Hydrophobic aerogel materials

Patent metadata

Field	Value
Publication number	US-10233303-B2
Application number	US-201715835258-A
Country	US
Kind code	B2
Filing date	Dec 7, 2017
Priority date	Oct 3, 2014
Publication date	Mar 19, 2019
Grant date	Mar 19, 2019

Abstract

The present disclosure provides an aerogel composition which is durable and easy to handle, which has favorable performance in aqueous environments, and which also has favorable combustion and self-heating properties. Also provided is a method of preparing an aerogel composition which is durable and easy to handle, which has favorable performance in aqueous environments, and which has favorable combustion and self-heating properties. Further provided is a method of improving the hydrophobicity, the liquid water uptake, the heat of combustion, or the onset of thermal decomposition temperature of an aerogel composition.

First claim

What is claimed:

1. A reinforced aerogel composition comprising a silica-based framework, a reinforcement material, and at least one hydrophobic-bound silicon; wherein the reinforced aerogel composition has the following properties: i) a liquid water uptake of 40 wt % or less; and ii) a heat of combustion of 460 cal/g or less.

2. The reinforced aerogel composition of claim 1 , wherein the reinforcement material comprises a fiber reinforcement material.

3. The reinforced aerogel composition of claim 1 , wherein the reinforcement material comprises a sheet of fiber reinforcement material.

4. The reinforced aerogel composition of claim 1 , wherein the reinforcement material comprises a material other than a fiber reinforcement material.

5. The reinforced aerogel composition of claim 1 , wherein the reinforcement material comprises a sheet of material other than a sheet of fiber reinforcement material.

6. The reinforced aerogel composition of claim 2 , wherein the reinforced aerogel composition has a heat of combustion between 265 cal/g and 460 cal/g.

7. The reinforced aerogel composition of claim 6 , wherein the reinforced aerogel composition has a density of 0.40 g/cm3 or less.

8. The reinforced aerogel composition of claim 6 , wherein the reinforced aerogel composition has a thermal conductivity between 15 mW/M*K and 30 mW/M*K.

9. The reinforced aerogel composition of claim 6 , wherein the reinforced aerogel composition has an onset of thermal decomposition of hydrophobic organic materials between 515° C. and 635° C.

10. The reinforced aerogel composition of claim 6 , wherein the reinforced aerogel composition has an onset of thermal decomposition of hydrophobic organic materials between 550° C. and 635° C.

11. The reinforced aerogel composition of claim 6 , wherein the reinforced aerogel composition has an onset of thermal decomposition of hydrophobic organic materials between 575° C. and 635° C.

12. The reinforced aerogel composition of claim 6 , wherein the reinforced aerogel composition has an onset of thermal decomposition of hydrophobic organic materials between 600° C. and 635° C.

13. The reinforced aerogel composition of claim 6 , wherein the hydrophobic organic content in the aerogel composition is between 2 wt % and 10 wt %.

14. The reinforced aerogel composition of claim 6 , wherein the hydrophobic organic content in the aerogel composition is between 2 wt % and 8 wt %.

15. The reinforced aerogel composition of claim 6 , wherein the hydrophobic organic content in the aerogel composition is between 2 wt % and 6 wt %.

16. The reinforced aerogel composition of claim 6 , wherein the reinforced aerogel composition has a ratio of T 1-2 :T 3 of between about 0.01 and 0.4, and a ratio of Q 1-3 :Q 4 of between about 0.1 and 1.5.

17. The reinforced aerogel composition of claim 6 , wherein the reinforced aerogel composition is an aerogel blanket composition.

18. A reinforced aerogel composition comprising a silica-based framework, a reinforcement material, and at least one hydrophobic-bound silicon; wherein the reinforced aerogel composition has the following properties: i) a liquid water uptake of 40 wt % or less; and ii) an onset of thermal decomposition of hydrophobic organic materials of 515° C. or higher.

19. The reinforced aerogel composition of claim 18 , wherein the reinforcement material comprises a fiber reinforcement material.

20. The reinforced aerogel composition of claim 18 , wherein the reinforcement material comprises a sheet of fiber reinforcement material.

21. The reinforced aerogel composition of claim 18 , wherein the reinforcement material comprises a material other than a fiber reinforcement material.

22. The reinforced aerogel composition of claim 18 , wherein the reinforcement material comprises a sheet of material other than a sheet of fiber reinforcement material.

23. The reinforced aerogel composition of claim 19 , wherein the reinforced aerogel composition has an onset of thermal decomposition of hydrophobic organic materials between 515° C. and 635° C.

24. The reinforced aerogel composition of claim 23 , wherein the reinforced aerogel composition has a density of 0.40 g/cm3 or less.

25. The reinforced aerogel composition of claim 23 , wherein the reinforced aerogel composition has a thermal conductivity between 15 mW/M*K and 30 mW/M*K.

26. The reinforced aerogel composition of claim 23 , wherein the reinforced aerogel composition has an onset of thermal decomposition of hydrophobic organic materials between 550° C. and 635° C.

27. The reinforced aerogel composition of claim 23 , wherein the reinforced aerogel composition has an onset of thermal decomposition of hydrophobic organic materials between 575° C. and 635° C.

28. The reinforced aerogel composition of claim 23 , wherein the reinforced aerogel composition has an onset of thermal decomposition of hydrophobic organic materials between 600° C. and 635° C.

29. The reinforced aerogel composition of claim 23 , wherein the hydrophobic organic content in the aerogel composition is between 2 wt % and 10 wt %.

30. The reinforced aerogel composition of claim 23 , wherein the hydrophobic organic content in the aerogel composition is between 2 wt % and 8 wt %.

31. The reinforced aerogel composition of claim 23 , wherein the hydrophobic organic content in the aerogel composition is between 2 wt % and 6 wt %.

32. The reinforced aerogel composition of claim 23 , wherein the reinforced aerogel composition has a ratio of T 1-2 :T 3 of between about 0.01 and 0.4, and a ratio of Q 1-3 :Q 4 of between about 0.1 and 1.5.

33. The reinforced aerogel composition of claim 23 , wherein the reinforced aerogel composition is an aerogel blanket composition.

Assignees

• Aspen Aerogels Inc

Inventors

• Evans Owen Richard
• Dekrafft Kathryn Elizabeth
• Zafiropoulos Nicholas Anthony
• Dong Wenting
• Mihalcik David J
• Gould George L
• Melnikova Irene

Classifications

• C08K3/38

  Boron-containing compounds · CPC title

• C08K3/36 Primary

  Silica · CPC title

• C01B33/159

  Coating or hydrophobisation · CPC title

• C08K3/34

  Silicon-containing compounds · CPC title

• B01J13/0091

  Preparation of aerogels, e.g. xerogels · CPC title