Positive electrode active material precursor for lithium secondary battery, positive electrode active material manufactured by using thereof, and lithium secondary battery including the same

Patent metadata

Field	Value
Publication number	US-10224541-B2
Application number	US-201514926282-A
Country	US
Kind code	B2
Filing date	Oct 29, 2015
Priority date	Jun 8, 2012
Publication date	Mar 5, 2019
Grant date	Mar 5, 2019

Abstract

Positive electrode active materials are provided. The positive electrode active materials includes a primary particle formed of a plurality of metals including a first metal and a secondary particle formed of at least one of the primary particle. The secondary particle includes a core part, a shell part, a seed region where the primary particle having concentration gradient of the first metal is disposed and a maintain region where the primary particle having constant concentration of the first metal is disposed, the seed region adjacent to the core part and a maintain region adjacent to the sell part, and length of the seed region in a direction from the core part to the shell part is 1 μm.

First claim

What is claimed is:

1. A positive electrode active material comprising:
a primary particle formed of a plurality of metals including a first metal; and
a secondary particle formed of at least one of the primary particle, wherein the secondary particle includes
a core part,
a shell part,
a seed region where the primary particle having concentration gradient of the first metal is disposed and
a maintain region where the primary particle having constant concentration of the first metal is disposed,

wherein the seed region is adjacent to the core part,
wherein the maintain region is adjacent to the shell part,
wherein a length of the seed region in a direction from the core part to the shell part is at least 1 μm,
wherein a crystal structure of the primary particle has an a-axis and a c-axis,
wherein the a-axis is in a direction from the core part to the shell part of the secondary particle, and a c-axis is perpendicular to the a-axis, and
wherein a ratio of an a-axis direction length to a c-axis direction length of the primary particle gradually increases from the core part to the shell part of the secondary particle.

2. The positive electrode active material of claim 1 , wherein the primary particle comprises:
a seed portion disposed in the seed region and having concentration gradient of the first metal; and
a maintain portion disposed in the maintain region, having constant concentration of the first metal and extending to the shell part from the core part.

3. The positive electrode active material of claim 2 , wherein
the secondary particle further comprises an intermediate region disposed between the seed region and the maintain region,
the primary particle further comprises an intermediate portion disposed in the intermediate region, and
the intermediate portion comprises a gradient portion having concentration gradient of the first metal and a uniform portion having constant concentration of the first metal.

4. The positive electrode active material of claim 2 , wherein a concentration of the first metal in the seed portion decreases as going in a direction from the core part to the shell part.

5. The positive electrode active material of claim 2 , wherein the seed portion is higher than the maintain portion in concentration of the first metal.

6. The positive electrode active material of claim 2 , wherein the seed portion and/or the maintain portion have a rod shape radiating in a direction from the core part to the shell part.

7. The positive electrode active material of claim 2 , wherein the plurality of the metals further comprises a second metal and a third metal, at least one of the second metal and the third metal show increasing concentration gradient in the seed portion.

8. The positive electrode active material of claim 1 , wherein the maintain region is longer than the seed region in a direction from the core part to the shell part.

9. The positive electrode active material of claim 1 , wherein the first metal includes nickel (Ni).

10. A positive electrode active material comprising:
a primary particle having an intermediate portion, the intermediate portion including a gradient portion which shows concentration gradient of a first metal and a uniform portion which extends from an end of the gradient portion and shows constant concentration of the first metal; and
a secondary particle composed of at least one of the primary particle, the secondary particle comprising a core part and a shell part,
wherein a crystal structure of the primary particle has an a-axis and a c-axis,
wherein the a-axis is in a direction from the core part to the shell part of the secondary particle, and a c-axis is perpendicular to the a-axis, and
wherein a ratio of an a-axis direction length to a c-axis direction length of the primary particle adjacent to the core part of the secondary particle is shorter than the ratio of the primary particle adjacent to the shell part of the secondary particle.

11. The positive electrode active material of claim 10 , wherein the gradient portion and the uniform portion are in one body.

12. The positive electrode active material of claim 10 , wherein the secondary particle further comprises a seed region adjacent to the core part and a maintain region adjacent to the shell part, and
wherein the primary particle comprises:
a seed portion disposed in the seed region and having concentration gradient of the first metal; and
a maintain portion disposed in the maintain region, extending toward the shell part from the seed portion and having constant concentration of the first metal.

13. The positive electrode active material of claim 12 , wherein the intermediate portion is disposed between the seed portion and the maintain portion, the gradient portion is adjacent to the seed element and the uniform portion is adjacent to the maintain portion.

14. The positive electrode active material of claim 10 , wherein the concentration of the first metal in the gradient portion decreases as approaching to the uniform portion.

15. A secondary battery comprising:
the positive electrode active material according to claim 1 ;
a negative electrode disposed on the positive electrode; and
an electrolyte between the positive electrode and the negative electrode.

16. A positive electrode active material comprising:
a primary particle including a plurality of metal; and
a secondary particle including a plurality of the primary particle,
wherein the secondary particle has a core part and a shell part,
wherein the primary particle in the shell part is longer than the primary particle in the core part wherein the primary particle has an a-axis and a c-axis in crystal structure, wherein the a-axis of the primary particle is aligned in a direction from the core part of the secondary particle to the shell part of the secondary particle, and wherein an a-axis direction length of the primary particle increases as approaching to the shell part of the secondary particle from the core part of the secondary particle.

17. The positive electrode active material of claim 16 , wherein the secondary particle includes a seed region, and a length of the seed region is at least 1 μm.

18. The positive electrode active material of claim 16 , wherein the secondary particle includes a seed region, and the seed region is adjacent to the core part of the secondary particle, and the secondary particle further includes a maintain region where concentration of the metal is constant, the maintain region adjacent to the shell part of the secondary particle.

19. The positive electrode active material of claim 16 , wherein the secondary particle includes a seed region, and the metal concentration in the seed region decreases as approaching to the shell part of the secondary particle from the core part of the secondary particle.

Assignees

• Iucf Hyu
• Enerceramic Inc

Inventors

• Park Gang-Jun
• Noh Hyung-Joo
• Sun Yang-Kook
• Park Jang-Wook

Classifications

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M4/366 Primary

  as layered products · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• C01P2002/80

  defined by measured data other than those specified in group C01P2002/70 · CPC title