Hydrophobic aerogel materials

Patent metadata

Field	Value
Publication number	US-10233302-B2
Application number	US-201715835136-A
Country	US
Kind code	B2
Filing date	Dec 7, 2017
Priority date	Oct 3, 2014
Publication date	Mar 19, 2019
Grant date	Mar 19, 2019

Abstract

The present disclosure provides an aerogel composition which is durable and easy to handle, which has favorable performance in aqueous environments, and which also has favorable combustion and self-heating properties. Also provided is a method of preparing an aerogel composition which is durable and easy to handle, which has favorable performance in aqueous environments, and which has favorable combustion and self-heating properties. Further provided is a method of improving the hydrophobicity, the liquid water uptake, the heat of combustion, or the onset of thermal decomposition temperature of an aerogel composition.

First claim

What is claimed:

1. A method for preparing a fiber- or foam-reinforced aerogel composite, comprising:
Providing a reinforced, silica-based aerogel composition comprising a silica-based aerogel framework including aerogel material, a fiber or foam reinforcement material, and at least one hydrophobic-bound silicon, and having a hydrophobic organic content between 2 wt % and 12 wt % of the reinforced aerogel composition; and
Exposing the reinforced, silica-based aerogel composition to heat treatment in a reduced oxygen atmosphere, wherein
the heat treatment comprises exposure to one or more temperatures between 515° C. and 700° C., for at least 1 minute,
the reinforced, silica-based aerogel composition is not exposed to a temperature above 700° C. for more than 1 minute, and
the reinforced, silica-based aerogel composition after the heat treatment has a hydrophobic organic content between 2 wt % and 12wt %.

2. The method of claim 1 , wherein a fiber reinforcement material is used.

3. The method of claim 1 , wherein a sheet of fiber reinforcement material is used.

4. The method of claim 1 , wherein a foam reinforcement material is used.

5. The method of claim 2 , wherein the total duration of the heat treatment is between 1 minute and 60 minutes.

6. The method of claim 2 , wherein the total duration of the heat treatment is between 1 minute and 30 minutes.

7. The method of claim 2 , wherein the duration of the heat treatment in the reduced oxygen atmosphere at one or more temperatures between 515° C. and 700° C. is between 1minute and 30 minutes.

8. The method of claim 2 , wherein the duration of the heat treatment in the reduced oxygen atmosphere at one or more temperatures between 515° C. and 700° C. is between 1minute and 20 minutes.

9. The method of claim 2 , wherein the reduced oxygen atmosphere is 0.01% to 5% oxygen by volume.

10. The method of claim 2 , wherein the reduced oxygen atmosphere is 0.01% to 1% oxygen by volume.

11. The method of claim 2 , wherein the reinforced aerogel composition before the heat treatment comprises hydrophobic organic material, including aliphatic hydrophobic groups; and wherein the aliphatic hydrophobic groups comprise at least 50% of the hydrophobic organic material.

12. The method of claim 2 , wherein the reinforced aerogel composition before the heat treatment comprises hydrophobic organic material, including methyl hydrophobic groups; and wherein methyl hydrophobic groups comprise at least 50% of the hydrophobic organic material.

13. The method of claim 2 , wherein the reinforced aerogel composition has a hydrophobic organic content between 2 wt % and 10 wt % before the heat treatment and after the heat treatment.

14. The method of claim 2 , wherein the reinforced aerogel composition has a hydrophobic organic content between 2 wt % and 8 wt % before the heat treatment and after the heat treatment.

15. The method of claim 2 , wherein the reinforced aerogel composition has a hydrophobic organic content between 2 wt % and 6 wt % before the heat treatment and after the heat treatment.

16. A reinforced aerogel composition produced by the method of claim 1 , comprising a silica-based aerogel framework, a reinforcement material, and at least one hydrophobic-bound silicon.

17. The reinforced aerogel composition of claim 16 , wherein the reinforced aerogel composition has the following properties: i) a liquid water uptake of 40 wt % or less; ii) an onset of thermal decomposition of hydrophobic organic materials between 515° C. and 635° C.; iii) a heat of combustion between 265 cal/g and 717cal/g; and iv) a thermal conductivity between 15 mW/M*K and 30 mW/M*K.

18. The reinforced aerogel composition of claim 17 , wherein the reinforced aerogel composition has a heat of combustion between 265cal/g and 600 cal/g.

19. The reinforced aerogel composition of claim 17 , wherein the reinforced aerogel composition has a heat of combustion between 265 cal/g and 550 cal/g.

20. The reinforced aerogel composition of claim 17 , wherein the reinforced aerogel composition has a heat of combustion between 265 cal/g and 500 cal/g.

21. The reinforced aerogel composition of claim 17 , wherein the reinforced aerogel composition has a heat of combustion between 265 cal/g and 450 cal/g.

22. The reinforced aerogel composition of claim 17 , wherein the reinforced aerogel composition has an onset of thermal decomposition of hydrophobic organic materials between 525° C. and 635° C.

23. The reinforced aerogel composition of claim 17 , wherein the reinforced aerogel composition has an onset of thermal decomposition of hydrophobic organic materials between 550° C. and 635° C.

24. The reinforced aerogel composition of claim 17 , wherein the reinforced aerogel composition has an onset of thermal decomposition of hydrophobic organic materials between 575° C. and 635° C.

25. The reinforced aerogel composition of claim 17 , wherein the reinforced aerogel composition has an onset of thermal decomposition of hydrophobic organic materials between 600° C. and 635° C.

26. The reinforced aerogel composition of claim 17 , wherein the reinforced aerogel composition has an onset of thermal decomposition of hydrophobic organic materials between 615° C. and 635° C.

Assignees

• Aspen Aerogels Inc

Inventors

• Evans Owen Richard
• Dekrafft Kathryn Elizabeth
• Zafiropoulos Nicholas Anthony
• Dong Wenting
• Mihalcik David J
• Gould George L
• Melnikova Irene

Classifications

• C08K2003/2241

  Titanium dioxide · CPC title

• C08K3/22

  of metals · CPC title

• C08K2003/2262

  of manganese · CPC title

• C01B33/159

  Coating or hydrophobisation · CPC title

• C08K3/34

  Silicon-containing compounds · CPC title