Modified conjugated diene polymer and method for preparing the same

Patent metadata

Field	Value
Publication number	US-10233265-B2
Application number	US-201615357734-A
Country	US
Kind code	B2
Filing date	Nov 21, 2016
Priority date	Feb 6, 2012
Publication date	Mar 19, 2019
Grant date	Mar 19, 2019

Abstract

Disclosed are a modified conjugated diene polymer and a method for preparing the same. The modified conjugated diene polymer and the method for preparing the same advantageously provide superior compatibility with an inorganic filler, heat generation, tensile strength and abrasion resistance, low fuel consumption and excellent resistance on wet roads.

First claim

What is claimed is:

1. A method for preparing a modified conjugated diene polymer comprising:
(a) polymerizing a conjugated diene monomer, or a conjugated diene monomer and an aromatic vinyl monomer in the presence of a solvent using an organometallic compound to prepare an active polymer having a metal end group; and
(b) adding a compound represented by the following Formula 2 to the active polymer to modify the active polymer:

wherein R 1 is an alkyl group, R 2 is an alkylene group, R 3 and R 4 are an alkyl group, a is an integer of 1 to 3, n is 1, and R 1 , R 3 and R 4 are identical or different.

2. The method according to claim 1 , wherein the organometallic compound is used in an amount of 0.01 to 10 mmol, based on 100 g in total of the monomer.

3. The method according to claim 1 , wherein a molar ratio of the organometallic compound and the compound represented by Formula 2 is 1:0.1 to 1:10.

4. The method according to claim 1 , wherein the polymerizing (a) further comprises adding a polar additive.

5. The method according to claim 4 , wherein the polar additive is added in an amount of 0.001 to 50 g, based on 1 mmol in total of the organometallic compound.

6. A modified conjugated diene polymer rubber composition comprising 0.1 to 200 parts by weight of an inorganic filler with respect to 100 parts by weight of a modified conjugated diene polymer,
wherein the modified conjugated diene polymer is represented by the following Formula 1:

wherein R 1 is an alkyl group, R 2 is an alkylene group, R 3 and R 4 are an alkyl group, a is an integer of 1 to 3, l and k are 1, m is 1, p is a conjugated diene polymer chain, and b is an integer of 1 to 3, wherein b is not greater than a.

7. The modified conjugated diene polymer rubber composition according to claim 6 , wherein the composition comprises 0 to 100 parts by weight of carbon black, 5 to 200 parts by weight of silica and 2 to 20 parts by weight of a silane coupling agent, with respect to 100 parts by weight of a polymer mixture comprising 10 to 100% by weight of the modified conjugated diene polymer and 0 to 90% by weight of another conjugated diene polymer.

8. The modified conjugated diene polymer rubber composition according to claim 6 , wherein the inorganic filler is a silica filler.

9. A tire comprising the modified conjugated diene polymer rubber composition according to claim 6 .

10. A modifying agent comprising a compound represented by the following Formula 2:

wherein R 1 is an alkyl group, R 2 is an alkylene group, R 3 and R 4 are an alkyl group, a is an integer of 1 to 3, n is 1, and R 1 , R 3 and R 4 are identical or different.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Ro Mi
• Lee Sang Mi
• Lee Choon Hwa
• Yoon Byung Hoon
• Kim Jin Young
• Chun Moon Seok

Classifications

• C08C19/44

  of polymers containing metal atoms exclusively at one or both ends of the skeleton · CPC title

• C08F236/10

  with vinyl-aromatic monomers · CPC title

• C08K3/36

  Silica · CPC title

• C08L15/00

  Compositions of rubber derivatives (C08L11/00, C08L13/00 take precedence) · CPC title

• C07F7/1804 Primary

  Compounds having Si-O-C linkages (Si-O-acyl linkages C07F7/1896) · CPC title