Intermediate film for laminated glass, and laminated glass

Patent metadata

Field	Value
Publication number	US-10226912-B2
Application number	US-201314371938-A
Country	US
Kind code	B2
Filing date	Jan 11, 2013
Priority date	Jan 13, 2012
Publication date	Mar 12, 2019
Grant date	Mar 12, 2019

Abstract

An interlayer film for laminated glass that can improve a sound insulation property of an obtained laminated glass when the interlayer film for laminated glass is used for configuring the laminated glass is provided. The interlayer film for laminated glass according to the present invention includes a first layer and a second layer laminated on a first surface of the first layer. The first layer includes a polyvinyl acetate resin and a plasticizer.

First claim

The invention claimed is:

1. An interlayer film for laminated glass comprising:
a first layer;
a second layer laminated on a first surface of the first layer; and
a third layer laminated on a second surface opposite to the first surface of the first layer,
wherein the first layer comprises a combination of a thermoplastic resin and a plasticizer,
the thermoplastic resin in the first layer consists essentially of a polyvinyl acetate homopolymer resin,
a polymerization degree of the polyvinyl acetate homopolymer resin in the first layer is 1500 or more and 15,000 or less,
the plasticizer in the first layer is at least one of (a) triethylene glycol di-n-butanoate, (b) triethylene glycol di-n-propanoate, and (c) an ester compound of adipic acid and an alcohol having a linear or a branched structure having a carbon number of 4 to 8,
the combination of the polyvinyl acetate homopolymer resin and the plasticizer comprised in the first layer has a cloud point of 80° C. or less when the cloud point is measured using a solution in which 8 parts by weight of the polyvinyl acetate homopolymer resin is dissolved in 100 parts by weight of the plasticizer,
the second layer comprises a polyvinyl acetal resin and a plasticizer,
the polyvinyl acetal resin in the second layer has an acetylation degree of 15 mol % or less and a hydroxyl group content of 20 mol % or more,
the plasticizer in the second layer is at least one of (a) triethylene glycol di-n-butanoate, (b) triethylene glycol di-n-propanoate, and (c) an ester compound of adipic acid and an alcohol having a linear or a branched structure having a carbon number of 4 to 8, and
a content in parts by weight of the plasticizer in the second layer to 100 parts by weight of the polyvinyl acetal resin in the second layer is 5 parts by weight or more 50 parts by weight or less.

2. The interlayer film for laminated glass according to claim 1 ,
wherein the first layer comprises a tackifier.

3. The interlayer film for laminated glass according to claim 2 , wherein the first layer consists essentially of the thermoplastic resin, the plasticizer, and the tackifier.

4. The interlayer film for laminated glass according to claim 1 ,
wherein the third layer comprises a polyvinyl acetal resin; and
the polyvinyl acetal resin in the third layer has an acetylation degree of 15 mol % or less and a hydroxyl group content of 20 mol % or more.

5. The interlayer film for laminated glass according to claim 4 ,
wherein the first layer comprises a tackifier; and
the tackifier is a rosin resin.

6. The interlayer film for laminated glass according to claim 1 , wherein a thickness of the first layer is 0.02 mm to 0.5 mm, a thickness of the second layer is 0.1 mm to 0.5 mm, and a thickness of the third layer is 0.1 mm to 0.5 mm.

7. The interlayer film for laminated glass according to claim 1 , wherein a content in parts by weight of the plasticizer in the second layer to 100 parts by weight of the polyvinyl acetal resin in the second layer is less than a content in parts by weight of the plasticizer in the first layer to 100 parts by weight of the polyvinyl acetate, homopolymer resin in the first layer.

8. The interlayer film for laminated glass according to claim 7 , wherein the third layer comprises a polyvinyl acetal resin and a plasticizer, a content in parts by weight of the plasticizer in the third layer to 100 parts by weight of the polyvinyl acetal resin in the third layer being less than the content in parts by weight of the plasticizer in the first layer to 100 parts by weight of the polyvinyl acetate homopolymer resin in the first layer.

9. The interlayer film for laminated glass according to claim 8 , wherein an absolute value of a difference between (A) the content in parts by weight of the plasticizer in the first layer to 100 parts by weight of the polyvinyl acetate resin in the first layer and each of (B1) the content in parts by weight of the plasticizer in the second layer to 100 parts by weight of the polyvinyl acetate homopolymer resin in the second layer, and (B2) the content in parts by weight of the plasticizer in the third layer to 100 parts by weight of the polyvinyl acetal resin in the third layer is 5 parts by weight or more.

10. A laminated glass comprising:
a first component for laminated glass,
a second component for laminated glass, and
an interlayer film sandwiched between the first component for laminated glass and the second component for laminated glass,
wherein the interlayer film is the interlayer film for laminated glass according to claim 1 .

Assignees

• Sekisui Chemical Co Ltd

Inventors

• Shimamoto Michio
• Matsuda Shota
• Yang Sinyul

Classifications

• Y10T428/31859

  Next to an aldehyde or ketone condensation product · CPC title

• B32B2250/40

  Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA · CPC title

• Y10T428/31935

  Ester, halide or nitrile of addition polymer · CPC title

• C08K5/0016

  Plasticisers · CPC title

• B32B17/10036

  comprising two outer glass sheets · CPC title