Methods for preparing and collecting polyaromatic compounds, and products comprising polyaromatic compounds

Patent metadata

Field	Value
Publication number	US-10233281-B2
Application number	US-201515511071-A
Country	US
Kind code	B2
Filing date	Sep 25, 2015
Priority date	Sep 26, 2014
Publication date	Mar 19, 2019
Grant date	Mar 19, 2019

Abstract

Disclosed are methods for preparing and collecting a polyaromatic compound. Also disclosed are products comprising a polyaromatic compound.

First claim

What is claimed is:

1. A method comprising:
a first subjecting step, wherein a first biomass is subjected to a first fluid comprising hot compressed water, thereby forming a first mixture;
wherein the first mixture comprises a first liquid fraction comprising a first solubilized polyaromatic compound and a first solid fraction;

optionally, separating at least a portion of the first solid fraction from the first liquid fraction;
a first acidifying step, wherein the first liquid comprising the first solubilized polyaromatic compound is acidified at a temperature of at least about 90° C., thereby forming a second mixture comprising a first precipitated polyaromatic compound; and
a first collecting step, wherein at least a portion of the first precipitated polyaromatic compound is collected, thereby obtaining a first collected precipitated polyaromatic compound;
wherein a substantial portion of the first collected precipitated polyaromatic compound is not discarded and is not combusted.

2. The method of claim 1 , wherein at least a portion of the first collected precipitated polyaromatic compound is sold, bartered, traded, or any combination thereof; or
wherein at least a portion of the first collected precipitated polyaromatic compound is incorporated into a product capable of sale, barter, trade, or any combination thereof.

3. The method of claim 1 , wherein the first precipitated polyaromatic compound is selected from the group consisting of lignin, pseudolignin, a polyfuranic compound, and any combination thereof.

4. The method of claim 1 , wherein the first fluid has a temperature of about 130° C. to about 374° C.

5. The method of claim 1 , wherein the first fluid consists essentially of hot compressed water.

6. The method of claim 1 , wherein the first liquid comprising the first solubilized polyaromatic compound does not comprise spent liquor.

7. The method of claim 1 , wherein the first biomass is raw biomass.

8. The method of claim 1 , wherein the first biomass is obtained by a process selected from the group consisting of acid hydrolysis, enzymatic hydrolysis, sulfur dioxide treatment, hot compressed water treatment, and any combination thereof.

9. The method of claim 1 , wherein at least a portion of the first solid fraction or a first solid derived from the first solid fraction is, in a second subjecting step, subjected to a third fluid comprising hot compressed water, thereby forming a third mixture, wherein the third mixture comprises a second liquid fraction comprising a second solubilized polyaromatic compound and a second solid fraction.

10. The method of claim 9 , wherein the hot compressed water in the third fluid is supercritical water.

11. The method of claim 9 , wherein the third fluid consists essentially of hot compressed water.

12. The method of claim 9 , wherein the second subjecting step employs the first solid derived from the first solid fraction, wherein the first solid derived from the first solid fraction is obtained by exposing the first solid fraction to a process selected from the group consisting of acid hydrolysis, enzymatic hydrolysis, sulfur dioxide treatment, hot compressed water treatment, and any combination thereof.

13. The method of claim 9 , further comprising:
optionally, separating at least a portion of the second solid fraction from the second liquid fraction;
a second acidifying step, wherein the second liquid comprising the second solubilized polyaromatic compound is acidified at a temperature of at least about 90° C., thereby forming a fourth mixture comprising a second precipitated polyaromatic compound; and
a second collecting step, wherein at least a portion of the second precipitated polyaromatic compound is collected, thereby obtaining a second collected precipitated polyaromatic compound;
wherein a substantial portion of the second collected precipitated polyaromatic compound is not discarded and is not combusted.

14. The method of claim 13 , wherein at least a portion of the second collected precipitated polyaromatic compound is sold, bartered, traded, or any combination thereof; or
wherein at least a portion of the second collected precipitated polyaromatic compound is incorporated into a product capable of sale, barter, trade, or any combination thereof.

15. The method of claim 13 , wherein the second precipitated polyaromatic compound is selected from the group consisting of lignin, pseudolignin, a polyfuranic compound, and any combination thereof.

16. The method of claim 13 , wherein the second liquid comprising the second solubilized polyaromatic compound does not comprise spent liquor.

17. The method of claim 2 , wherein at least a portion of the first collected precipitated polyaromatic compound is incorporated into a product capable of sale, barter, trade, or any combination thereof, and the product is a thermoplastic.

18. The method of claim 2 , wherein at least a portion of the first collected precipitated polyaromatic compound is incorporated into a product capable of sale, barter, trade, or any combination thereof, and the product is an adhesive.

19. The method of claim 14 , wherein at least a portion of the second collected precipitated polyaromatic compound is incorporated into a product capable of sale, barter, trade, or any combination thereof, and the product is a thermoplastic.

20. The method of claim 14 , wherein at least a portion of the second collected precipitated polyaromatic compound is incorporated into a product capable of sale, barter, trade, or any combination thereof, and the product is an adhesive.

Assignees

• Renmatix Inc

Inventors

• Capanema Ewellyn A
• Balakshin Mikhail Y
• Kosa Matyas
• Harris Stephen Herbert

Classifications

• C08H8/00

  Macromolecular compounds derived from lignocellulosic materials {(pretreatment thereof B27N)} · CPC title

• C08G61/125

  with a five-membered ring containing one oxygen atom in the ring · CPC title

• C08G2261/3222

  containing one or more oxygen atoms as the only heteroatom, e.g. furan · CPC title

• C08G2261/3223

  containing one or more sulfur atoms as the only heteroatom, e.g. thiophene · CPC title

• C08G61/10 Primary

  only aromatic carbon atoms, e.g. polyphenylenes · CPC title