Photo-electrochemical reaction device

Patent metadata

Field	Value
Publication number	US-10233549-B2
Application number	US-201615255739-A
Country	US
Kind code	B2
Filing date	Sep 2, 2016
Priority date	May 20, 2014
Publication date	Mar 19, 2019
Grant date	Mar 19, 2019

Abstract

To convert light into a chemical substance with high conversion efficiency. A device, comprising: a photovoltaic layer having a first face and a second face; an oxidation electrode layer electrically connected to the first face of the photovoltaic layer; a reduction electrode layer electrically connected to the second face of the photovoltaic layer; a first electrolytic solution being supplied to the oxidation electrode layer; a second electrolytic solution being supplied to the reduction electrode layer; and a porous layer, provided to in contact with at least one of the first electrolytic solution and the second electrolytic solution, having fine pores through which a product produced by the oxidation reaction or the reduction reaction passes, and being given a temperature gradient wherein the product being purified by the porous layer.

First claim

What is claimed is:

1. A photoelectrochemical reaction device, comprising:
a photovoltaic layer having a first face and a second face opposite each other and configured to perform charge separation by energy of light irradiated to the first face or the second face;
an oxidation electrode layer electrically connected to the first face and configured to cause an oxidation reaction of water;
a reduction electrode layer electrically connected to the second face and configured to cause a reduction reaction of at least one of water and carbon dioxide;
a tank to store a first electrolytic solution and a second electrolytic solution, the first electrolytic solution containing water and being configured to be supplied to the oxidation electrode layer, the second electrolytic solution containing at least one selected from the group consisting of water and carbon dioxide and being configured to be supplied to the reduction electrode layer; and
a porous layer, being provided in the tank to contact with the oxidation electrode layer or the reduction electrode layer, having fine pores through which an oxidation product and the first electrolytic solution or a reduction product and the second electrolytic solution pass, and being configured to get a temperature gradient and thus purify the oxidation product or the reduction product and vaporize the first electrolytic solution or the second electrolytic solution.

2. The device of claim 1 , wherein:
the reduction product and the oxidation product respectively contains hydrogen and oxygen;
at least a part of the reduction product or the oxidation product is configured to be repeatedly vaporized and liquefied by moving from a high temperature side to a low temperature side of the porous layer through the fine pores, to remove moisture in the reduction product or the oxidation product and to thereby extract the hydrogen or the oxygen.

3. The device of claim 1 , wherein
the reduction product contains a carbon compound; and
the porous layer is configured to repeatedly perform vaporization and liquefaction of at least a part of the reduction product while moving the reduction product from a high temperature side to a low temperature side through the fine pores to rectify the carbon compound.

4. The device of claim 1 , wherein the porous layer is in contact with the oxidation electrode layer and the reduction electrode layer.

5. The device of claim 1 , further comprising:
a product flow path in contact with the porous layer.

6. The device of claim 5 , wherein the product flow path is provided on the porous layer.

7. The device of claim 5 , wherein the product flow path is surrounded by the porous layer.

8. The device of claim 1 , wherein:
the porous layer has a first region and a second region; and
the reduction electrode layer is provided to separate the first region and the second region.

9. The device of claim 8 , further comprising:
a first product flow path in contact with the first region; and
a second product flow path in contact with the second region.

10. The device of claim 1 , wherein the porous layer is provided on the first electrolytic solution or the second electrolytic solution.

11. The device of claim 1 , wherein the porous layer is provided on the tank.

12. The device of claim 1 , wherein the porous layer is hydrophobic and conductive.

13. The device of claim 1 , further comprising:
a first electrolytic solution path through which the first electrolytic solution passes to the oxidation electrode layer, or a second electrolytic solution path through which the second electrolytic solution passes to the reduction electrode layer.

14. The device of claim 1 , wherein:
the oxidation electrode layer is provided on the first face, and
the reduction electrode layer is provided on the second face.

15. The device of claim 1 , wherein the porous layer contains an oxidation catalyst for the oxidation reaction or a reduction catalyst for the reduction reaction.

Assignees

• Toshiba Kk

Inventors

• Ono Akihiko
• Mikoshiba Satoshi
• Kudo Yuki
• Kitagawa Ryota
• Tamura Jun
• Tsutsumi Eishi
• Sugano Yoshitsune

Classifications

• C25B1/003

  Chemistry & Metallurgy · mapped topic

• C25B9/08 Primary

  Chemistry & Metallurgy · mapped topic

• Y02P20/135

  Cross-Sectional Technologies · mapped topic

• C25B9/00

  Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features · CPC title

• Y02E60/366

  Cross-Sectional Technologies · mapped topic