Method for controlling the process for making isocyanates

Patent metadata

Field	Value
Publication number	US-10227294-B2
Application number	US-201615767870-A
Country	US
Kind code	B2
Filing date	Sep 28, 2016
Priority date	Oct 16, 2015
Publication date	Mar 12, 2019
Grant date	Mar 12, 2019

Abstract

The invention relates to a method for preparing an aromatic polyisocyanate in an isocyanate plant comprising a reaction section for a phosgenation reaction, wherein a primary aromatic amine is reacted with phosgene compounds in a reaction section to obtain an isocyanate comprising reaction product and wherein CO2 concentration in the gases coming from the reaction section is measured and analyzed, and wherein the conditions in the phosgenation reaction are adjusted in case the CO2 concentration in the gases coming from the reaction section is higher than a background CO2 concentration.

First claim

The invention claimed is:

1. A method for preparing an aromatic polyisocyanate in an isocyanate plant comprising a reaction section for a phosgenation reaction, the method comprising the steps of:
a) providing a primary aromatic amine stream and a phosgene stream via an inlet in the reaction section;
b) reacting the primary aromatic amines with the phosgene compounds in the reaction section to obtain an isocyanate comprising reaction product;
c1) measuring CO 2 concentration in the gases coming from the reaction section;
d1) analyzing the CO 2 concentration coming from the reaction section by comparing with a background CO 2 concentration, wherein the background CO 2 concentration comprises the CO 2 concentration in the phosgene stream;
e) adjusting conditions in the phosgenation reaction in case the CO 2 concentration in the gases coming from the reaction section is higher than a background CO 2 concentration and/or deviates with more than 2 vol %, in view of the total volume of the gases coming from the reaction section.

2. A method for preparing an aromatic polyisocyanate in an isocyanate plant comprising a reaction section for a phosgenation reaction and a work-up section which is downstream of the reaction section and treats an isocyanate comprising stream, the method comprising the steps of:
a) providing a primary aromatic amine stream and phosgene stream via an inlet in the reaction section;
b) reacting the primary aromatic amine compounds with the phosgene compounds in the reaction section to obtain an isocyanate comprising reaction product;
c2) measuring CO 2 concentration in the gases coming from the reaction section and the work-up section;
d2) analyzing the CO 2 concentration coming from the reaction section and the work-up section by comparing with a background CO 2 concentration range;
e) adjusting conditions in the phosgenation reaction in case the CO 2 concentration in the gases coming from the reaction section and the work-up section is higher than a background CO 2 concentration and/or deviates with more than 2 vol %, preferably in view of the total volume of the gases coming from the reaction section.

3. The method according to claim 1 , wherein the inlet comprises a mixing nozzle having at least two conduits one providing the primary aromatic amine stream and one providing the phosgene stream and of which the conduits have a conduit end opening where the primary aromatic amine stream and phosgene stream are discharged in the reaction section.

4. The method according to claim 3 , wherein the adjustment of the conditions of the phosgenation reaction is the adjustment of the size of at least one conduit end opening in the nozzle.

5. The method according to claim 4 , wherein the adjustment of the size is decreasing the size of at least one conduit end opening.

6. The method according to claim 3 , wherein the adjustment of the conditions of the phosgenation reaction is the adjustment of the angle of at least one of the conduits.

7. The method according to claim 3 , wherein the adjustment of the conditions of the phosgenation reaction is the adjustment of the distance between at least two of the conduits.

8. The method according to claim 1 , wherein the inlet comprises a mixing device which is a rotor-stator mixer having a rotor and the adjustment of the conditions of the phosgenation reaction is the adjustment of the speed of the rotor.

9. The method according to claim 1 , wherein the adjustment of the conditions of the phosgenation reaction is adjusting the flow ratio of the primary aromatic amine compounds stream and the phosgene stream at the inlet of the reaction section, by decreasing or increasing the flow ratio.

10. The method according to claim 1 , wherein the adjustment of the conditions of the phosgenation reaction is adjusting the pressure in the reaction section.

11. The method according to claim 1 , wherein the adjustment of the conditions of the phosgenation reaction is adjusting the temperature in the reaction section.

12. The method according to claim 1 , wherein the adjustment of the conditions of the phosgenation reaction is adjusting the residence time of the reaction mixture of the primary aromatic amine compounds with the phosgene compounds in the reaction section.

13. The method according to claim 1 , wherein the adjustment of the conditions of the phosgenation reaction is adjusting the concentration of the primary aromatic amine in the primary aromatic amine stream and/or the phosgene compounds in the phosgene stream.

14. The method according to claim 1 , wherein the CO 2 concentration is measured via infrared, gas chromatography, titration, near infrared, and/or UV.

15. The method according to claim 1 , wherein the background CO 2 concentration further comprises the CO 2 concentration in the primary aromatic amine stream.

Assignees

• Huntsman Int Llc

Inventors

• Muller Peter
• Carr Robert Henry

Classifications

• B01J2219/00186

  controlling the composition of the reactive mixture · CPC title

• B01J2219/00051

  Controlling the temperature · CPC title

• B01J2219/00166

  controlling the residence time inside the reactor vessel · CPC title

• B01J2219/00202

  at the reactor outlet · CPC title

• C07C263/10 Primary

  by reaction of amines with carbonyl halides, e.g. with phosgene · CPC title