High strength steel wire for spring excellent in coiling performance and hydrogen embrittlement resistance and method for manufacturing same
US-2015101715-A1 · Apr 16, 2015 · US
US10227670B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10227670-B2 |
| Application number | US-201515113631-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 22, 2015 |
| Priority date | Jan 23, 2014 |
| Publication date | Mar 12, 2019 |
| Grant date | Mar 12, 2019 |
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To provide a piston ring of low-alloy steel having excellent nitridability, namely, a piston ring of low-alloy steel having excellent thermal conductivity and capable of being provided with a sufficient nitrided layer, steel comprising by mass 0.45-0.65% of C, 0.15-0.35% of Si, 0.65-1.00% of Mn and 0.60-1.10% of Cr as indispensable alloy elements, and less than 0.35% of Mo, less than 0.25% of V and less than 0.001% of B as optional alloy elements, the total amount of the indispensable alloy elements and the optional alloy elements being less than 3.0% by mass, is formed into a piston ring; and the nitrided layer is formed on its surface.
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What is claimed is: 1. A piston ring made of steel comprising C, Si, Mn and Cr as indispensable alloy elements, and Mo, V and B as optional alloy elements; said indispensable alloy elements having a composition comprising by mass 0.45-0.65% of C, 0.15-0.35% of Si, 0.65-1.00% of Mn, and 0.60-1.10% of Cr; said optional alloy elements having a composition comprising by mass less than 0.35% of Mo, less than 0.25% of V, and less than 0.001% of B; the total amount of said indispensable alloy elements and said optional alloy elements being less than 3.0% by mass; and a nitrided layer being formed on the surface; wherein the outermost surface of said nitride layer is a diffusion layer exposed by removing a compound layer; wherein said diffusion layer has hardness of 700-900 HV0.05 to the depth of 40 μm from said outermost surface and a hardness reduction ratio of 3 HV0.05/μm or less in a depth direction to the depth of 40 μm from said outermost surface; and wherein said steel contains C concentrated in prior austenite grain boundaries. 2. The piston ring according to claim 1 , whose base material has hardness, which is 90-100% of the hardness before nitriding. 3. The piston ring according to claim 1 , wherein prior austenite grains in said steel have a grain size number of 8 or more. 4. The piston ring according to claim 1 , wherein said steel has a structure in which spheroidal cementite is dispersed in a tempered martensite matrix. 5. The piston ring according to claim 1 , which is a compression ring having said nitrided layer formed on side surfaces of the piston ring. 6. A method for producing the piston ring recited in claim 1 from a wire made of steel comprising C, Si, Mn and Cr as indispensable alloy elements, and Mo, V and B as optional alloy elements; said indispensable alloy elements having a composition comprising by mass 0.45-0.65% of C, 0.15-0.35% of Si, 0.65-1.00% of Mn, and 0.60-1.10% of Cr; said optional alloy elements having a composition comprising by mass less than 0.35% of Mo, less than 0.25% of V, and less than 0.001% of B; and the total amount of said indispensable alloy elements and said optional alloy elements being less than 3.0% by mass; comprising conducting oil tempering at a quenching temperature of 820-930° C. and a tempering temperature of 440-500° C. before forming said piston ring; and conducting a strain-removing heat treatment at a temperature of 420-480° C., lower than said tempering temperature, and nitriding at a temperature within ±30° C. from said tempering temperature, after forming the piston ring. 7. The method for producing a piston ring according to claim 6 , wherein annealing is conducted before said oil tempering.
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