Defect detection method for monolithic separation membrane structures, repair method, and monolithic separation membrane structures

Patent metadata

Field	Value
Publication number	US-10232318-B2
Application number	US-201514661319-A
Country	US
Kind code	B2
Filing date	Mar 18, 2015
Priority date	Sep 28, 2012
Publication date	Mar 19, 2019
Grant date	Mar 19, 2019

Abstract

Each cell is pressurized with gas from outside of the cell, the amount of permeation of the gas permeated into each cell is measured, and a cell having the amount of permeation greater than (average value of all cells+A) (wherein A is a predetermined value of σ to 6σ, where σ is the standard deviation) is considered to be defective. Alternatively, pressure is reduced for each cell, the degree of vacuum in each cell is measured, and a cell having the degree of vacuum worse than (average value of all cells+A) is considered to be defective. Then, a polymer compound is poured into the defective cells of the monolithic separation membrane structure and cured so that the defective cells are sealed. Alternatively, the polymer compound formed in advance as the sealing member is inserted into the defective cells to seal the defective cells.

First claim

The invention claimed is:

1. A monolithic separation membrane structure comprising:
a monolithic substrate having a plurality of cells defined and formed by porous partition walls from one end face to an other end face in a longitudinal direction, and a separation membrane formed on inner wall faces of the cells;
wherein both end portions of cells that have defects in the separation membrane are sealed with sealing members through which fluid does not pass, and the sealing members extend into each of the cells that have defects at least 1 mm from each respective end face, and
wherein the sealing members are of polymer compound.

2. The monolithic separation membrane structure according claim 1 , wherein the polymer compound is a synthetic resin.

3. The monolithic separation membrane structure according to claim 2 , wherein the synthetic resin is one of epoxy, silicon-based, and fluorine-based resins.

4. The monolithic separation membrane structure according to claim 1 , wherein the separation membrane is formed of an inorganic material.

5. The monolithic separation membrane structure according to claim 4 , wherein the inorganic material is one of zeolite, carbon, and silica.

6. The monolithic separation membrane structure according to claim 4 , wherein the monolithic substrate is of a porous ceramic.

7. The monolithic separation membrane structure according to claim 4 , having a withstand pressure for use of 1 MPa or more.

8. The monolithic separation membrane structure according to claim 1 , wherein the monolithic substrate is of a porous ceramic.

9. The monolithic separation membrane structure according to claim 8 , having a withstand pressure for use of 1 MPa or more.

10. The monolithic separation membrane structure according to claim 1 , having a withstand pressure for use of 1 MPa or more.

11. The monolithic separation membrane structure according to claim 1 , wherein the sealing members completely fill the cells that have defects.

12. The monolithic separation membrane structure according to claim 1 ,
wherein the plurality of cells includes separation cells and water collection cells, and both end portions of the separation cells that have defects in the separation membrane are sealed with the sealing members.

Assignees

• Ngk Insulators Ltd

Inventors

• Miyahara Makoto
• Ichikawa Makiko
• Yajima Kenji
• Nakamura Shinji
• Nagasaka Ryujiro

Classifications

• G01M3/3254

  using a flow detector (G01M3/3245, G01M3/3272 take precedence) · CPC title

• B01D65/108 Primary

  Repairing membranes · CPC title

• B29C70/766

  on the end part of a tubular article · CPC title

• B29K2079/08

  PI, i.e. polyimides or derivatives thereof · CPC title

• B01D69/02

  characterised by their properties · CPC title