Cryogenic system for removing acid gases from a hydrocarbon gas stream

Patent metadata

Field	Value
Publication number	US-10222121-B2
Application number	US-201514828951-A
Country	US
Kind code	B2
Filing date	Aug 18, 2015
Priority date	Sep 9, 2009
Publication date	Mar 5, 2019
Grant date	Mar 5, 2019

Abstract

A system for removing acid gases from a raw gas stream is provided. The system includes a cryogenic distillation tower. The cryogenic distillation tower has a controlled freezing zone that receives a cold liquid spray comprised primarily of methane. The tower receives and then separates the raw gas stream into an overhead methane gas stream and a substantially solid material comprised on carbon dioxide. The system includes a collector tray below the controlled freezing zone. The collector tray receives the substantially solid material as it is precipitated in the controlled freezing zone. The system also has a filter. The filter receives the substantially solid material and then separates it into a solid material comprised primarily of carbon dioxide, and a liquid material comprising methane. The solid material may be warmed as a liquid and sold, while the liquid material is returned to the cryogenic distillation tower.

First claim

What is claimed is:

1. A method for removing acid gases from a dehydrated raw gas stream, comprising:
providing a cryogenic distillation tower, the tower having a controlled freezing zone that receives a cold liquid spray comprised primarily of methane, and a collector tray below the controlled freezing zone;
injecting the raw gas stream into the cryogenic distillation tower;
chilling the raw gas stream so as to cause carbon dioxide within the raw gas stream to precipitate upon the collector tray as a slurry, while allowing methane to vaporize and exit the cryogenic distillation tower as an overhead methane stream;
passing the overhead methane stream through a refrigeration system downstream of the cryogenic distillation tower, the refrigeration system cooling the overhead methane stream;
returning a portion of the cooled overhead methane stream to the cryogenic distillation tower as liquid reflux to serve as the cold liquid spray;
removing the slurry from the cryogenic distillation tower;
separating the slurry into a solid material comprised primarily of carbon dioxide, and a liquid material comprising methane, said separating step comprising passing the slurry through a first filter, thereby producing a first filter cake comprising the solid material, and a first filtrate comprising the liquid material, and wherein the first filtrate further comprises methane and carbon dioxide, in liquid phase;
warming solid material taken primarily from the first filter cake to produce a carbon dioxide stream, in liquid phase, wherein the liquid carbon dioxide stream comprises a portion of the carbon dioxide stream; and
returning at least a portion of the liquid material to the cryogenic distillation tower.

2. The method of claim 1 , wherein:
the collector tray comprises a downcomer into which the precipitated slurry falls; and
the collector tray directs the slurry out of the cryogenic distillation tower (i) by gravitational flow, (ii) by operation of a mechanical translation device, (iii) by aid of spraying a portion of the cold liquid spray into the collector tray and against the slurry, or (iv) by combinations thereof.

3. The method of claim 1 , wherein:
the cryogenic distillation tower further comprises an upper rectification zone above the controlled freezing zone, and a lower distillation zone below the controlled freezing zone; and
the raw gas stream is injected into the lower distillation zone;
and further comprising releasing a bottoms stream from the lower distillation zone, the bottoms stream comprising acid gases in liquid phase; and
wherein returning at least a portion of the liquid material to the cryogenic distillation tower comprises delivering the liquid material to the lower distillation zone.

4. The method of claim 1 , wherein said separating step further comprises:
rinsing the first filter cake using a liquid carbon dioxide stream;
mixing the first filter cake with the liquid carbon dioxide stream to produce a first solid-liquid slurry; and
delivering the first solid-liquid slurry to a second filter, thereby producing a second filter cake comprised primarily of solid carbon dioxide, and a second filtrate comprising methane, in liquid phase.

5. The method of claim 4 ,
further comprising combining the first filtrate and the second filtrate; and
wherein the liquid material that is returned to the lower distillation zone comprises the combined first filtrate and second filtrate.

6. The method of claim 5 , further comprising:
rinsing the second filter cake using the liquid carbon dioxide stream;
mixing the second filter cake to produce a solid-liquid slurry; and
delivering the solid-liquid slurry to a third filter, thereby producing a third filter cake comprised primarily of solid carbon dioxide, and a third filtrate comprising methane, in liquid phase.

7. The method of claim 1 , wherein the warming comprises passing slurry taken from the first filter cake through a heat exchanger such that heat is exchanged with the raw gas stream.

8. The method of claim 1 , wherein the first filter comprises a porous medium or a centrifuge.

9. The method of claim 1 , wherein the step of returning at least a portion of the liquid material to the cryogenic distillation tower comprises injecting the first filtrate directly back into the controlled freezing zone.

10. The method of claim 6 , further comprising:
combining the second filtrate and the third filtrate;
injecting the second filtrate and the third filtrate into a distillation separator, thereby producing a bottoms liquid stream comprised primarily of carbon dioxide, in liquid phase, and a recovery methane stream; and
combining the overhead methane stream from the cryogenic distillation tower with the recovery methane stream.

11. The method of claim 2 , wherein the collector tray is inclined towards the downcomer to direct the slurry into the downcomer.

Assignees

• Cullinane John Tim
• Northrop Paul Scott
• Exxonmobil Upstream Res Co

Inventors

• Cullinane John Tim
• Northrop Paul Scott

Classifications

• C10L3/102

  of acid contaminants · CPC title

• F25J3/0209

  Natural gas or substitute natural gas · CPC title

• F25J3/067

  separation of carbon dioxide (production of carbon dioxide in general C01B32/00) · CPC title

• F25J2205/84

  using filter · CPC title

• F25J2200/94

  Details relating to the withdrawal point · CPC title