 1 , wherein the static working electrode is a disk electrode or a ring disk electrode.

4. The apparatus of claim 1 , wherein the rotatable unit further comprises two or more blades being symmetrically arranged relative to the at least one electrolytic surface of the static working electrode.

5. The apparatus of claim 1 , wherein the control unit controls rotation speed of the rotatable unit.

6. The apparatus of claim 1 , wherein the control unit is a magnetic stirrer detachably coupled to the magnetic stir bar.

7. The apparatus of claim 1 , further comprising a reference electrode and a counter electrode.

8. The apparatus of claim 1 , wherein the at least one electrolytic surface is located at bottom of the static working electrode;
wherein the apparatus further comprises an electrical contact connected to the static working electrode for transmitting current;
wherein the magnetic stir bar comprises a hole and at least two blades and is located on top of the electrolytic surface, wherein the hole is for accommodating the static working electrode, and the at least two blades are arranged in a symmetrical way to each other; and
wherein the control unit comprises a magnetic stirrer for generating electric field for controlling the rotation of the magnetic stir bar;
wherein the aroused relative motion is symmetrical relative to the at least one electrolytic surface of the static working electrode.

9. The apparatus of claim 8 , wherein the static working electrode is a disk electrode or a ring disk electrode.

10. The apparatus of claim 8 , wherein the electrical contact is an electrical wire or a bundle of electrical wires.

11. The apparatus of claim 8 , wherein a center of the magnetic stir bar is located along a vertical axis of the body.

Assignees

• Hong Kong Applied Science & Tech Research Inst Co Ltd

Inventors

• Sun Yaofeng
• Xu Sha

Classifications

• G01N27/28

  Electrolytic cell components · CPC title

• G01N27/4166 Primary

  measuring a particular property of an electrolyte · CPC title

• C25D21/12 Primary

  Process control or regulation (controlling or regulating in general G05) · CPC title

• G01N27/30

  Electrodes, e.g. test electrodes; Half-cells (G01N27/414 takes precedence) · CPC title