System and method for the direct calorimetric measurement of laser absorptivity of materials

Patent metadata

Field	Value
Publication number	US-10234411-B2
Application number	US-201615213210-A
Country	US
Kind code	B2
Filing date	Jul 18, 2016
Priority date	Jul 17, 2015
Publication date	Mar 19, 2019
Grant date	Mar 19, 2019

Abstract

A method and system for calorimetrically measuring the temperature-dependent absorptivity of a homogeneous material dimensioned to be thin and flat with a predetermined uniform thickness and a predetermined porosity. The system includes a material holder adapted to support and thermally isolate the material to be measured, an irradiation source adapted to uniformly irradiate the material with a beam of electromagnetic radiation, and an irradiation source controller adapted to control the irradiation source to uniformly heat the material during a heating period, followed by a cooling period when the material is not irradiated. A thermal sensor measures temperature of the material during the heating and cooling periods, and a computing system first calculates temperature-dependent convective and radiative thermal losses of the material based on the measured temperature of the material during the cooling period when beam intensity is zero, followed by calculation of the temperature-dependent absorptivity of the material based on the temperature-dependent convective and radiative thermal losses determined from the cooling period.

First claim

We claim:

1. A calorimetric method of measuring the temperature-dependent absorptivity of a material, comprising:
providing a homogeneous material dimensioned to be thin and flat with a predetermined uniform thickness and a predetermined porosity;
thermally isolating the material;
uniformly irradiating the material with a beam of electromagnetic radiation having a predetermined intensity to uniformly heat the material during a heating period, followed by a cooling period when the material is not irradiated and the intensity of the beam is zero;
measuring the temperature of the material during the heating and cooling periods;
determining temperature-dependent convective and radiative thermal losses of the material based on the measured temperature of the material during the cooling period when beam intensity is zero, and the thickness and porosity of the material; and
determining the temperature-dependent absorptivity of the material based on the temperature-dependent convective and radiative thermal losses determined from the cooling period, the thickness and porosity of the material, and the intensity of the beam.

2. The method of claim 1 ,
wherein the material is a powder or liquid provided in a thermally conductive container having a container volume with a uniform and shallow depth, and with the powder or liquid conformably filling the container volume to capacity to have the predetermined thickness and the predetermined porosity; and
wherein the temperature of the powder or liquid is measured by measuring the temperature of the container.

3. The method of claim 2 ,
wherein the container has an opening defined by a rim into the container volume; and
wherein the powder is made to conformably fill the container volume to capacity by using an implement adapted to remove excess powder in the container volume when run along the rim of the opening.

4. The method of claim 2 ,
wherein the powder or liquid material is thermally isolated by suspending the powder or liquid-filled container on at least two wires suspended between end supports.

5. The method of claim 1 ,
wherein a solid material is thermally isolated by suspending the solid material on at least two wires suspended between end supports.

6. A system for calorimetrically measuring the temperature-dependent absorptivity of a homogeneous material dimensioned to be thin and flat with a predetermined uniform thickness and a predetermined porosity, comprising:
a material holder adapted to support and thermally isolate the material to be measured;
an irradiation source adapted to uniformly irradiate the material with a beam of electromagnetic radiation;
an irradiation source controller adapted to control the irradiation source to uniformly heat the material with a beam having a predetermined intensity during a heating period, followed by a cooling period when the material is not irradiated and the intensity of the beam is zero;
a thermal sensor adapted to measure temperature of the material during the heating and cooling periods; and
a computing system operably connected to the thermal sensor, and adapted to determine temperature-dependent convective and radiative thermal losses of the material based on the measured temperature of the material during the cooling period when beam intensity is zero, and the thickness and porosity of the material, and to determine the temperature-dependent absorptivity of the material based on the temperature-dependent convective and radiative thermal losses determined from the cooling period, the thickness and porosity of the material, and the intensity of the beam.

7. The system of claim 6 ,
wherein the material holder comprises a thermally conductive container having a container volume with a uniform and shallow depth so that a powder or liquid material conformably filling the container volume to capacity has the predetermined thickness and the predetermined porosity; and
wherein the thermal sensor is adapted to measure temperature of the powder or liquid material by measuring the temperature of the container.

8. The system of claim 7 ,
wherein the container has an opening defined by a rim into the container volume, and the system further comprises an implement adapted to remove excess powder in the container volume when run along the rim of the opening.

9. The system of claim 7 ,
wherein the material holder further comprises at least two wires suspended between end supports for suspending the powder or liquid-filled container thereon to thermally isolate the powder or liquid material.

10. The system claim 6 ,
wherein the material holder further comprises at least two wires suspended between end supports for suspending a solid material thereon to thermally isolate the solid material.

11. The system of claim 6 ,
wherein the computing system operably is operably connected to the irradiation controller for receiving start and stop times of the irradiation source for identifying the heating and cooling periods.

Assignees

• Rubenchik Alexander
• Golosker Ilya V
• Leblanc Mary M
• Mitchell Scott C
• Wu Sheldon S
• L Livermore Nat Security Llc

Inventors

• Rubenchik Alexander
• Golosker Ilya V
• Leblanc Mary M
• Mitchell Scott C
• Wu Sheldon S

Classifications

• G01K17/00

  Measuring quantity of heat (measuring temperature by calorimetry G01K3/00 - G01K11/00; specially adapted for measuring thermal properties of materials, e.g. specific heat, heat of combustion G01N) · CPC title

• G01N25/48

  on solution, sorption, or a chemical reaction not involving combustion or catalytic oxidation · CPC title

• G01K17/04

  Calorimeters using compensation methods {, i.e. where the absorbed or released quantity of heat to be measured is compensated by a measured quantity of heating or cooling} · CPC title

• G01N25/4853

  Details · CPC title

• G01N25/486

  Sample holders · CPC title