Process for producing a catalyst and catalyst as such

Patent metadata

Field	Value
Publication number	US-10226765-B2
Application number	US-201515129645-A
Country	US
Kind code	B2
Filing date	Mar 27, 2015
Priority date	Mar 27, 2014
Publication date	Mar 12, 2019
Grant date	Mar 12, 2019

Abstract

To be able to produce an SCR catalyst ( 2 ), in particular one having a zeolite fraction (Z) as catalytically active fraction, in a reliable process and at the same time achieve good catalytic activity of the catalyst ( 2 ), an inorganic binder fraction (B) which is catalytically inactive in the starting state and has been treated to develop catalytic activity is mixed into a catalyst composition ( 4 ). The inorganic binder component for the binder fraction (B) is, in the starting state, preferably porous particles ( 10 ), in particular diatomaceous earth, which display mesoporosity. To effect catalytic activation, the individual particles ( 10 ) are either coated with a catalytically active layer ( 12 ) or transformed into a catalytically active zeolite ( 14 ) with maintenance of the mesoporosity.

First claim

The invention claimed is:

1. A process for producing an extruded catalyst, the process comprising extruding a catalyst composition to produce the extruded catalyst body, wherein the catalyst composition comprises an inorganic binder fraction comprising silicate-based particles, at least a portion of which silicate-based particles comprise:
(a) particles of diatomaceous earth each coated with a layer of a catalytically active zeolite;
(b) particles of diatomaceous earth comprising an internal catalytically active zeolite structure; or
(c) both (a) and (b);

such that the silicate-based particles exhibit rheological properties suitable for extrusion.

2. The process according to claim 1 , wherein the extruded catalyst composition further comprises a catalytically active component admixed with the inorganic binder fraction.

3. The process according to claim 2 , wherein the catalytically active component comprises a molecular sieve-based catalyst, a titanium-vanadium-based catalyst, or a tungsten oxide-cerium oxide-based catalyst.

4. The process according to claim 3 , wherein the titanium-vanadium-based catalyst is a titanium-vanadium system, a titanium-vanadium-tungsten system, a titanium-vanadium-tungsten silicon system, a titanium-vanadium-silicon system, a titanium-vanadium-tungsten-iron system, a titanium-vanadium-tungsten-silicon-iron system or a titanium-vanadium-silicon-iron system.

5. The process according to claim 3 , wherein the tungsten oxide-cerium oxide-based catalyst is a Fe—W/CeO 2 system or a Fe—W/CeZrO 2 system.

6. The process according to claim 2 , wherein the catalytically active component comprises a crystalline aluminosilicate zeolite.

7. The process according to claim 6 , wherein the crystalline aluminosilicate zeolite has the framework structure CHA, AEI, ERI, MFI, BEA, FAU, AFX or FER.

8. The process according to claim 6 , wherein the crystalline aluminosilicate zeolite is activated with copper or iron.

9. The process according to claim 1 , wherein the diatomaceous earth particles have a mesoporosity or macroporosity with pores having diameters greater than 2 nm.

10. The process according to claim 9 , wherein the particles of diatomaceous earth have pores with diameters greater than 5 nm.

11. The process according to claim 1 , wherein the particles of the inorganic binder fraction comprises particles of diatomaceous earth, each coated with the layer of catalytically active zeolite.

12. The process according to claim 11 , wherein the layer of catalytically active zeolite has a thickness that is less than 20% of the average particle diameter of the particles of diatomaceous earth.

13. The process of claim 11 , wherein the particles of diatomaceous earth, each coated with the layer of catalytically active zeolite, are prepared by coating particles of diatomaceous earth with catalytically active zeolite particles.

14. The process of claim 11 , wherein the particles of diatomaceous earth, each coated with the layer of catalytically active zeolite, are prepared by coating particles of diatomaceous earth with catalytically inactive zeolite particles to form a coated composition and subjecting the coated composition to an exchange with one or more ions of a catalytically active metal.

15. The process according to claim 1 , wherein the inorganic binder comprises particles of diatomaceous earth comprising an internal catalytically active zeolite structure.

16. The method of claim 15 , wherein the particles of diatomaceous earth that have been transformed to contain an internal catalytically active zeolite structure are prepared by:
(a) hydrothermally treating particles of diatomaceous earth under conditions sufficient to crystallize at least a portion of the internal structure of the particles of the diatomaceous earth to form hydrothermally treated particles containing a zeolite structure and having a morphology of the diatomaceous earth particles;
(b) calcining the hydrothermally treated particles to form calcined particles having a morphology of the diatomaceous earth particles; and
(c) subjecting the calcined particles to an exchange with one or more ions of a catalytically active metal.

17. The method of claim 16 , wherein the one or more ions of a catalytically active metal comprise copper or iron ions.

18. The process according to claim 1 , wherein the particles of diatomaceous earth have an average particle diameter in the range of from 1 micron to 100 microns.

19. The process according to claim 18 , wherein catalytically active layer thickness is in the range of from 0.5 micron to 10 microns.

20. A catalyst produced by a process according to claim 1 .

Assignees

• Johnson Matthey Plc

Inventors

• Bauer Juergen
• Dotzel Ralf
• Muench Joerg Werner

Classifications

• B01D2255/20761

  Copper · CPC title

• B01J29/076

  containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium · CPC title

• B01J37/0009 Primary

  Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst · CPC title

• B01J29/58

  containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium · CPC title

• B01J2229/186

  not in framework positions · CPC title