Ion trap with spatially extended ion trapping region

Patent metadata

Field	Value
Publication number	US-10224196-B2
Application number	US-201615243200-A
Country	US
Kind code	B2
Filing date	Aug 22, 2016
Priority date	Aug 25, 2011
Publication date	Mar 5, 2019
Grant date	Mar 5, 2019

Abstract

A mass or mass to charge ratio selective ion trap is disclosed which directs ions into a small ejection region. A RF voltage acts to confine ions in a first (y) direction within the ion trap. A DC or RF voltage acts to confine ions in a second (x) direction. A quadratic DC potential well acts to confine ions in a third (z) direction within the ion trap. The profile of the quadratic DC potential well progressively varies along the second (x) direction.

First claim

The invention claimed is:

1. An ion trapping or guiding device comprising:
an array of electrodes comprising a first layer of electrodes and a second layer of electrodes, wherein said first and second layers of electrodes are spaced apart in a first (y) direction and are substantially parallel to each other and to a plane orthogonal to said first (y) direction and extending in a second (x) and a third (z) direction; and
one or more voltage sources arranged and adapted to apply one or more voltages to said array of electrodes so as to generate a substantially quadratic DC potential that acts to confine ions within an ion trapping volume in said third (z) direction and a DC potential barrier or well which acts to confine ions within said ion trapping volume in said second (x) direction in order to confine ions substantially within said ion trapping volume wherein ions are fundamentally confined to a plane defined by said first (y) and said second (x) directions but expand to fill a substantially rectangular prism which is spatially elongated at least in the second (x) direction,
wherein said first and second layers each comprise a plurality of segmented rod electrodes extending in the third (z) direction.

2. The device of claim 1 , wherein ions are ejected or separated in the third (z) direction.

3. The device of claim 1 , wherein said ion trapping volume acts to substantially confine ions to a plane orthogonal to said third (z) direction.

4. The device of claim 1 , wherein a dimension of said substantially rectangular prism in said second (x) direction is larger than a dimension in the first (y) direction.

5. The device of claim 4 , wherein the dimension of said substantially rectangular prism in said first (y) direction is larger than a dimension in the third (z) direction.

6. The device of claim 1 , wherein said one or more voltage sources are arranged and adapted to apply one or more voltages so as to cause ions of a selected mass to charge ratio to move from a first region of said ion trapping volume to a second region of said ion trapping volume wherein ions are ejected, in use, from said second region.

7. The device of claim 6 , wherein said one or more voltage sources are arranged and adapted to apply one or more voltages for exciting ions within said second region in order to eject said ions from said second region.

8. The device of claim 1 , wherein said one or more voltage sources are arranged and adapted to apply one or more RF voltages to generate a pseudo-potential barrier or well which acts to confine ions within said ion trapping volume in said first (y) direction.

9. The device of claim 1 , wherein the form of said substantially quadratic DC potential varies across or along the length of the device such that said substantially quadratic DC potential is steeper in a first region of said ion trapping volume and shallower in a second region of said ion trapping volume.

10. The device of claim 9 , wherein, in use, ions are caused to move from said first regions into said second regions, wherein ions are ejected from said second regions.

11. The device of claim 1 , wherein said one or more voltage sources are arranged and adapted to apply one or more RF voltages to generate one or more pseudo-potential barriers or wells which act to confine ions within said ion trapping volume in said second (x) direction.

12. The device of claim 1 , wherein said one or more voltage sources are arranged and adapted to generate one or more DC potentials which act to create one or more ion transmission channels through the device.

13. The device of claim 1 , wherein said one or more voltages act to substantially confine ions between said first and second layers of electrodes within a plane orthogonal to said third (z) direction, and wherein the spatial extent of the ion trapping volume in the third (z) direction is determined at least in part by the kinetic energy and/or mutual repulsion between ions confined within the trapping volume.

14. A collision cell comprising as device as claimed in claim 1 .

15. An ion trapping or guiding device comprising:
an array of electrodes comprising a first layer of electrodes and a second layer of electrodes, where said first and second layers each comprise a plurality of segmented rod electrodes extending in a third (z) direction, where said first and second layers of electrodes are spaced apart in a first (y) direction and are substantially parallel to each other and to a plane orthogonal to said first (y) direction and extending in a second (x) and the third (z) direction, the plurality of segmented rod electrodes comprising at least three segmented rod electrodes; and
one or more voltage sources arranged and adapted to apply one or more voltages to said array of electrodes so as to confine ions substantially within an ion trapping volume which is spatially elongated at least in the second (x) direction.

16. The device of claim 1 , wherein said substantially rectangular prism is arranged substantially perpendicular to electrodes of the first layer of electrodes and the second layer of electrodes.

17. The device of claim 1 , wherein said substantially rectangular prism is arranged substantially at a center location of the first layer of electrodes and the second layer of electrodes with respect to the third (z) direction.

Assignees

• Micromass Ltd

Inventors

• Giles Kevin
• Green Martin Raymond
• Kenny Daniel James
• Langridge David J
• Wildgoose Jason Lee

Classifications

• H01J49/422

  Two-dimensional RF ion traps (ion guides without mass selection H01J49/062) · CPC title

• H01J49/0031

  Step by step routines describing the use of the apparatus (H01J49/0081 takes precedence) · CPC title

• H01J49/4285 Primary

  Applying a resonant signal, e.g. selective resonant ejection matching the secular frequency of ions (H01J49/429, H01J49/428 take precedence) · CPC title

• H01J49/40

  Time-of-flight spectrometers (H01J49/36 takes precedence) · CPC title

• H01J49/062

  Ion guides (linear ion traps performing mass selection H01J49/4225, mass filters H01J49/421) · CPC title