Fluorothermoplastic polymer compositions

Patent metadata

Field	Value
Publication number	US-10227484-B2
Application number	US-201515503098-A
Country	US
Kind code	B2
Filing date	Aug 13, 2015
Priority date	Aug 22, 2014
Publication date	Mar 12, 2019
Grant date	Mar 12, 2019

Abstract

Described herein is a composition comprising (i) a hydrofluorothermoplastic polymer, wherein the hydrofluorothermoplastic polymer is derived from: (a) 50-85 mol % tetrafluoroethene; (b) 2-15 mol % hexafluoropropene; (c) 10-35 mol % vinylidene fluoride; and (d) 0.1 to 5 mol % of a bromine-containing monomer; and (ii) a perhalogenated thermoplastic polymer. Such compositions can be used in multilayer constructions in, for example, fuel hose applications.

First claim

What is claimed is:

1. A composition comprising
(i) a hydrofluorothermoplastic polymer, wherein the hydrofluorothermoplastic polymer is derived from:
(a) 50-85 mol % tetrafluoroethene;
(b) 2-15 mol % hexafluoropropene;
(c) 10-35 mol % vinylidene fluoride; and
(d) 0.1 to 5 mol % of a bromine-containing monomer; and

(ii) a perhalogenated thermoplastic polymer having a melting point of 150 to 315° C. with the ratio of the hydrofluorothermoplastic polymer to the perhalogenated thermoplastic polymer on a mass to mass basis of 10:90 and 90:10 and wherein the composition has a permeation constant of less than 2.5 g mm/m 2 d when measured at 60° C. with CE10 fuel.

2. The composition according to claim 1 , wherein the perhalogenated thermoplastic polymer is selected from FEP, PFA, and a homopolymer or copolymer comprising CTFE.

3. The composition of claim 1 , wherein the composition comprises a blend of the hydrofluorothermoplastic polymer and the perhalogenated thermoplastic polymer.

4. The composition of claim 1 , wherein the composition comprises a core-shell particle, wherein (i) the core comprises the perhalogenated thermoplastic polymer and the shell comprises the hydrofluorothermoplastic polymer or (ii) the core comprises the hydrofluorothermoplastic polymer and the shell comprises the perhalogenated thermoplastic polymer.

5. The composition of claim 1 , wherein the hydrofluorothermoplastic polymer is further derived 0.1-5 mol % of a fluorinated allyl ether monomer and/or fluorinated vinyl ether monomer.

6. The composition of claim 1 , wherein the bromine-containing monomer is fluorinated.

7. The composition of claim 1 , wherein the bromine-containing monomer is selected from F 2 C═CHBr, F 2 C═CFBr, H 2 C═CH—CF 2 —CF 2 —Br, H 2 C═CH—CF 2 —Br, F 2 C═CF—O—(CF 2 ) x —Br, F 2 C═CF—O—CF(CF 3 )—CF 2 —O—(CF 2 ) x —Br, F 2 C═CF—CF 2 —O—(CF 2 ) x —Br, H 2 C═CH—CH 2 —Br, F 2 C═CF—O—CF 2 —CFBr—CF 3 , and combinations thereof, where x is 2, 3, 4, or 5.

8. The composition of claim 5 , wherein the fluorinated vinyl ether monomer is selected from perfluoro(methyl vinyl ether) (PMVE), perfluoro(ethyl vinyl ether) (PEVE), perfluoro(n-propyl vinyl ether) (PPVE-1), perfluoro(2-propoxypropyl vinyl ether) (PPVE-2), perfluoro(3-methoxy-n-propyl vinyl ether), perfluoro(2-methoxyethyl vinyl ether), CF 3 —(CF 2 ) 2 —O—CF(CF 3 )—CF 2 —O—CF(CF 3 )—CF 2 —O—CF═CF 2 (PPVE-3), and combinations thereof.

9. The composition of claim 5 , wherein the fluorinated allyl ether monomer is selected from perfluoro(methyl allyl ether), perfluoro(ethyl allyl ether), perfluoro(n-propyl allyl ether), perfluoro(2-propoxypropyl allyl ether), perfluoro(3-methoxy-n-propyl allyl ether), perfluoro(2-methoxyethyl allyl ether), CF 3 —(CF 2 ) 2 —O—CF(CF 3 )—CF 2 —O—CF(CF 3 )—CF 2 —O—CF 2 CF═CF 2 , and combinations thereof.

10. A multilayer article comprising:
a first polymer layer comprising the composition of claim 1 ; and
a second polymer layer wherein the second polymer layer is an elastomer
wherein the first polymer layer is intimate contact with the second polymer layer.

11. The multilayer article of claim 10 , wherein a bonding interface between the first polymer layer and the second polymer layer consists essentially of a first material having the composition of the first polymer layer and a second material having the composition of the second polymer layer.

12. The multilayer article of claim 10 , wherein the first polymer layer and the second polymer layer have a peel strength of at least 1 lb/in.

13. The multilayer article of claim 10 , further comprising a third layer, wherein the third layer is bonded to the first polymer layer or the second polymer layer.

14. The multilayer article of claim 10 , wherein the multilayer article is a hose.

15. A method of making a composition comprising:
(i) providing a first latex comprising a hydrofluorothermoplastic polymer derived from:
(a) 50-85 mol % tetrafluoroethene;
(b) 2-15 mol % hexafluoropropene;
(c) 10-35 mol % vinylidene fluoride monomer; and
(d) 0.1 to 5 mol % of a bromine-containing monomer; and

(ii) providing a second latex comprising a perhalogenated thermoplastic polymer having a melting point of 150 to 315° C.;
(iii) combining the first latex and the second latex to form a latex blend; and
(iv) further processing the latex blend to form a dry powder.

16. A method of making a composition comprising:
(i) providing a core comprising a perhalogenated thermoplastic polymer having a melting point of 150 to 315° C.;
(ii) polymerizing around the core, a shell comprising a hydrofluorothermoplastic polymer derived from:
(a) 50-85 mol % tetrafluoroethene;
(b) 2-15 mol % hexafluoropropene;
(c) 10-35 mol % vinylidene fluoride; and
(d) 0.1 to 5 mol % of a bromine-containing monomer.

17. A method of making a composition comprising:
(i) providing a core comprising a hydrofluorothermoplastic polymer derived from:
(a) 50-85 mol % tetrafluoroethene;
(b) 2-15 mol % hexafluoropropene;
(c) 10-35 mol % vinylidene fluoride; and
(d) 0.1 to 5 mol % of a bromine-containing monomer

(ii) polymerizing around the core, a shell comprising a perhalogenated thermoplastic polymer having a melting point of 150 to 315° C.

Assignees

• 3M Innovative Properties Co

Inventors

• Chen Lisa P
• Hintzer Klaus
• Kaspar Harald
• Lochhaas Kai H
• Muggli Mark W
• Schrooten Jens
• Sohlo Allen M
• Traunspurger Helmut
• Weilandt Karl D
• Zipplies Tilman C

Classifications

• B32B27/322

  comprising halogenated polyolefins, e.g. PTFE · CPC title

• C08F214/222

  with fluorinated vinyl ethers · CPC title

• B32B1/08

  Tubular products · CPC title

• B32B25/12

  comprising natural rubber · CPC title

• B32B27/304

  comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF · CPC title