Method for making ceramic matrix composite articles

Patent metadata

Field	Value
Publication number	US-10227264-B2
Application number	US-201514798019-A
Country	US
Kind code	B2
Filing date	Jul 13, 2015
Priority date	Jul 13, 2015
Publication date	Mar 12, 2019
Grant date	Mar 12, 2019

Abstract

A method of forming a composite article may include impregnating an inorganic fiber porous preform with a first slurry composition. The slurry composition includes particles, a solvent, and a pre-gellant material. Gelling of the pre-gellant material in the slurry composition is initiated to substantially immobilize the particles and yield a gelled article. The method also includes impregnating the gelled article with a second solution that includes a high char-yielding component, and pyrolyzing the high char-yielding component to yield carbon and form a green composite article. The green composite article is then infiltrated with a molten metal or alloy infiltrant to form the composite article. The molten infiltrant reacts with carbon, and the final composite article may include less residual metal or alloy than a composite article formed without using the second solution.

First claim

The invention claimed is:

1. A method comprising:
impregnating an inorganic fiber porous preform with a first slurry composition, wherein the first slurry composition comprises ceramic particles, a solvent, and a pre-gellant material;
initiating gelation of the pre-gellant material in the first slurry composition to substantially immobilize the particles and yield a gelled article;
heating the gelled article to substantially remove the gel and open pores;
impregnating the open pores with a second solution, wherein the second solution is different from the first slurry composition, and comprises a high char-yielding component, wherein the second solution does not comprise ceramic particles, and wherein the first slurry composition does not include the high char-yielding component;
pyrolyzing the high char-yielding component to yield carbon and form a green composite article; and
infiltrating the green composite article with a molten metal or alloy to form a final composite article, wherein at least some of the molten metal or alloy reacts with the carbon to form a metal carbide.

2. The method of claim 1 , wherein the high char-yielding component comprises at least one of furfuryl alcohol or a phenolic material.

3. The method of claim 1 , wherein the second solution further comprises at least one of a second solvent, a polymer interrupter, an acid catalyst, and a secondary polymer.

4. The method of claim 3 , wherein the second solvent comprises water.

5. The method of claim 3 , wherein the polymer interrupter comprises an alcohol.

6. The method of claim 3 , wherein the acid catalyst comprises at least one of nitric acid, hydrochloric acid, or paratoluene sulfonic acid (PTSA).

7. The method of claim 3 , wherein the secondary polymer comprises at least one of poly(ethylene glycol), polyvinyl alcohol (PVA), or polyvinyl pyrollidone (PVP).

8. The method according to claim 3 , wherein the inorganic fiber preform comprises at least one coating comprising at least one of carbon, aluminum nitride, boron nitride, silicon nitride, silicon carbide, boron carbide, a metal boride, a transition metal silicide, a transition metal oxide, a transition metal silicate, or a rare earth metal silicate.

9. The method of claim 1 , further comprising, after impregnating the gelled article with the second solution, heating the gelled article including the second solution to polymerize the high char-yielding component.

10. The method according to claim 1 , wherein the pre-gellant material comprises at least one of a monomer that is polymerized to form a gel or a polysaccharide.

11. The method according to claim 1 , wherein the inorganic fiber preform comprises fibers comprising at least one of aluminum oxide (Al 2 O 3 ), mullite (Al 6 Si 2 O 13 ), zirconium oxide (ZrO 2 ), carbon (C), graphite, silicon carbide, silicon carbonitride, or silicon nitride.

12. The method according to claim 1 , where the particles in the first slurry composition comprises at least one of aluminum nitride, aluminum diboride, boron carbide, aluminum oxide, mullite, zirconium oxide, carbon, silicon carbide, silicon nitride, a transition metal nitride, a transition metal boride, a transition metal oxide, a transition metal silicate, or a rare earth oxide.

13. A method comprising:
impregnating a silicon carbide fiber porous preform with a first slurry composition, wherein the first slurry composition comprises silicon carbide particles, a solvent, and a pre-gellant material;
initiating gelation of the pre-gellant material in the first slurry composition to substantially immobilize the silicon carbide particles and yield a gelled article;
heating the gelled article to substantially remove the gel and open pores while leaving silicon carbide particles in the silicon carbide fiber porous preform;
impregnating the open pores with a second solution, wherein the second solution is different from the first slurry composition, and comprises furfuryl alcohol, wherein the second solution does not comprise ceramic particles, and wherein the first slurry composition does not include a high char-yielding component;
pyrolyzing the furfuryl alcohol to yield carbon and form a green composite article; and
infiltrating the green composite article with a molten material infiltrant comprising silicon to form a final composite article, wherein at least some of the silicon reacts with the carbon to form silicon carbide.

14. The method of claim 13 , further comprising, after impregnating the gelled article with the second solution, heating the gelled article including the second solution to polymerize the furfuryl alcohol.

15. The method of claim 13 , further comprising, after heating the gelled article including the second solution to polymerize the furfuryl alcohol, heating the gelled article including polymerized furfuryl alcohol to substantially remove other components of the second solution.

16. The method of claim 13 , wherein the second solution further comprises a second solvent, a polymer interrupter, an acid catalyst, and a secondary polymer.

17. The method of claim 16 , wherein the second solvent comprises water, the polymer interrupter comprises an alcohol, the acid catalyst comprises nitric acid, and the secondary polymer comprises polyethylene glycol.

Assignees

• Rolls Royce High Temperature Composites Inc

Inventors

• Harris Stephen Isaiah

Classifications

• C04B2235/728

  Silicon content · CPC title

• C04B2235/616

  Liquid infiltration of green bodies or pre-forms · CPC title

• C04B2235/6023

  Gel casting · CPC title

• C04B2235/5248

  Carbon, e.g. graphite · CPC title

• C04B2235/5244

  Silicon carbide · CPC title