Synthesis and incorporation of high-temperature ammonia-release agent in lit-end cigarettes

Patent metadata

Field	Value
Publication number	US-10226065-B2
Application number	US-201715427437-A
Country	US
Kind code	B2
Filing date	Feb 8, 2017
Priority date	Oct 25, 2004
Publication date	Mar 12, 2019
Grant date	Mar 12, 2019

Abstract

A tobacco smoking mixture and/or a cigarette wrapper with high-temperature ammonia-release agents therein are provided, wherein the high-temperature ammonia-release agents are present in an amount effective to reduce the cytotoxicity of gas phase or particulate matter formed during smoking of the cigarette. The high-temperature ammonia-release agents can be formed by heating an aqueous mixture of an iron precursor compound, an ammonia source compound and an acid.

First claim

What is claimed is:

1. A method of making high-temperature ammonia-release agents, comprising:
forming an aqueous solution of an iron precursor compound, an ammonia source compound, and orthophosphoric acid; and
heating the solution to a temperature sufficient to precipitate the high-temperature ammonia-release agents from the solution, wherein the iron precursor compound is selected from the group consisting of oxidized iron particles, lepidocrocite, phosphosiderite and goethite.

2. The method of claim 1 , wherein the forming the aqueous solution comprises forming the aqueous solution using an ammonia source compound selected from the group consisting of ammonium dihydrogen phosphate, diammonium hydrogen phosphate, ammonia gas, ammonium carbonate, ammonium bicarbonate, ammonium hydroxide and urea.

3. The method of claim 1 , wherein a solution of the iron precursor compound, the ammonia source compound and the orthophosphoric acid are stirred in an open unpressurized vessel.

4. The method of claim 3 , wherein a precipitate of ammonium iron (III) bis-hydrogen phosphate hydrate is precipitated from the solution.

5. The method of claim 4 , wherein the precipitate is filtered, washed and dried to produce a free flowing crystalline high-temperature ammonia release powder.

6. The method of claim 1 , further comprising heating an aqueous solution of iron oxide hydroxide and orthophosphoric acid and precipitating a phosphosiderite intermediate precipitate from the solution, adding ammonium dihydrogen phosphate and precipitating ammonium iron (III) bis-hydrogen phosphate hydrate.

7. The method of claim 1 , wherein FeOOH is combined with a first solution of H 3 PO 4 and NH 4 H 2 PO 4 in water to form a second solution, stirring the second solution, and precipitating the high-temperature ammonia release agents.

8. The method of claim 1 , wherein FeOOH is combined with H 3 PO 4 in boiling water, adding NH 4 H 2 PO 4 to the boiling water, stirring and precipitating the high-temperature ammonia release agents.

9. The method of claim 1 , wherein the high-temperature ammonia release agents release ammonia at a temperature of at least about 200° C.

10. The method of claim 1 , further comprising incorporating the high-temperature ammonia release agents in tobacco cut filler.

11. The method of claim 1 , further comprising incorporating the high-temperature ammonia release agents in reconstituted tobacco.

12. The method of claim 1 , further comprising incorporating the high-temperature ammonia release agents in a cigarette wrapper.

13. The method of claim 1 , further comprising incorporating the high-temperature ammonia release agents in a web of fibrous cellulosic material.

14. The method of claim 1 , further comprising incorporating the high-temperature ammonia release agents in web-filler material.

15. The method of claim 1 , further comprising incorporating the high-temperature ammonia release agents in a slurry and spraying the slurry onto tobacco cut filler.

16. The method of claim 1 , further comprising incorporating the high-temperature ammonia release agents in a slurry and spraying the slurry onto a base web during a papermaking process.

17. The method of claim 1 , further comprising incorporating the high-temperature ammonia release agents in a cigarette wrapper having a permeability of about 2 Coresta units to about 200 Coresta units.

18. The method of claim 1 , further comprising dusting moistened tobacco cut filler with particles of the high-temperature ammonia release agents.

19. The method of claim 1 , further comprising dusting a slurry of reconstituted tobacco material with particles of the high-temperature ammonia release agents.

Assignees

• Philip Morris Usa Inc

Inventors

• Fournier Jay A
• Paine John B
• Fernandez Douglas A

Classifications

• A24B15/30

  by organic substances {(A24B15/281 takes precedence)} · CPC title

• C01B25/451

  containing metal and ammonium · CPC title

• A24B15/42

  by organic and inorganic substances {(A24B15/281 takes precedence)} · CPC title

• A24D1/02

  with special covers · CPC title

• A24D1/002

  with additives, e.g. for flavouring · CPC title